• Title/Summary/Keyword: mixed agreement

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Validity for Classifying the Stages of Change among the Dietary Assessment Methods on Eating Fruits and Vegetables for American College Students

  • Chung, Sang-Jin;Sharon L. Hoerr;Ralph Levine;Won O. Song;Gayle Coleman
    • Journal of Community Nutrition
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    • v.4 no.3
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    • pp.143-150
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    • 2002
  • The objective of this study is to establish outcome validity for three instruments that assess whether subjects met recommendations for daily servings of fruits and vegetables for“Stage of Change”research. A convenience sample of 294 college students was recruited from introductory nutrition classes at Michigan State University in the United States. To measure servings of fruits and vegetables, separately, three types of methods (self-rated intake, 24-hour recall and food frequency) were used in comparison to the servings from a three-day food record, the criterion used. The outcome validity was assessed based on whether or not at least two servings of fruits and three servings of vegetables were reported. Validity was assessed by sensitivity, to measure the ability to detect low intakes, and by specificity, to measure ability to detect adequate intakes. Cohen's kappa was used as well to examine the agreement between the three methods and a three-day food record. The results showed, for fruits, the 24-hour recall had the best agreement (recall 0.54, self-rated : 0.31, food frequency : 0.29) with a three-day food record for servings consumed by people in pre-action or post-action stages. Sensitivity for fruit was also best using a recall (0.81). For vegetables, however, all three methods had low agreement (food frequency : 0.27, recall : 0.21, self-rated : 0.17) with the results of the three-day food record. Self-rated intakes for vegetables had the best sensitivity (0.66) and the food frequency had the best specificity (0.73). Therefore, researcher can use the 24-hour recall method to identify people who consume inadequate servings of fruit. To detect adequate vegetable intake, the food frequency was best of the three methods. Accuracy may be improved by probing for vegetables in mixed dishes and on sandwiches. (J Community Nutrition 4(3): 143∼150, 2002)

The Effect of Gas Environment on the Electronic and Optical Properties of Amorphous Indium Zinc Tin Oxide Thin Films

  • Denny, Yus Rama;Lee, Sun-Young;Lee, Kang-Il;Seo, Soon-Joo;Oh, Suhk-Kun;Kang, Hee-Jae;Heo, Sung;Chung, Jae-Gwan;Lee, Jae-Cheol;Tougaard, Seven
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.141-141
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    • 2012
  • The electronic and optical properties of Indium Zinc Tin Oxide (IZTO) thin films using gas environment were investigated by X-ray photoelectron spectroscopy (XPS) and reflection electron energy loss spectroscopy (REELS). REELS spectra revealed that the band gaps of IZTO thin films are 3.26, 3.07, and 3.46 eV for water mixed with oxygen, argon mixed with oxygen, and air environments, respectively. The measured band gaps by REELS are consistent with the optical band gaps obtained by UV-Spectrometer. The optical properties represented by the dielectric function $\mathfrak{m}$, the refractive index n, the extinction coefficient k, and the transmission coefficient T of the IZTO thin films with different gas environments were determined from a quantitative analysis of REELS spectra. The calculated transmission from quantitative analysis of REELS spectra shows good agreement with transmission measured by UV-spectrometer. The transmission values of 89% and low electrical resistivity of $3.55{\times}10^{-3}{\Omega}{\cdot}cm$ have been achieved for argon mixed with oxygen which indicates that the gas enviroment plays an important role in improving the electronic and optical properties of films.

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mPW1PW91 Study of Complexation of Alkali Metal Ions with Mixed [2 + 2'] Calix[4]aryl Derivatives

  • Choe, Jong-In
    • Bulletin of the Korean Chemical Society
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    • v.33 no.10
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    • pp.3321-3330
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    • 2012
  • The complexation characteristics of mixed [2 + 2'] calix[4]aryl derivatives (3 and 4) with alkali metal cations were investigated by the mPW1PW91 (hybrid HF-DF) calculation method. The total electronic and Gibbs free energies of the various complexes (cone, partial-cone, 1,2-alternate, and 1,3-alternate) of sodium and potassium cations with 3 and 4 were analyzed and compared. The structures of the endo- or exo-complexes of the alkali metal cation with the host 3 were optimized using the mPW1PW91/6-31G(d) method, followed by mPW1PW91/6-311+G(d) calculations. The structures of the endo- or exo-complexes of the alkali metal cation with the host 4 were optimized using the mPW1PW91/6-31G(d,p) method. The mPW1PW91 calculated relative energies of the various conformations of the free hosts (3 and 4) suggest that the cone conformers of 3 and 4 are the most stable. The mPW1PW91calculations also suggest that the complexation efficiencies of the sodium ion with hosts 3 and 4 are about 24 and 27 kcal/mol better than those of the potassium ion, respectively. These trends are in good agreement with the experimental results. The exo-complexation efficiencies of the sodium ion toward the conformers of hosts 3 and 4 are roughly 14 and 17 kcal/mol better than those for the endo-$Na^+$-complexes of 3 and 4, respectively. The exo-complexation of the cone isomer of 3 with cation could be confirmed by the differences of the diagnostic C=O bands in the free host and its complex's IR spectra.

Numerical Study of Mixed Convection Nanofluid in Horizontal Tube (수평원형관내 나노유체의 혼합대류에 관한 수치적 연구)

  • Choi, Hoon-Ki;Lim, Yun-Seung
    • Journal of Convergence for Information Technology
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    • v.9 no.8
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    • pp.155-163
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    • 2019
  • Laminar mixed convection of a nanofluid consists of water and $Al_2O_3$ in a horizontal circular tube has been studied numerically. Two-phase mixture model has been used to investigate hydrodynamic and thermal behaviors of the nanofluid with variables physical properties. Three dimensional Navier-Stokes, energy and volume fraction equations have been discretized using the finite volume method. The Brownian motions of nanoparticles have been considered to determine the thermal conductivity and dynamic viscosity of $Al_2O_3$-Water nanofluid, which depend on temperature. The calculated results show good agreement with the previous numerical data. Results show that in a given Reynolds number (Re), increasing solid nanoparticles volume fraction and Richardson number (Ri) increases the convective heat transfer coefficient and wall shear stress.

Investigation of some Natural Product Extracts as Corrosion Inhibitors for Mild Steel in Acid Mediu

  • Subramania, A.;Sathiya Priya, A.R.;Saravanan, S.;Abdul Nasser, A.J.;Vasudevan, T.
    • Corrosion Science and Technology
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    • v.4 no.6
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    • pp.231-235
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    • 2005
  • The inhibitive effect of extracts of tamarind seeds and jackfruit seeds, curry leaves and henna leaves on corrosion of mild steel in 1M HCl solution have been studied by weight loss, potentiodynamic polarization and impedance measurements. Results obtained from the electrochemical techniques were in good agreement with weight loss results. From the weight loss data, the values of surface coverage ($\Theta$) and corrosion rate were calculated. The inhibition efficiency (IE) increased with increasing inhibitor concentration in 1M HCl solution. In all the cases the adsorption of the natural product extracts on the mild steel surface from 1M HCl follows the Langmuir adsorption isotherm relationship. Potentiodynamic polarization studies reveal the fact that all the four natural product extracts act as mixed type inhibitors. The decrease in the inhibition efficiency follows the order: Extracts of jackfruit seed>henna leaves>curry leaves>tamarind seed.

A numerical study of the incompressible flow over a circular cylinder near a plane wall using the Immersed Boundary - Finite Difference Lattice Boltzmann Method (가상경계 유한차분 격자 볼츠만 법을 이용한 평판근처 원형 실린 더 주위의 비압축성 유동에 관한 수치적 연구)

  • Yang, Hui-Ju;Jeong, Hae-Kwon;Kim, Lae-Sung;Ha, Man-Yeong
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2731-2736
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    • 2007
  • In this paper, incompressible flow over a cylinder near a plane wall using the Immersed Boundary. Finite Difference Lattice Boltzmann Method (IB-FDLBM) is implemented. In this present method, FDLBM is mixed with IBM by using the equilibrium velocity. We introduce IBM so that we can easy to simulate bluff-bodies. With this numerical procedure, the flow past a circular cylinder near a wall is simulated. We calculated the flow patterns about various Reynolds numbers and gap ratios between a circular cylinder and plane wall. So these are enabled to observe for vortex shedding. The numerical results are found to be in good agreement with those of previous studies.

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Role of Some Phenylthiourea Derivatives as Corrosion Inhibitors for Carbon Steel in HCl Solution

  • Fouda, Abd El-Aziz El-Sayed;Hussein, Ahmed
    • Journal of the Korean Chemical Society
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    • v.56 no.2
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    • pp.264-273
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    • 2012
  • Five derivatives of phenylthiourea namely: 1-(4-methoxyphenyl)-3-phenylthiourea (1), 1-(4-methylphenyl)-3- phenylthiourea (2), 1-(4-bromophenyl)-3-phenylthiourea (3), 1-(4-chlorophenyl)-3-phenylthiourea (4) and 1-phenylthiourea (5) have been evaluated as new inhibitors for the corrosion of carbon steel in 2 M HCl solution using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques. Potentiodynamic polarization measurements showed that these derivatives are mixed-type inhibitors. The inhibition efficiency was found to increase with inhibitor concentration and decreases with rise in temperature. The thermodynamic parameters of adsorption and activation were determined and discussed. Nyquist plots showed depressed semicircles with their centre below real axis. The adsorption process of studied derivatives on carbon steel surface obeys Temkin adsorption isotherm. The synergistic effect of these derivatives and some anions is discussed from the viewpoint of adsorption models. The electrochemical results are in good agreement with the calculated quantum chemical HOMO and LUMO energies of the tested molecules.

A Study on the Velocity Profiles and Pressure Distributions in Ejector Linking Inhale Duct (흡입관이 부착된 이젝터의 속도분포와 압력분포 연구)

  • Lee Heang-Nam;Park Gil-Moon;Lee Duck-Gu;Sul Jae-Lim
    • Journal of Advanced Marine Engineering and Technology
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    • v.29 no.5
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    • pp.488-494
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    • 2005
  • The ejector is used to obtain a vacuum state, and it has been applied to a lot of industry field such as a heat engine, a fluid instrument power plant. a food industry, an environment industry etc., because there is no problem even it is mixed with any kind of liquid, gas. and solid. The flow characteristics in the ejector was investigated by a PIV and a CFD. The agreement between numerical analysis and experiment shows the validity of this study and the results of this study would be useful to the engineers who design for the flow systems for heating. ventilation. air conditioning and wastewater purification plants.

HELIOS Verification Against High Plutonium Content Pressurized Water Reactor Critical Experiments

  • Kim, Taek-Kyum;Joo, Hyung-Kook;Jung, Hyung-Guk;Kim, Young-Jin
    • Proceedings of the Korean Nuclear Society Conference
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    • 1997.05a
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    • pp.15-20
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    • 1997
  • We present the results HELIOS verification against VENUS PWR critical experiments loaded with high plutonium content mixed oxides fuels. The effective multiplication factors are calculated to be slightly supercritical within an acceptable error bound. In the prediction of power shape, HELIOS results are in close agreement with the measured values. The RMS errors of re-normalized calculated fission rate distribution are less than 1.4 % with either explicit or implicit models or micro tubes/rods in each fuel assembly for both ALL-MOX and GD-MOX mock-up cores.

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A Study on the Characteristics of Flammability for Organic Solvents of Three Component Systems (3성분계 유기용제의 인화특성에 관한 연구)

  • 임우섭;목연수;최재욱;최일곤;하동명;조태제
    • Journal of the Korean Society of Safety
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    • v.14 no.3
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    • pp.120-126
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    • 1999
  • This study was accomplished by measuring the lower and upper flash point with air blowing method and grasping the characteristics of flammability for the three component systems, which are made up of the Benzene-Toluene-o-Xylene and Methylethylketone-Toluene-o-Xylene. These three component systems are widely used in the various industrial fields together with the development of industry. The results are as follows ; 1 ) Isothermal line is plotted on the triangular diagram for flash points determined in each solutions. From this line, the mixed compositions which indicated the same lower and upper flash points in each different composition could be read on this diagram, if the composition of mixtures are known. 2) Lower and upper explosion limits obtained from the flash points determined for the three component solution are compared with the value calculated from Le Chatelier's law. Especially the lower explosion limits are in a good agreement with the calculated values.

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