• Title/Summary/Keyword: nano carbon black

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Characteristics of Pt/C Nano-catalyst Synthesized by Arc Plasma Deposition (아크 플라즈마 증착공정을 통한 Pt/C 나노촉매 합성 및 특성평가)

  • Joo, Hye-Sook;Choi, Han-Shin;Ha, Heon-Phil;Kim, Do-Hyang
    • Journal of Powder Materials
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    • v.19 no.1
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    • pp.6-12
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    • 2012
  • Electricity is generated by the combined reactions of hydrogen oxidation and oxygen reduction which occur on the Pt/C catalyst surface. There have been lots of researches to make high performance catalysts which can reduce Pt utilization. However, most of catalysts are synthesized by wet-processes and a significant amount of chemicals are emitted during Pt/C synthesis. In this study, Pt/C catalyst was produced by arc plasma deposition process in which Pt nano-particles are directly deposited on carbon black surfaces. During the process, islands of Pt nano-particles were produced and they were very fine and well-distributed on carbon black surface. Compared with a commercialized Pt/C catalyst (Johnson & Matthey), finer particle size, narrower size distribution, and uniform distribution of APD Pt/C resulted in higher electrochemical active surface area even at the less Pt content.

A new nano-composite carbon ink for disposable dopamine biosensors (나노컴포지트 카본 잉크가 전착된 일회용 도파민 바이오센서)

  • Dinakaran, T.;Chang, S.-C.
    • Analytical Science and Technology
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    • v.29 no.1
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    • pp.35-42
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    • 2016
  • A new nano-composite carbon ink for the development of disposable dopamine (DA) biosensors based on screen-printed carbon electrodes (SPCEs) is introduced. The method developed uses SPCEs coupled with a tyrosinase modified nano-composite carbon ink. The ink was prepared by an “in-house” procedure with reduced graphene oxide (rGO), Pt nanoparticles (PtNP), and carbon materials such as carbon black and graphite. The rGO-PtNP carbon composite ink was used to print the working electrodes of the SPCEs and the reference counter electrodes were printed by using a commercial Ag/AgCl ink. After the construction of nano-composite SPCEs, tyrosinase was immobilized onto the working electrodes by using a biocompatible matrix, chitosan. The composite of nano-materials was characterized by X-ray photoelectron spectroscopy (XPS) and the performance characteristics of the sensors were evaluated by using voltammetric and amperometric techniques. The cyclic voltammetry results indicated that the sensors prepared with the rGO-PtNP-carbon composite ink revealed a significant improvement in electro-catalytic activity to DA compared with the results obtained from bare or only PtNP embedded carbon inks. Optimum experimental parameters such as pH and operating potential were evaluated and calibration curves for dopamine were constructed with the results obtained from a series of amperometric detections at −0.1 V vs. Ag/AgCl. The limit of detection was found to be 14 nM in a linear range of 10 nM to 100 µM of DA, and the sensor’s sensitivity was calculated to be 0.4 µAµM−1cm−2.

Nano-scale Ink Particles for Electrophoretic Display with High Optical Density

  • Choi, Yong-Gir;Cho, Young-Tae;Park, Seung-Chul;Lee, Yong-Eui;Kim, Chul-Hwan;An, Chee-Hong;Kim, Hyoung-Sub
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.865-867
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    • 2009
  • In this paper, we describe the fabrication of nano-scale ink particles with narrow size distribution to offer high optical density in electrophoretic display applications. Charged white ($TiO_2$ and polyester) and black (carbon black and polyester) nano size ink particles in size range of 200 ~ 700nm were made successively using modified non-aqueous base emulsion process. The EPD showed white reflectance of 58% and saturation voltage of ${\pm}10V$.

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Heat generation characteristics of the heating mortar according to repeated electricity supply (반복전기공급에 따른 발열모르타르의 발열 특성)

  • Kim, Young-Min;Lim, Chang-Min;Gwon, Hyeon-U;Lee, Gun-cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.04a
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    • pp.170-171
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    • 2022
  • In recent years, due to the occurrence of traffic accidents caused by black ice in winter, the number of personal injuries is increasing rapidly. Black ice is a phenomenon that occurs like a thin layer of ice on the road surface. Accordingly, many developments of heat-generating concrete are being developed to remove ice by increasing the temperature by supplying constant electricity to places where black ice is likely to occur. These heating elements are being developed by mixing a conductive material represented by carbon nanotubes with concrete. However, research up to now has been focused on efficient temperature rise and derivation of the optimum mixing ratio, and the evaluation of maintaining heat generation performance during continuous repetition is insufficient. Therefore, in this study, a heating test specimen was manufactured and 50V power was repeatedly supplied to evaluate the heating characteristics.

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An Electrochemical Study on the Carbon Black Conductor Prepared by Plasma Pyrolysis of Methane (메탄 플라즈마 분해에 의해 제조된 카본블랙 도전재의 전기화학적 특성에 대한 연구)

  • Yoon, Se-Rah;Lee, Joong-Kee;Cho, Won-Ihl;Baek, Young-Soon;Ju, Jae-Beck;Cho, Byung-Won
    • Journal of the Korean Electrochemical Society
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    • v.6 no.1
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    • pp.6-12
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    • 2003
  • Plasma carbon black(PB) which prepared by plasma pyrolysis of methane was treated at 800, 1300 and $2100^{\circ}C$ under $2\times10^{-2}$ torr. Four different samples including raw PB were added to $LiCoO_2$, cathode active material of lithium secondary battery, to investigate effects of properties of plasma black as conductors on electrochemical characteristics. Based on our experimental results, PB conductors with low amount of surface functional groups and high electrical conductivity enhanced the cyclability and the initial discharge capacity. However, deterioration of rate capability and cyclability were observed (or the plasma black treated at $2100^{\circ}C$ For the plasma black conductor prepared from plasma pyrolysis, the effects of properties of carbon black on electrochemical characteristics were combined results of changes in electrical conductivity and structural properties such as agglomeration of plasma black. The conductivity of plasma black increased with treatment temperature, while dispersion of plasma black decreased. As a result, the high cyclability of cell was observed at $800^{\circ}C$ of heat treatment temperature.

Characterization of Carbon Nanofiber Electrode with different Ketjenblack Conducting Material Mixing Amount Using EDLC (Ketjenblack 전도제 혼합량에 따른 EDLC용 탄소나노섬유 전극의 특성)

  • Choi, Weon-Kyung
    • Journal of Hydrogen and New Energy
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    • v.19 no.2
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    • pp.163-170
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    • 2008
  • Carbon nanofibers with nano-sized structures were evaluated as a active material using supercacitor electrode which could store electrochemical energy reversibly. A feasibility of EDLC electrode was estimated with specific surface area measurement by BET method and mesopore structure of carbon nanofiber surface could be explained electrochemical absorption-desorption in aqueous electrolyte. A capacitance of carbon nanofiber electrode was increased gradually, depending on the ratio of Ketjenblack as a conducting material. Ketjen Black $20{\sim}25\;wt.%$ ratio in electrode was observed a suitable amount of conducting material by cyclic voltametry results.

A Study on the PTC Thermistor Characteristics of Polyethylene and Polyethylene Copolymer Composite Systems in Melt and Solution Manufacturing Method (용액 및 용융 가공방법에 따른 PE 및 PE 공중합물의 PTC 서미스터 특성 연구)

  • 김재철;박기헌;남재도
    • Polymer(Korea)
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    • v.26 no.6
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    • pp.812-820
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    • 2002
  • The positive temperature coefficient (PTC) characteristics of polymer composites were investigated with the nano-sized carbon black particles using solution tasting and melt compounding methods. The polymeric PTC composites should the electrical threshold at 35 wt% for the melt compounding method and 40 wt% for the solution casting method. The ethylene vinylacetate copolymer (EVA) composite showed a gradual increase of resistance as a function of temperature and showed a maximum at the polymer molting point. The resistance of the high-density polythylene (HDPE) composite remains unchanged with temperature but started to Increase sharply near the melting point of HDPE and showed a maximum resistance at the melting point of HDPE. The dispersion of nano-sized carbon black particles was investigated by scanning electron microscopy (SEM) and low resistance after electrical threshold, and both methods exhibited a well dispersed morphology. When the electric current was applied to the PTC composites, the resistance started increasing at the curie temperature and further increased until the trip temperature was roached. Then the resistance remained stable over the trip temperature. The secondary increase started at T$\sub$m/ of matrix polymer and kept increasing up to the trip temperature.

Electromagnetic-wave Shielding by Nano Particles-contained Glass Fiber Reinforced Composite Materials (나노입자 첨가 유리섬유강화 복합재료의 전자기파 차폐특성)

  • 정우균;안성훈;원명식
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.10a
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    • pp.1331-1334
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    • 2004
  • The research on electromagnetic shielding has been advanced for military applications as well as for commercial products. Utilizing the reflective properties and absorptive properties of shielding material, the replied signal measured at the rear surface or at the signal source can be minimized. The shielding effect was obtained from materials having special absorptive properties or from structural characteristics such as stacking sequence. Recently researchers studied the electromagnetic properties of nano size particles. In this research {glass fiber}/{epoxy}/{nano particle} composites(GFR-Nano composites), was fabricated using various nano particles, and their properties in electromagnetic shielding were compared. For the visual observation of the nano composite materials, SEM(Scanning Electron Microscope) and TEM(Transmission Electron Microscope) were used. For the measurement of electromagnetic shielding, HP8719ES S-parameter Vector Network Analyser System was used on the frequency range of 8 GHz~12GHz. Among the nano particles, carbon black and Multi-Walled Carbon Nano-Tube (MWCNT) revealed outstanding electromagnetic shielding. Although silver nano particles (flake and powder) were expected to have effective electromagnetic shielding due to their excellent electric conductivities, test showed little shielding effect.

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Comparison of Electromagnetic-wave Shielding Effect in Glass Fiber Reinforced Nano Composites (유리섬유강화 나노 복합재료의 전자기파 차폐효과 비교)

  • Jung Woo-Kyun;Won Myung-Sik;Ahn Sung-Hoon
    • Journal of the Korean Society for Precision Engineering
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    • v.22 no.10 s.175
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    • pp.121-128
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    • 2005
  • The research on electromagnetic shielding has been advanced for military applications as well as for commercial products. Utilizing the reflective properties and absorptive properties of shielding material, the replied signal measured at the rear surface or at the signal source can be minimized. The shielding effect was obtained from materials having special absorptive properties and structural characteristics such as stacking sequence. Recently researchers studied the electromagnetic properties of nano size particles. In this research {glass fiber}/{epoxy}/{nano particle} composites(GFR-Nano composites) was fabricated using various nano particles, and their properties in electromagnetic shielding were compared. For the visual observation of the nano composite materials, SEM(Scanning Electron Microscope) and TEM(Transmission Electron Microscope) were used. For the measurement of electromagnetic shielding, HP8719ES S-parameter Vector Network Analyser System was used on the frequency range of 8 GHz${\~}$12GHz. Among the nano particles, carbon black and Multi-Walled Carbon Nano-Tube (MWCNT) revealed outstanding electromagnetic shielding. Although silver nano particles (flake and powder) were expected to have effective electromagnetic shielding due to their excellent electric conductivities, test results showed little shielding characteristics.

Effect of Conducting Carbon Layer on AC Thin Film EL Device

  • Park, Lee-Soon;Baek, Jeong-Ju;Park, Jin-Woo;Kim, Dae-Yong;Bae, Sung-Choon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.917-919
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    • 2003
  • The effect of conducting carbon layer on the performance of AC thin film EL display was examined. It was found that incorporation of small amount of carbon nano-tube and conducting additive greatly improve the luminance of the inorganic EL compared to the one with only conducting carbon black.

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