• Bulletin of the Korean Chemical Society
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• 제24권1호
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• pp.55-59
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• 2003

This work is focused on analyzing ion-pair interactions and showing the effect of solvent induced inter-atomic attractions in various dielectric environments. To estimate the stability of ion-pairs, SCI-PCM ab initio MO calculations were carried out. We show that the solvent-induced attraction or ‘cavitation' energy of the ion-pair interactions in solution that arises mainly from the stabilization of the water molecules by the generation of an electrostatic field. In fact, even the strong electrostatic interaction characteristic of ion-pair interactions in the gas phase cannot overcome the destabilization or reorganization of the water molecules around solute cavities that arise from cancellation of the electrostatic field. The solvent environment, possibly supplemented by some specific solvent molecules, may help place the solute molecule in a cavity whose surroundings are characterized by an infinite polarizable dielectric medium. This behavior suggests that hydrophobic residues at a protein surface could easily contact the side chains of other nearby residues through the solvent environment, instead of by direct intra-molecular interactions.

• 한국염색가공학회지
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• 제13권6호
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• pp.435-440
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• 2001

This study investigates the rheological properties of in-situ polymerized solutions of polyacrylonitrile(PAN) and acrylonitrile(AN) -itaconic acid(IA) in dimethyl sulfoxide(DMSO) in terms of temperature, concentration, and time. The complex viscosity and storage modulus of the solutions were generally increased with elapsing time, which is ascribable to the three-dimensional pseudostructures formed by strong inter- or Intra-molecular attractions through Polar -CN and -COOH groups. The three-dimensional pseudonetworks would lead to relation of the acrylic solutions in long term. This was more noticeable at higher temperature within the temperature range examined. In the case of 20% solutions one can not observe lower Newtonian flow region in the viscosity curve. Disappearance of lower Newtonian flow region is indicative of heterogeneity of the solution system. Casson Plot of the viscosity data revealed that 20% solutions of PAN and AN-IA copolymer in DMSO clearly demonstrated positive yield stress, ascertaining formation of pseudostructures in the solution systems.

• 한국염색가공학회지
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• 제13권6호
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• pp.77-77
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• 2001

This study investigates the rheological properties of in-situ polymerized solutions of polyacrylonitrile(PAN) and acrylonitrile(AN)-itaconic acid(IA) in dimethyl sulfoxide(DMSO) in terms of temperature, concentration, and time. The complex viscosity and storage modulus of the solutions were generally increased with elapsing time, which is ascribable to the three-dimensional pseudostructures formed by strong inter- or intra-molecular attractions through Polar -CN and -COOH groups. The three-dimensional pseudonetworks would lead to gelation of the acrylic solutions in long term. This was more noticeable at higher temperature within the temperature range examined. In the case of 20% solutions one can not observe lower Newtonian flow region in the viscosity curve. Disappearance of lower Newtonian flow region is indicative of heterogeneity of the solution system. Casson Plot of the viscosity data revealed that 20% solutions of PAN and AN-IA copolymer in DMSO clearly demonstrated positive yield stress, ascertaining formation of pseudostructures in the solution systems.

• Macromolecular Research
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• 제14권6호
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• pp.654-658
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• 2006

Recent developments in equations of state for molecular fluids have demonstrated the feasibility of using the hard-sphere equation to describe the effects of repulsive forces in simple fluids. By including a suitable term for attractive forces, most conveniently a uniform background potential, the properties of bio-macromolecular interaction can be roughly calculated. However, the choice of the potential used in perturbed hard-sphere chain (PHSC) theory for describing the attractions between macromolecules is rather complicated. For hard-sphere chains, the prediction accuracy from each model strongly depends on the choice of potential function.

• Korean Chemical Engineering Research
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• 제46권6호
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• pp.1081-1086
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• 2008

양자 점을 이용한 QD-LED(Quantum Dot - Light Emitting Device)의 소자 제작을 하기 위해서는 양자 점의 균일한 배열이 중요하다. 핵-껍질(core-shell) 구조의 CdSe/ZnS 양자 점을 기판에 고 밀도, 고 균일도로 배열하기 위하여 두 종류의 분자 끈(molecular linker)을 사용하였고, 공정의 단순화와 비용 절감을 위하여 고분자 도장인 PDMS(polydimethylsiloxane)를 이용한 미세접촉인쇄방법으로 양자 점들을 배열하였다. $TiO_2/ITO$ 기판에 양자 점을 고정시켜주는 역할을 하는 분자 끈으로는 2-carboxyethylphosphonic acid(CAPO)를 사용하였고, 양자 점 사이의 인력을 향상시켜주는 분자 끈으로는 1,6-hexanedithiol(HDT)을 사용하였다. 양자 점들의 배열 특성을 주사전자현미경(SEM, scanning electron microscope)과 원자 힘 현미경(AFM, atomic force microscope)으로 분석하였고, 광 발광분광기(PL, photoluminescence spectroscope)로 발광특성을 측정하였다.

• ALGAE
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• 제35권4호
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• pp.337-347
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• 2020

Haraldiophyllum hawaiiense sp. nov. is described as a new mesophotic alga and a new genus record for the Hawaiian Islands. Six specimens were collected at a depth range of 81-93 m from Papahānaumokuākea Marine National Monument, and their morphology investigated, as well as molecular phylogenetic analyses of the plastidial ribulose-1,5-bisphosphate carboxylase-oxygenase large-subunit (rbcL) gene and a concatenated alignment of rbcL and nuclear large-subunit rRNA gene (LSU) sequences. Phylogenetic analyses supported H. hawaiiense sp. nov. as a distinct lineage within the genus Haraldiophyllum, and sister to a large clade containing the type species, H. bonnemaisonii, as well as H. crispatum and an undescribed European specimen. The six Hawaiian specimens were shown to be identical, but unique among other species of the genus as well as the recently segregated genus Neoharaldiophyllum, which comprises half of the species previously included in Haraldiophyllum. The vegetative morphology of H. hawaiiense sp. nov. resembles Neoharaldiophyllum udoense (formerly H. udoensis); however, no female or post-fertilization structures were found in the Hawaiian specimens to allow a more comprehensive comparison. The molecular phylogenies demonstrate that Haraldiophyllum is paraphyletic, suggesting either that the Myriogrammeae tribe includes undescribed genera, including Haraldiophyllum sensu stricto, or that Neoharaldiophyllum species should be transferred into the genus Haraldiophyllum. However, based on vegetative morphology and molecular analyses, and pending resolution of this taxonomic issue, the Hawaiian specimens are placed within the genus Haraldiophyllum. This new record for the Hawaiian Islands highlights the novel biodiversity from mesophotic depths, reaffirming the need for further investigation into the biodiversity of Mesophotic Coral Ecosystems.

• 한국수학사학회지
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• 제21권3호
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• pp.1-30
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• 2008

뉴턴의 중력이론의 성공은 수학물리학을 태동시키는 바, 최초로 19세기 초의 분자력의 모델성립에 중요한 요소로 등장하였다. 라플라스는 여기서 회전타원체의 작용이라는 모델을 이용하였고 회전타원체의 작용은 이계편미분방정식으로 표현이 되었다. 이것을 풀어서 유체를 담은 용기의 기하학적 모습과 와 유체와 고체의 접촉각에 대응시켰다. 알 수 없는 분자간거리는 추상적이고 미지의 힘 함수 $\varphi(f)$를 써서 표현하여, 분자 작용반경이라는 개념을 도입하여 이론적인 포텐셜 함수의 이론적인 토대를 구축하였다. 뉴턴의 중력이론은 라플라스이론에서 완성을 이루었고, 이후 분자력의 모델로서 작용을 하였다. 라플라스-영의 모세관이론은 수학적으로는 극소 곡면론에서 물리학적으로는 표면장력현상으로 설명이 된다.

• 한국인터넷방송통신학회논문지
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• 제17권6호
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• pp.151-160
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• 2017

지역의 관광지 및 문화를 체험 콘텐츠로 개발하는 방법 중 고화질의 비디오 영상을 대형 디스플레이에 표시하는 게 일반적인 방식으로 체험자의 능동적 참여와 다른 지역의 영상 체험과의 특별한 차별성이 필요하게 된다. 본 논문은 단분자 OLED와 능동형을 사용하여 지역의 명소를 투명 OLED 듀얼 레이어 디스플레이 시스템과 확장형 영상 구현 및 증강형 인터렉션 기법을 융합하여 체험자에게 새로운 경험과 아름다운 명소에 직접 와 있는 것과 같은 현실감 있는 체험을 제공 한다. 본 논문에서는 영상의 레이어에 추가적인 영상과 UI 레이어를 입혀 관광지 정보, 날씨, 지도, 숙박, 축제, 사진 자료등을 영상과 함께 체험할 수 있도록 하였으며, 듀얼 레이어 시스템 외에 추가로 양단에 세로형 55인치 디스플레이를 보조적으로 각각 1대씩 추가 연동하는 멀티 디스플레이 시스템을 더해 체험자에게 웅장한 몰입감과 인터페이스 연동의 재미를 더할 수 있도록 구현하였으며, 투명 OLED 및 듀얼 레이어 패널과 3채널 멀티 영상 재생 기법을 활용하여 한국의 전라남도 지역의 명소를 시공간의 제약 없이 상시 체험 가능한 증강형 체험 콘텐츠을 개발하였다.