• Title/Summary/Keyword: mixture 모델

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Experiment and Simulation of 4-bed PSA for Hydrogen Separation from Multi-Component Mixture Gases (다성분 혼합 기체로부터 수소 분리를 위한 4-bed PSA 실험과 전산 모사)

  • Yang, Se-Il;Park, Ju-Yong;Jang, Seong-Cheol;Choi, Do-Young;Kim, Sung-Hyun;Choi, Dae-Ki
    • Korean Chemical Engineering Research
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    • v.46 no.2
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    • pp.414-422
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    • 2008
  • Adsorption experiments for $H_2$, $CH_4$, CO, $CO_2$ on activated carbon and zeolite 5A were performed by static volumetric method. A 4-bed pressure swing adsorption (PSA) process was to study separation of hydrogen from multi-component mixture gases ($H_2$ 72.2%, $CH_4$ 4.06%, CO 2.03%, $CO_2$ 21.6%). Dual-site langmuir (DSL) isotherm showed good or fair agreement with the experimental results. The optimum height of activated carbon layer was 55 cm with breakthrough results on the packing ratio of activated carbon to zeolite 5A. In PSA process, the effects of the process parameters such as total cycle time ($T_c$), ${\Delta}P$ at the provide purge step and adsorption pressure on the PSA performance were studied experimentally and theoretically.

Purification of p-Dioxanone from p-Dioxanone and Diethylene Glycol Mixture by a Layer Melt Crystallization (경막형 용융결정화에 의한 파라디옥사논과 디에틸렌글리콜 혼합물로부터 파라디옥사논의 정제)

  • Kim, Sung-Il;Kim, Chul-Ung;Park, So-Jin
    • Korean Chemical Engineering Research
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    • v.43 no.5
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    • pp.595-602
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    • 2005
  • In order to purify diethylene glycol as main impurity included in p-dioxanone, SLE (solid-liquid equilibria) and mixture density on two components system of p-dioxanone and diethylene glycol were measured and a layered melt crystallization with seed has been applied. The SLE of p-dioxanone and diethylene glycol were a simple eutectic system and the temperature and PDX concentration at eutectic point were 0.08 and 246 K, respectively. Densities of their binary mixtures were well fitted by the best correlation equation, ${\rho}_l=0.405+1.361x+0.002T-0.004xT$. In the melt crystallization, the growth rate (G) was proportional to the 1.5th power of the subcooling degree. The effective distribution coefficient ($K_{eff}$) as the degree of impurity removal was observed to increase with increasing the growth rate and initial p-dioxanone concentration. And also, $K_{eff}$ was correlated with Z function using Wintermantel's model such as $K_{eef}=-0.0604+6.392{\times}Z$. Finally, PDX purity through the optimization of this process can be obtained over 99%.

Effect of Various Gums on Flow Properties and Yield Stress of Korean Sweet Potato Starch (여러 종류의 검 첨가가 국내산 고구마전분의 유동특성 및 Vane 항복응력에 미치는 영향)

  • Choi, Hye-Mi;Yoo, Byoung-Seung
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.38 no.9
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    • pp.1253-1257
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    • 2009
  • The effects of seven commercial gums (xanthan gum, guar gum, pectin, gum arabic, gellan, locust bean gum, and sodium alginate) at different concentrations (0, 0.3, and 0.6%) on flow properties of sweet potato starch (SPS) pastes were investigated. Flow behavior characteristics were adequately described by power law flow model, and yield stress was also measured by vane method. SPS-gum mixtures (5% w/w) at $25^{\circ}C$ were found to have high shear-thinning flow behavior with yield stress, and their consistency index (K) and apparent viscosity ($\eta_{a,100}$) increased with elevated gum concentration, except for pectin and sodium alginate. Vane yield stress ($\sigma_o$) value of SPS-pectin mixture was lower when compared to other mixtures while that of SPS-gellan mixture was much higher. Most of the gums, except for pectin, gum arabic, and sodium alginate, showed a synergistic effect on the elastic properties of SPS-gum mixtures. In general, the flow properties of SPS-gum mixtures appeared to be strongly influenced by the addition of gum, and dependent on the type and concentration of gum.

Hybrid Method using Frame Selection and Weighting Model Rank to improve Performance of Real-time Text-Independent Speaker Recognition System based on GMM (GMM 기반 실시간 문맥독립화자식별시스템의 성능향상을 위한 프레임선택 및 가중치를 이용한 Hybrid 방법)

  • 김민정;석수영;김광수;정호열;정현열
    • Journal of Korea Multimedia Society
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    • v.5 no.5
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    • pp.512-522
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    • 2002
  • In this paper, we propose a hybrid method which is mixed with frame selection and weighting model rank method, based on GMM(gaussian mixture model), for real-time text-independent speaker recognition system. In the system, maximum likelihood estimation was used for GMM parameter optimization, and maximum likelihood was used for recognition basically Proposed hybrid method has two steps. First, likelihood score was calculated with speaker models and test data at frame level, and the difference is calculated between the biggest likelihood value and second. And then, the frame is selected if the difference is bigger than threshold. The second, instead of calculated likelihood, weighting value is used for calculating total score at each selected frame. Cepstrum coefficient and regressive coefficient were used as feature parameters, and the database for test and training consists of several data which are collected at different time, and data for experience are selected randomly In experiments, we applied each method to baseline system, and tested. In speaker recognition experiments, proposed hybrid method has an average of 4% higher recognition accuracy than frame selection method and 1% higher than W method, implying the effectiveness of it.

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Evaluation of Interlayer Shear Properties and Bonding Strengths of a Stress-Absorbing Membrane Interlayer and Development of a Predictive Model for Fracture Energy (덧씌우기 응력흡수층에 대한 전단, 부착강도 평가 및 파괴에너지 예측모델 개발)

  • Kim, Dowan;Mun, Sungho;Kwon, Ohsun;Moon, Kihoon
    • International Journal of Highway Engineering
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    • v.20 no.1
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    • pp.87-95
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    • 2018
  • PURPOSES : A geo-grid pavement, e.g., a stress-absorbing membrane interlayer (SAMI), can be applied to an asphalt-overlay method on the existing surface-pavement layer for pavement maintenance related to reflection cracking. Reflection cracking can occur when a crack in the existing surface layer influences the overlay pavement. It can reduce the pavement life cycle and adversely affect traffic safety. Moreover, a failed overlay can reduce the economic value. In this regard, the objective of this study is to evaluate the bonding properties between the rigid pavement and a SAMI by using the direct shear test and the pull-off test. The predicted fractural energy functions with the shear stress were determined from a numerical analysis of the moving average method and the polynomial regression method. METHODS : In this research, the shear and pull-off tests were performed to evaluate the properties of mixtures constructed using no interlayer, a tack-coat, and SAMI with fabric and without fabric. The lower mixture parts (describing the existing pavement) were mixed using the 25-40-8 joint cement-concrete standard. The overlay layer was constructed especially using polymer-modified stone mastic asphalt (SMA) pavement. It was composed of an SMA aggregate gradation and applied as the modified agent. The sixth polynomial regression equation and the general moving average method were utilized to estimate the interlayer shear strength. These numerical analysis methods were also used to determine the predictive models for estimating the fracture energy. RESULTS : From the direct shear test and the pull-off test results, the mixture bonded using the tack-coat (applied as the interlayer between the overlay layer and the jointed cement concrete) had the strongest shear resistance and bonding strength. In contrast, the SAMI pavement without fiber has a strong need for fractural energy at failure. CONCLUSIONS : The effects of site-reflection cracking can be determined using the same tests on cored specimens. Further, an empirical-mechanical finite-element method (FEM) must be done to understand the appropriate SAMI application. In this regard, the FEM application analy pavement-design analysis using thesis and bonding property tests using cored specimens from public roads will be conducted in further research.

Production of Extrudates Formulated from Pacific Sand Lance Sauce By-Product and Dried Biji (까나리 액젓 부산물과 건조 비지를 첨가한 압출성형물의 제조)

  • Han, Gyu-Hong;Kim, Byung-Yong;Lee, Jae-Kwon
    • Korean Journal of Food Science and Technology
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    • v.34 no.2
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    • pp.186-193
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    • 2002
  • This study was conducted to enhance the protein quality of wheat flour extrudates with the addition of fish sauce by-products and dried biji. The experimental design was used to determine the optimum ratio of each ingredient. The compositional and functional properties of test extrudate were measured, and these values were applied to the mathematical models. A canonical form and trace plot showed that the influence of each ingredient on the mixture final product. Protein content of extrudate was increased by the addition of the dried biji, and bending failure stress of extrudate became hardened due to interaction effects between dried biji and pacific sand lance sauce by-product. Also, the addition of dried biji decreased ash and salt contents. An optimum formulation was obtained as 15.83 : 44.17 : 40% with numerical and 15.74 : 44.26 : 26.40% with graphical method (pacific sand lance sauce by-product : dried biji : wheat flour). Based on the growth performance, feed conversion efficiency was slightly lower than control group, but the protein content in feed extrudate increased to a large extent compared to that mixed with wet biji.

Biofilter Model for Robust Biofilter Design: 1. Adsorption Behavior of the Media of Biofilter (강인한 바이오필터설계를 위한 바이오필터모델: 1. 바이오필터 담체의 흡착거동)

  • Lee, Eun Ju;Seo, Kyo Seong;Jeon, Wui-Sook;Lim, Kwang-Hee
    • Korean Chemical Engineering Research
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    • v.50 no.1
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    • pp.149-154
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    • 2012
  • The adsorption and desorption behavior of biofilter-medium was investigated on the performance of an adsorption column. Continuous flow-isothermal adsorption experiments were performed to treat waste air containing such a VOC as ethanol under the same condition of > 90% relative humidity as the condition of the feed to a biofilter process. In case of feeding waste air containing ethanol of 1,000 ppmv (or 2,050 mg ethanol/$m^3$) to the adsorption system at the rate of 2 L/min, the onsets of its breakthrough and reaching the state of dynamic equilibrium at the exit had been delayed 10 and 3 times, respectively, later than those at the 1st stage sampling port. Moreover, in case of 2,000 ppmv (or 4,100 mg ethanol/$m^3$), they had been delayed 9 and 3 times, respectively. Thus, regardless of feeding concentration, the ratios of delaying period were observed to be quite consistent each other at the exit of the adsorption column. With regard to the period of desorption, the ratios of delaying period were consistent each other to be 1.5 for both cases. In addition, the effect of microbial activity and sterilization-process was studied on adsorption equilibrium. The ethanol concentration in the vapor phase of vials packed with sterilized granular activated carbon (GAC) was quite consistent to that with unsterilized GAC. However, the ethanol concentrations in the vapor phase of vials packed with unsterilized compost and the unsterilized mixture of GAC and compost were higher than those with sterilized compost and the sterilized mixture of GAC and compost, respectively.

Adsorption and Desorption Dynamics of Ethane and Ethylene in Displacement Desorption Process using Faujasite Zeolite (제올라이트(faujasite)를 이용한 치환탈착공정에서 에탄, 에틸렌의 흡, 탈착 동특성)

  • Lee, Ji-In;Park, Jong-Ho;Beum, Hee-Tae;Yi, Kwang-Bok;Ko, Chang-Hyun;Park, Sung Youl;Lee, Yong-taek;Kim, Jong-Nam
    • Korean Chemical Engineering Research
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    • v.48 no.6
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    • pp.768-775
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    • 2010
  • Adsorption dynamics of ethane/ethylene mixture gas and desorption dynamics during the displacement desorption with propane as a desorbent in the column filled with faujasite adsorbent were investigated experimentally and theoretically. The simulation that adopted heat and mass balance and an ideal adsorbed solution theory (IAST) for the multicomponent adsorption equilibrium well predicted the experimental breakthrough curves of the adsorption and desorption. At the adsorption breakthrough experiments, roll-ups of ethane increased as the adsorption pressure increased and the adsorption temperature decreased. During the displacement desorption with propane in the column saturated with ethane/ethylene mixture gas, almost 100% of ethylene was obtained for a certain time interval. The adsorption strength of the desorbent greatly affected the adsorption and re-adsorption dynamics of ethylene. The re-adsorption capacity for ethylene has been greatly reduced when iso-propane, which is stronger desorbent than propane, was used as desorbent. It was found from the simulation that the performance of the displacement desorption process would be superior when the ratio of ${(q_s{\times}b)}_{C_2H_4}/{(q_s{\times}b)}_{C_3H_s}$ was 0.83, that is, the adsorption strengths of ethylene and the desorbent were similar.

Development of Actual Measurement Spacing Factor Using Spacing Data of Air Void in Concrete (콘크리트의 공극 간격 데이터를 활용한 실측간격계수 개발)

  • Lee, Jin-Bum;Jeon, Sung-Il;Kwon, Soo-Ahn;An, Ji-Hwan
    • Journal of the Korea Concrete Institute
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    • v.23 no.6
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    • pp.701-709
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    • 2011
  • One of the typical evaluation models of concrete air-void system is spacing factor (SF), which was suggested by Power. Power Spacing Factor (PSF) has a disadvantage of the result being different from the actual case due to the existence of entrapped air, because PSF uses average single spacing factor. Therefore, the Actual Measurement Spacing Factor (AMSF) using actually measured data of air void spacing was developed from this study. PSF and AMSF were compared and evaluated in this study by using the image analysis test result of concrete mixture. This study results showed that PSF and AMSF are generally similar, but AMSF had a larger value when PSF was greater than $400{\mu}m$. The results indicated a possibility of PSF giving false measurement estimation where the measurement is less than the actual value in the concrete mixture containing less air. Also, in the result of PSF and AMSF analysis according to the existence of entrapped air, AMSF showed a larger value in the analysis without entrapped air. But PSF showed a smaller value in the analysis without entrapped air, which was different from the actual case. Because PSF used average single spacing factor, it tended to give a false result. The study results showed that AMSF gave more accurate analysis results.

Compromised feature normalization method for deep neural network based speech recognition (심층신경망 기반의 음성인식을 위한 절충된 특징 정규화 방식)

  • Kim, Min Sik;Kim, Hyung Soon
    • Phonetics and Speech Sciences
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    • v.12 no.3
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    • pp.65-71
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    • 2020
  • Feature normalization is a method to reduce the effect of environmental mismatch between the training and test conditions through the normalization of statistical characteristics of acoustic feature parameters. It demonstrates excellent performance improvement in the traditional Gaussian mixture model-hidden Markov model (GMM-HMM)-based speech recognition system. However, in a deep neural network (DNN)-based speech recognition system, minimizing the effects of environmental mismatch does not necessarily lead to the best performance improvement. In this paper, we attribute the cause of this phenomenon to information loss due to excessive feature normalization. We investigate whether there is a feature normalization method that maximizes the speech recognition performance by properly reducing the impact of environmental mismatch, while preserving useful information for training acoustic models. To this end, we introduce the mean and exponentiated variance normalization (MEVN), which is a compromise between the mean normalization (MN) and the mean and variance normalization (MVN), and compare the performance of DNN-based speech recognition system in noisy and reverberant environments according to the degree of variance normalization. Experimental results reveal that a slight performance improvement is obtained with the MEVN over the MN and the MVN, depending on the degree of variance normalization.