• Title/Summary/Keyword: molten alloy

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Effects of Mg-Al Alloy and Pure Ti on High Temperature Wetting and Coherency on Al Interface Using the Sessile Drop Method (정적법을 이용한 Mg-Al계 합금과 순수 Ti의 고온 젖음현상 및 Al계면에서의 정합성에 미치는 영향)

  • Han, Chang-Suk;Kim, Woo-Suk
    • Korean Journal of Materials Research
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    • v.31 no.1
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    • pp.38-42
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    • 2021
  • In this study, high temperature wetting analysis and AZ80/Ti interfacial structure observation are performed for the mixture of AZ80 and Ti, and the effect of Al on wetting in Mg alloy is examined. Both molten AZ80 and pure Mg have excellent wettability because the wet angle between molten droplets and the Ti substrate is about 10° from initial contact. Wetting angle decreases with time, and wetting phenomenon continues between droplets and substrate; the change in wetting angle does not show a significant difference when comparing AZ80-Ti and Mg-Ti. As a result of XRD of the lower surface of the AZ80-Ti sample, in addition to the Ti peak of the substrate, the peak of TiAl3, which is a Ti-Al intermetallic compound, is confirmed, and TiAl3 is generated in the Al enrichment region of the Ti substrate surface. EDS analysis is performed on the droplet tip portion of the sample section in which pure Mg droplets are dropped on the Ti substrate. Concentration of oxygen by the natural oxide film is not confirmed on the Ti surface, but oxygen is distributed at the tip of the droplet on the Mg side. Molten AZ80 and Ti-based compound phases are produced by thickening of Al in the vicinity of Ti after wetting is completed, and Al in the Mg alloy does not affect the wetting. The driving force of wetting progression is a thermite reaction that occurs between Mg and TiO2, and then Al in AZ80 thickens on the Ti substrate interface to form an intermetallic compound.

Effect of Alloy Elements on Galvannealed Coating Quality in IF High Strength Steels (IF 고강도 합금화 용융아연도금강판의 표면품질에 미치는 합금원소의 영향)

  • Jeon, Sun-Ho;Chin, Kwang-Geun;Shin, Kwang-Soo;Sohn, Ho-Sang;Kim, Dai-Ryong
    • Korean Journal of Metals and Materials
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    • v.46 no.5
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    • pp.289-295
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    • 2008
  • The effect of the alloy elements(Si/Mn) ratio on the coating quality including wettabilty with molten zinc, galvannealing kinetics and crater has been investigated in interstitial-free high strength steel(IFHSS) containing Si and Mn. When the Si/Mn ratio was below 0.75, IF-HSS exhibited a good wettability leading to a good galvannealed coating quality after annealing at $800^{\circ}C$ for 40s in $15%H_2-N_2$ mixed gas with dew point $-60^{\circ}C$. In contrast, the wettability and galvannealed coating quality were deteriorated in the Si/ Mn ratio above 0.75. It is shown that they have relevance to oxides forms by selective oxidation on the steel surface. The oxide particles dispersed on the steel surface with a surface coverage of below 40% resulted in good wettability and galvannealed coating quality. The oxide particle is mainly consisted of $Mn_2SiO_4$ with low contact angle in molten zinc. On the other hand, the continuous oxide layer on the steel surface, such as network- and film-type,caused to poor wettability and galvannealed coating quality. The coverage of oxide layer was above 80%, and its chemical species was $SiO_2$ with high contact angle in molten zinc. Consequently, the Si/Mn alloy ratio played an importance role in galvannealed coating quality of IF-HSS.

Thermal Insulation Improvement by Laminated Adiabatic Structure Change in Holding Furnace with Molten Aluminum Alloy (알루미늄 용탕 보온용기의 단열재 적층구조 변경을 통한 보온성 향상)

  • Hwang, June-Sun;Kang, Chung-Gil
    • Journal of Korea Foundry Society
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    • v.31 no.6
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    • pp.336-341
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    • 2011
  • Recently, aluminium usage in the automobile industry has been increased cause of its lightweight. The aluminium has a melting-solidification process in producing line and another melting process was needed in manufacturing process. Two times of melting process for making ingot and casting not only makes the loss of time and money but contaminates the air with Sox, Nox. For this reason, the holding furnace with laminated adiabatic material was developed. This holding furnace can deliver the molten aluminium directly to the industry needing molten aluminium. Recent holding furnace has above $15^{\circ}C/h$ of cooling rate and that causes solidification of molten aluminium. The ANSYS software was used to analysis the heat transfer. The adiabatic materials were laminated with optimized arrangement and holding furnace shape was changed with optimized modelling by ANSYS analysis for reducing the cooling rate of molten aluminium in holding furnace.

Evaluation of Wear Performance of Corroded Materials in an 800℃ Molten Salt Environment (800℃ 용융염 환경에서 부식된 재료의 마모 성능 평가)

  • Yong Seok Choi;Kyeongryeol Park;Seongmin Kang;Unseong Kim;Kyungeun Jeong;Ji Ha Lee;Tae Woong Ha;Kyungjun Lee
    • Tribology and Lubricants
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    • v.40 no.3
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    • pp.97-102
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    • 2024
  • The next-generation Molten Salt Reactor is known for its high safety because it uses nuclear fuel dissolved in high-temperature molten salt, unlike traditional solid atomic fuel methods. However, the high-temperature molten salt causes severe corrosion in internal structural materials, threatening the reactor's safety. Therefore, it is crucial to investigate the high-temperature corrosion resistance and wear performance of materials used in reactors to ensure safety. In this study, the high-temperature corrosion resistances and wear performances of corrosion samples in a NaCl-MgCl2-KCl (20-40-40 [wt%]) molten salt are investigated to evaluate the applicability of economically viable stainless steels, 316SS and 304SS. Hastelloy C276 and a new alloy containing a small amount of Nb are used as reference samples for comparative analysis. The mass loss, mass loss rate per unit volume, and surface roughness of each sample are measured to understand the corrosion mechanisms. Scanning electron microscopy and energy-dispersive spectroscopy analyses are employed to analyze the corrosion mechanisms. Wear tests on the corroded samples are also conducted to assess the extent of corrosion. Based on the experimental results, we predict the lifespans of the materials and evaluate their suitability as candidate materials for molten salt reactors. The data obtained from the experiments provide a valuable database for structural materials that can enhance the stability of molten salt reactors and recommend high-temperature corrosion-resistant materials suitable for next-generation reactors.

Design of a non-contacting single infrared sensor for high frequency dental casting machine (치과용 고주파 주조기를 위한 비접촉 단일 온도센서 설계)

  • Hwang, In;Won, Yonggwan;Lee, Sang-Hun;Song, Sung-Geun
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.20 no.8
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    • pp.1546-1552
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    • 2016
  • In addition, because it uses preheating to dissolve an alloy in general, it is hard to regulate the appropriate melting temperature of the alloy and brewing time and shows the defect of the supplementation thing due to the super-heating. Once the alloy is molten and then most of the casting by attaching a sight glass or non-contact temperature sensor is suitable casting temperature the operator pressing a button to generate a centrifugal force to inject the molten alloy into a crucible in the casting ring. These results, and most of the cast temperature is too high or too low to generate a lot of casting defects do not get into a uniform cast body. In this paper, we developed a dental casting machine for high frequency using a single temperature sensor which can measure the actual temperature of the alloy than the temperature of the external non-contact measurement using a temperature sensor.

Effect of Pouring Temperature on the Casting Characteristics and Microstructure of Twin-roll Cast BCuP Alloy (BCuP계 합금의 쌍롤주조시 주조특성과 미세조직에 미치는 주입온도의 영향)

  • Joo, Dae-Heon;Kim, Myung-Ho
    • Journal of Korea Foundry Society
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    • v.21 no.4
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    • pp.232-238
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    • 2001
  • Experimental study on the twin roll strip casting of BCuP-5(Cu-15wt%Ag-wt5%P) alloy was carried out using laboratory scale horizontal type twin roll caster. In this study, among the various operating parameters, such as tundish angle, contact angle, pouring temperature, roll speed, presetting gap of the rolls and kinds of roll and tundish materials, effect of pouring temperature for strip casting of BCuP-5 alloy which has long freezing range of about $170^{\circ}C$ was mainly investigated. BCuP-5 alloy strip was successfully produced when pouring molten metal at lower temperature than its liquidus temperature. Microstructure of the cast strip consists of primary Cu and eutectic. Especially the size of primary Cu phase increased with decreasing of pouring temperature.

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Formation of $Al_2O_3$-Composites by the Melt Oxidation of an AlZnMg-alloy (AlZnMg-합금의 용융산화에 의한 $Al_2O_3$-복합재료의 형성)

  • 김일수;김상호;강정윤
    • Journal of the Korean Ceramic Society
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    • v.33 no.9
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    • pp.985-994
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    • 1996
  • The initiation and growth of $\alpha$-Al2O3/metal composites by the directed oxidation of molten commercial AlZnMg-alloy at 1223-1423K were investigated. Spontaneous bulk growth did not occur on the alloy alone. but the uniform initiation and growth of the composite were obtained by putting a thin layer of SiO2 particles on the surface of the alloy. Without SiO2 the external surface of the oxide layer was convered by MgO and MgAl2O4. But with the SiO2 reaction initiate the porous ZnO layers were found on the growth surface. The higher process temperature yielded a lower metal content. The oxidation product of $\alpha$-Al2O3 was found to be oriented with c-axis parallel to th growth direction. The growth rates increased with temperature and the apparent activation energy was 111.8 kJ/mol.

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Identification and Microstructure Observation of Reaction Products formed at Alumina/Ag-33.5Cu-1.5Ti Brazing alloy Interface (알루미나의 Ag-33.5Cu-1.5Ti 브레이징 합금 계면에서 생성되는 반응층의 미세조직 관찰과 상 동정)

  • 최시경;권순용
    • Journal of the Korean Ceramic Society
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    • v.33 no.9
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    • pp.1045-1049
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    • 1996
  • Pressureless-sintered polycrystalline alumina and carbon steel were joined with Ag-33.5Cu-1.5Ti (wt%) brazing alloy. SEM observation revealed that two reaction layers with different thicknesses were continuously formed between the alumina and the brazing alloy. A thick layer formed on the brazing alloy side was identified as Ti3(Cu0.93Al0.07)3O phase with diamond cubic structure. Another thin layer adjacent to the alumina was revealed as $\delta$-TiO phase of which the crystal structure was HCP with a lattice parameter of a0=0.419 nm and c0=0.284 nm. It was confirmed using XPS analysis that $\delta$-TiO was formed directly by a redox reaction of alumina with titanium ir, molten brazing alloy.

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APPLICATION OF DISPROPORTIONATION REACTION TO SURFACE TREATMENT

  • Oki, Takeo
    • Journal of the Korean institute of surface engineering
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    • v.29 no.5
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    • pp.478-481
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    • 1996
  • Disproportionation reaction is very important and interesting reaction to be applied to such surface treatment as metal, alloy, compound coating, a surface etching and so on. In gaseous system, the reaction of Al chloride is applied to Al and Al alloy coating, and the similar reaction of Ti chloride is also used for Ti, Ti alloy and Ti compound coating. As for aqueous system, this reaction is utilized to such metal coat as Sn etc. and metal etching such as Cu, Fe and so on. Also in molten salts system, this reaction has many application for surface treatment like metal, alloy and compound coatings for corrosion, wear, heat resistance and so forth. For instance, carbide film, nitride film, boride film, alloy film, quite new different film from the components of substrate material are coated in single and multiple component film system by the disproportionation reaction.

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The Effect of Additive Elements on the Formation of Oxide Skins of AI-10wt.% Si Alloy Melts (용융 Al-10wt.%Si 합금의 산화피 형성에 미치는 첨가원)

  • 최재영;양정식;백영남
    • Journal of the Korean institute of surface engineering
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    • v.22 no.4
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    • pp.179-184
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    • 1989
  • This study seeks to the morphological changes in the oxide skin of the Al-10wt.%si alloy melts. These changes depend on the oxidation time and the temperature of the molten alloy, as well as the effects of adding Mg, Cu and Ni. Thess affects observed by X-ray diffractometer(XRD) and scanning electron microscope(SEM)' Very litte oxide skins on Al-10wtwt.%Si alloy melts can be detected by XRD because it is less than the measuring capabillity of the XRD, or the formation of noncrystalline oxide skins oxide skins canbe deteced by SEM. The addition of 1%Mg and 1%Cu-1%Mg-2.5%Ni to this base alloy crystallized the structure of the oxide skins and increased the oxidation in proportion to the length of time, but adding 3% had hardiy anyaffect at all on the crystal structure of the oxide skins.

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