• Korean Chemical Engineering Research
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• 제53권2호
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• pp.193-198
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• 2015

Polycaprolactone, Dichloromethane, 이산화탄소로 구성된 3성분계 고압 시스템의 상거동 측정 실험은 가변 부피 셀 장치를 이용해서 측정했다. 실험의 온도범위는 313.15 K에서 353.15 K, 압력은 약 300 bar까지 측정했으며 실험결과는 Polycaprolactone의 질량 분율이 1.0%, 2.0%, 3.0%일 때 온도와 이산화탄소/Dichloromethane의 질량 분율로 정리했다. 또한 실험 결과는 hybrid 상태방정식 (Peng-Robinson 상태방정식과 SAFT 상태방정식의 혼합형태) 을 이용하여 열역학적으로 검증하였으며, 혼합규칙은 반데르 발스의 단일 유체 혼합규칙을 사용했다. 이 다성분계 시스템에서 이원 상호 작용 파라미터 등, 각종 파라미터는 심플렉스 알고리즘을 통해 최적화했다.

• 한국결정성장학회지
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• 제31권6호
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• pp.276-281
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• 2021

반도체 회로를 제조하기 위해서 에칭, 세척, 증착 등의 공정들이 반복적으로 진행된다. 따라서 이러한 공정이 진행되면 진공장비 내부는 부식성이 높은 가혹한 플라즈마 환경에 노출되게 된다. 따라서 반도체 공정 장비의 내부를 플라즈마 노출에 강한 재료를 사용하여 코팅층의 에칭과 오염 입자의 생성을 최소화하여야 한다. 본 연구에서는 고상합성법에 의해 Y₂O₃와 YF₃ 분말을 원료물질로 옥시불화이트륨(YOF)를 성공적으로 합성하였다. Y₂O₃와 YF₃ 분말의 혼합비율은 1.0:1.0에서 1.0:1.6까지 조절하였으며, 혼합비율이 합성된 YOF 분말의 결정구조와 미세구조에 미치는 영향을 XRD와 FE-SEM으로 조사하였다. 합성된 YOF 분말을 이용하여 알루미늄 기판에 플라즈마 스프레이법으로 성공적으로 코팅하였다.

• 한국재료학회지
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• 제15권5호
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• pp.285-292
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• 2005

Anti-reflection film was coated by using spherical silica nano colloids. Silica colloid sol was reserved between two inclined slide glasses by capillary force, and particles were convectively stacked to form a film onto the substrate as the water evaporates. As the sliding speed increased, the thickness of the film decreased and the wavelength at the maximum transmittance decreased. The microstructure observed by SEM showed that silica particles were nearly close packed, which enabled the calculation of the effective refractive index of the film. The film thickness was measured by proffer and calculated from the wavelength of maximum transmittance and the effective refractive index. The effective refractive index of the film could be controlled by a subtle controlling of the coating speed and by mixing two different sized silica particles. When the 100 nm and 50 m particles were mixed at 4:1-5:1 volume ratio, the maximum transmittance of $95.2\%$ for one-sided coating was obtained. This is the one that has increased by $3.8\%$ compared to bare glass substrate, and shows that $99.0\%$ of transmittance or $1.0\%$ of reflectance can be achieved by the simple process if both sides of the substrate are coated.

• 한국환경보건학회지
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• 제35권5호
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• pp.376-385
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• 2009

The characteristics of Lake Cheonhoji water and sediment were investigated in oder to utilize these as fundamental materials for the management of lake water quality. The hydrographic properties of Lake Cheonhoji which are relatively low chance of nutrients loading from the watershed and a long retention time of lake water, lead to the probability of high lake productivity. It was also observed that lake water showed stratification during summer and complete mixing during fall, even though water depth was relatively shallow. The trophic state was eutrophic to hypertrophic from summer to late fall. The overall properties of the sediment were oligohumic, high ignition loss and high composition of NAIP and Resid.-P, which might serve as potential pollution sources of lake water quality. In laboratory scale experiments, it was observed that leaching potential of nutrients in the sediment was greatly dependant upon water temperature and dissolved oxygen. Finally, water pollution in Lake Cheonhoji was considered to be largely due to the adverse cycle of uncontrollable eutrophication, which resulted in the subsequent occurrence of dead algae and animal plankton, organic sedimentation, reduction of dissolved oxygen and nutrients leaching, which again reinforced the cycle of eutrophication in the lake.

• 상하수도학회지
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• 제21권5호
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• pp.631-639
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• 2007

This study investigated the construction and operation status of sewer pipes and water-purifier tanks near densely populated areas like large apartment complexes, in order to find out cause for offensive orders. The study results revealed that the main cause arose from the water-purifier tank and public sewer pipes near ordinary residential areas. First, in case of independent water-purifier tanks, the air is forced into the rotten part of large tanks nearby which should be operated in an anaerobic state, so that the tank changes into an aerobic state, or dirty water, which is returned during the sludge return process, falls on the top of the rotten tank, preventing scum from forming within the tank. Such problems cause incompletely purified water in the purifier tank to be discharged, which in turn results in filthy water. Second, in case of public sewer pipes, deteriorated or aging pipes, or the mixture of rain water and dirty water by mixing up combined and separated sewers system can cause foul odors in residential areas. Therefore, offensive odors in residential areas can be radically reduced through the appropriate construction and management of facilities including water-purifier tanks. As well, if more separate sewers are installed as part of an improvement project for public sewer pipes, complaints about foul smell can be minimized.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2009년도 제33회 추계학술대회논문집
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• pp.42-46
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• 2009

고압 조건에서 작동하는 고성능 액체 로켓 엔진에 대한 이해를 위해 초임계 조건의 스월 인젝터에서 액체 산소의 동적 특성이 수치적으로 연구되었다. 난류 수치 모델은 large eddy simulation을 기반으로 하였으며 보존 방정식과 SRK 상태 방정식, Chung의 기법을 포함하고 있다. 또한 수렴 속도의 증가를 위해 예조건화 기법이 적용되었다. 수치 해석 결과는 이상 기체 상태 방정식을 적용한 결과와 비교 되었으며 인젝터 내부와 연소실에서 액상이 존재하는 영역에서의 상태량과 동적 특성의 차이가 관찰되었다.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2006년도 춘계 학술발표회 논문집
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• pp.352-361
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• 2006

The grouting method is widely used in construction to reduce permeability and reinforce the ground. If the cement and grout material are not mixed well in the injection tip equipment, an opposite flow and Interception state of the chemical grouting can occur. McG method installs a special grouting device to allow better mixing of the grouting material and prevent backward flow. The block of nozzle also diversify powder rate of cement. YSS that lowers $Na_2O$ and thereby increases durability is developed by gel-forming reaction material. In this study, the seepage state and unconfined compressive strength of the injection material using the special injection tip equipment is tested. The results of laboratory and field tests clearly demonstrate that the strength increases and permeability decreases using the McG method.

• 대한기계학회논문집
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• 제19권3호
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• pp.771-783
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• 1995

A simplified model for the so-called ACRT(accelerated crucible rotation technique) Bridgman crystal growth was considered in order to investigate the principal effects of the periodic variation of angular velocity. Numerical solutions were obtained for Ro=0.5, Ra=4.236*10$_{6}$ and E=2.176*10$^{-3}$ . The effects of spin-up process combined with natural convection was investigated as a preliminary study. The spin-up time scale for the present problem was a little larger than that observed for homogeneous spin-up problems. Numerical results reveal that over a time scale of (H$^{2}$/.nu..omega.$_{f}$)$^{1}$2/ the forced convection due to the formation of Ekman layer predominates. When the state of rigid body rotation is attained, natural convection due to buoyancy emerges as the main driving force and them the steady-state is approached asymptotically. Based on our preliminary results with simple spin-up, several fundamental features associated with variation of rotation speed are successfully identified. When a periodic variation of angular velocity was imposed, the system response was also periodic. Due to effect of mixing, the heat transfer was enlarged. From the analysis of time-averaged Nusselt number along the bottom surface the effect of a periodic variation of angular velocity on the interface location could be indirectly identified.d.

• 펄프종이기술
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• 제32권4호
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• pp.41-48
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• 2000

The main objective of this study was to investigate the packing state and optical properties of coated paper prepared with different coating colors by varying the blending ratio of such pigment as clay, $CaCO_3$, and plastic pigment. To evaluate the effect of packing state of pigment on the properties of coated paper, the coating thickness, which was theoretically calculated by specific gravity, and packing volume of pigment were used. It was found that there exists close relationship between the coating thickness and surface property of coated paper. For instance, the macro roughness(smoothness) of coated paper is closely related to bulkiness. Plastic pigments used in this research has a high finishing efficiency on the light weight coatings. Especially, hollow sphere pigment was very effective for improving the property of coated paper produced in this test. And when HSP was blended with $CaCO_3$the surface property such as smoothness and gloss improved significantly.

• 대한화학회지
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• 제11권4호
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• pp.143-149
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• 1967

액체 구조에 관한 천이상태 이론을 벤젠과 사염화탄소의 이성분 액체 혼합물에 적용시켰다. 각 성분의 상태합으로부터 액체 혼합물계의 상태합을 구하고, 이것으로부터 전체압, 부분압, 몰부파, 혼합엔트로피 및 압축율 등의 열역학적 성질을 여러 온도에서 계산하였다. 계산 결과는 문헌에서 얻은 실험값과 근사적으로 일치함을 발견하였다.