• Title/Summary/Keyword: multicomponent

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Numerical simulations and related problems in multiphase flow and multicomponent transport (다중상 흐름과 다종성분의 거동에 관한 수치적 모의와 문제점)

  • 이강근;이진용;천정용;유동렬;하규철;이철효
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 1998.11a
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    • pp.27-31
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    • 1998
  • Most models for the simulation of multi-phase flow and multi-species transport employ the capillary approach which uses the Darcy's law for the representation of mass flux of each phase. The capillary approach based on the Darcy's law require many empirical coefficients with complex functional dependencies rather than rigrous mathematical and physical formulation. The shortcoming of the capillary approach cause the numerical errors in the simulations by the multi-phase flow and transport models. This study discuss some of the problems related with the use of models.

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Multicomponent wide band gap oxide semiconductors for thin film transistors

  • Fortunato, E.;Barquinha, P.;Pereira, L.;Goncalves, G.;Martins, R.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.605-608
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    • 2006
  • The recent application of wide band gap oxide semiconductors to transparent thin film transistors (TTFTs) is making a fast and growing (r)evolution on the contemporary solid-state electronics. In this paper we present some of the recent results we have obtained using wide band gap oxide semiconductors, like indium zinc oxide, produced by rf sputtering at room temperature. The devices work in the enhancement mode and exhibit excellent saturation drain currents. On-off ratios above $10^6$ are achieved. The optical transmittance data in the visible range reveals average transmittance higher than 80 %, including the glass substrate. Channel mobilities are also quite respectable, with some devices presenting values around $25\;cm^2/Vs$, even without any annealing or other post deposition improvement processes. The high performances presented by these TTFTs associated to a high electron mobility, at least two orders of magnitude higher than that of conventional amorphous silicon TFTs and a low threshold voltage, opens new doors for applications in flexible, wearable, disposable portable electronics as well as battery-powered applications.

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Hydrogen Absorption by Laves Phase Related BCC Solid Solution Alloys

  • Akiba, Etsuo
    • Journal of Hydrogen and New Energy
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    • v.8 no.3
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    • pp.101-109
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    • 1997
  • We propose a new concept of hydrogen absorbing alloy, "Laves phase related BCC solid solution". It was firstly found among the phases tormed in multicomponent nominal $AB_2$ alloys which consisted of Zr and Ti for the A metal site and 5A, 6A and 7A transition metals for the B metal sites. In these alloys a BCC solid solution often coexisted with a Laves phase. It showed stability of hydrides and reaction kinetics almost identical to intermetallics such as Laves phase alloys. We prepared an almost pure "Laves phase related BCC solid solution" and found that it had a large hydrogen capacity (more than 2 mass%) and fast hydrogen absorption and desorption kinetics at ambient temperature and pressure. This new hydrogen absorbing alloy may open a new era of hydrogen related application such as hydrogen vehicles.

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Carbon-Based Solid Acid as an Efficient and Reusable Catalyst for the Synthesis of 1,8-Dioxodecahydroacridines Under Solvent-Free Conditions

  • Davoodnia, Abolghasem;Khojastehnezhad, Amir;Tavakoli-Hoseini, Niloofar
    • Bulletin of the Korean Chemical Society
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    • v.32 no.7
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    • pp.2243-2248
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    • 2011
  • Carbon-based solid acid catalyst was found to be highly efficient, eco-friendly and recyclable heterogeneous catalyst for the multicomponent reaction of dimedone, aromatic aldehydes, and a nitrogen source (ammonium acetate or aromatic amines) under solvent-free conditions, giving rise to 1,8-dioxodecahydroacridines in high yields. The present methodology offers several advantages, such as a simple procedure with an easy work-up, short reaction times, high yields, and the absence of any volatile and hazardous organic solvents.

Influence of VOCs Structure on Catalytic Oxidation Kinetics (휘발성 유기화합물(VOCs)의 촉매산화 전환에서 결합구조의 영향 및 속도특성)

  • 이승범;윤용수;홍인권;이재동
    • Journal of environmental and Sanitary engineering
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    • v.15 no.4
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    • pp.44-51
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    • 2000
  • The reactivity of a range of volatile organic compounds with differing functional groups observed over 0.5% $Pt/{\gamma}-Al_2O_3$ catalyst. In general, the reactivity pattern observed was alcohols > aromatics > ketones > cycloalkane > alkanes. The deep conversion was increased as reaction temperature was increased. A correlation was found between the reactivity of the individual and the strength of the weakest C-Hbond in structure. The conversion of volatile organic compounds increases in order methanol > benzene > cyclohexane > MEK > n-hexane. That is the effect of differences in total dissociation energy. An apparent zeroth-order kinetics with respect to inlet concentration have been observed. A simple multicomponent model based on two-stage redox model made reasonably good predictions of conversion over the range of parameters studied. thus, the catalytic process was suggested as the new VOCs control technology.

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Determination of Optimal Replacement Period for A Multicomponent System Consider with Failure Types (고장형태(故障形態)를 고려(考慮)한 다부품장비(多部品裝備)의 최적교환시기(最適交換時期) 결정(決定))

  • Lee, Seung-Jun;Gang, Chang-Uk;Hwang, Ui-Cheol
    • Journal of Korean Society for Quality Management
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    • v.19 no.2
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    • pp.117-124
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    • 1991
  • In this paper, it is assumed that a system is composed of an essential unit and a nonessential unit. During the running of the system, an essential unit is replaced at periodic replacement time T or at nth failure of essential unit whichever occurs first. Nonessential unit is replaced at its failure and at the replacement of essential unit. This paper derive optimal replacement period which minmises the total expected cost for replacement. The unimodality of totoal maintenance cost function is proved under the assumption that hazard rate of each component is continuous and monotone increasing failure rate(IFR). Based on this condition, it is shown that the optimal replacement period is finite and unique.

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Product Phase Control During Interdiffusion Reactions (상호 확산 반응 중의 생성상 제어)

  • Park, Joon-Sik;Kim, Ji-Hoon;Perepezko, John R.
    • Journal of Korea Foundry Society
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    • v.26 no.1
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    • pp.27-33
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    • 2006
  • Phase evolutions involving nucleation stages together with diffusional growth have been examined in order to provide a guideline for determining rate limiting stages during phase evolutions. In multiphase materials systems in coatings, composites or multilayered structures, diffusion treatments often result in the development of metastable/intermediate phases at the reaction interfaces. The development of metastable phases during solid state interdiffusion demonstrates that the nucleation reaction can be one controlling factor. Also, the concentration gradient and the relative magnitudes of the component diffusivities provide a basis for a phase selection and the application of a kinetic bias strategy in the phase selection. For multicomponent alloy systems, the identification of the operative diffusion pathway is central to control phase formation. Experimental access to the nucleation and growth stage is discussed in thin film multi layers and bulk samples.

Simulated Moving Bed [SMB] (모사 이동층 크로마토그래피)

  • Lee Chong-Ho;Koo Yoon-Mo
    • KSBB Journal
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    • v.20 no.3
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    • pp.192-196
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    • 2005
  • Chromatography has been a method of choice in the separation of complex biological mixtures for the analytical purpose in particular for the last half of century. In current years, chromatographic method extends its use to the preparative separation where the productivity per resin amount and solvent use become a matter of concern. Recently, simulated moving bed (SMB) method which claims high separation efficiency of the ideal counter-current moving bed chromatography has become a workhorse of preparative separation. SMB technology was developed in the early 1960s for large-scale hydrocarbon separation by UOP and approximately 120 Sorbex units have been licensed to date. Recently, SMB separation technology has been successfully extended from hydrocarbons and sugars to fine chemicals, particularly biochemicals, from laboratory to pilot to production plant. In this paper, the current status of SMB and its modifications were reviewed.

Predictive Modeling of Competitive Biosorption Equilibrium Data

  • Chu K.H.;Kim E.Y.
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.11 no.1
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    • pp.67-71
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    • 2006
  • This paper compares regression and neural network modeling approaches to predict competitive biosorption equilibrium data. The regression approach is based on the fitting of modified Langmuir-type isotherm models to experimental data. Neural networks, on the other hand, are non-parametric statistical estimators capable of identifying patterns in data and correlations between input and output. Our results show that the neural network approach outperforms traditional regression-based modeling in correlating and predicting the simultaneous uptake of copper and cadmium by a microbial biosorbent. The neural network is capable of accurately predicting unseen data when provided with limited amounts of data for training. Because neural networks are purely data-driven models, they are more suitable for obtaining accurate predictions than for probing the physical nature of the biosorption process.

Recalibrating virial black hole mass estimators

  • Park, Da-Woo;Woo, Jong-Hak
    • The Bulletin of The Korean Astronomical Society
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    • v.36 no.2
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    • pp.63.1-63.1
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    • 2011
  • In understanding AGN physics, it is fundamental to determine black hole masses. Based on the gas kinematics of the broad-line region, black hole masses can be derived from the product of the width of the broad emission lines and the continuum/line luminosities. For a sample of 37 intermediate-luminosity AGN at z~0.4, we obtained high quality spectra (S/N~100) using the Low Resolution Imaging Spectrometer(LRIS) at the KECK telescope, in order to calibrate various black hole mass estimators based on the Mg II (2798A), the $H{\beta}$ (4861A), and the $H{\alpha}$ (6563$\bar{A}$) emission lines. Based on our multicomponent fitting analysis, we subtract continuum, FeII emission, and host galaxy starlight, reducing systematic errors in measuring emission line widths. Combining low S/N SDSS spectra with our high S/N keck spectra, we determine a set of ~30 black hole masses of the sample for each emission line. Then by comparing various sets of black hole masses, we internally calibrate each mass estimators and investigate uncertainties and limitations of each mass estimator.

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