• Title/Summary/Keyword: minCD

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Characteristics of Se/CdS Heterojunction Fabricated by EBE Method (EBE법으로 제작한 Se/CdS 이종접합의 특성)

  • Park, Gye-Choon;Cho, Jae-Cheol;Yoo, Yong-Tek
    • Journal of Sensor Science and Technology
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    • v.2 no.1
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    • pp.87-94
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    • 1993
  • CdS and Se thin films were deposited on slide glass by EBE method respectively and surface morphology, crystal structure, electrical and optical properties were investigated by substrate temperature and annealing. The deposited CdS film was well fabricated with cubic structure at substrate temperature of $150^{\circ}C$. Se film was deposited with noncrystal structure until substrate temperature of $100^{\circ}C$, but Se film was grown with monoclinic structure at substrate temperature of $150^{\circ}C$. And so, after annealing at $150^{\circ}C$ for 15min, noncrystalline Se was proved to be hexagonal structure. Finally, the maximum output of Se/CdS heterojunction at 5000 lux was 4 $mW/cm^{2}$ and maximum spectral sensitivity was represented at 585nm.

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Electro-optical properties of organic EL device (유기 EL 소자의 전기-광학적 특성)

  • Kim, Min-Soo;Park, Lee-Soon;Park, Se-Kwang
    • Journal of Sensor Science and Technology
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    • v.6 no.4
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    • pp.252-257
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    • 1997
  • Organic EL devices, which have the sing3e-layer structure of ITO(indium-tin-oxide) /PPV(poly(p-phenylene vinylene))/cathode and the double-layer structure of ITO/PVK (poly(N- vinylcarbazole)) /PPV/cathode, were fabricated and their electro-optical properties were investigated. Experimental results, in single-layer structure, shown that the increment of temperature for thermal conversion of PPV film from $140^{\circ}C$ to $260^{\circ}C$ decreases the maximum luminance from $118.8\;cd/m^{2}$(20V) to $21.14\;cd/m^{2}$(28V) and shift the maximum peak of EL spectrum from 500nm to 580nm. The lower the work function of cathode is, the more the luminance and injection current of device. In double-layer structure, as the concentration of PVK solution decreases from 0.5 wt% to 0.05 wt%, the luminance of device increases from $70.71\;cd/m^{2}$(32V) to $152.7\;cd/m^{2}$(26V).

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A Study on the Cementation Reaction of Cadmium by Zinc Powders from Leaching Solution of Waste Nickel-Cadmium Batteries (폐니켈-카드뮴 전지 침출액으로부터 아연 분말을 이용한 카드뮴의 치환반응에 대한 연구)

  • Kim, Min-Jun;Park, Il-Jeong;Kim, Dae-Weon;Jung, Hang-Chul
    • Resources Recycling
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    • v.28 no.1
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    • pp.23-31
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    • 2019
  • Cementation is one of economical and efficient recycling method precipitating the metal ion in solution by adding another active metal. In this study for optimizing cadmium recovery efficiency, it was performed as a function of the effect of pH, temperature, particle size, and input amount of zinc in 0.1 M $CdSO_4$ solution and Ni-Cd battery leaching solutions, respectively. The particle size of zinc and temperature were key factors for Cd cementation and it was confirmed that the input amount of 2.6 of Zn/Cd ratio using granular-type zinc was optimal condition for selective Cd recovery efficiency at $25^{\circ}C$.

Fabrication and Evaluation of CdS/ZnS Quantum Dot Based Plastic Scintillator (CdS/ZnS 양자점 기반 플라스틱 섬광체 제작 및 성능평가)

  • Min, Su Jung;Kang, Ha Ra;Lee, Byung Chae;Seo, Bum Kyung;Cheong, Jae Hak;Roh, Changhyun;Hong, Sang Bum
    • Korean Chemical Engineering Research
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    • v.59 no.3
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    • pp.450-454
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    • 2021
  • Currently, gamma nuclide analysis is mainly used using inorganic scintillators or semiconductor detectors. These detectors have high resolution but there are less economical, limited in size, and low process ability than plastic scintillators. Therefore, quantum dot-based plastic scintillator was developed using the advantages of the quantum dot nanomaterial and the conventional plastic scintillator. In this study, efficient plastic scintillator was fabricated by adding CdS/ZnS based on the most widely used Cd-based nanomaterial in a polystyrene matrix. In addition, the performance of the commercial plastic scintillator was compared and it was analyzed through radiological measurement experiments. The detection efficiency of fabricated plastic scintillator was higher than commercial plastic scintillator, EJ-200. It is believed that this fabricated plastic scintillator can be used as a radioactivity analyzer in the medical and nuclear facility fields.

Treatability of Heavy Metals in the Washing Technology of Marine Sediments Contaminated with Organic Matter (세척기반처리에 의한 해양오염퇴적물에 함유된 유기 오염물질 제거 공정 중 중금속 처리 가능성)

  • Sim, Young Sub;Kim, Kyoung Rean;Kim, Suk Hyun
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.12
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    • pp.851-857
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    • 2014
  • Treatability of heavy metals in marine sediments contaminated with mainly organic matter was investigated on the basis of washing technology using oxidizers and surfactants. Sediment samples were collected at N area which expected for remediation project of contaminated marine sediment. For additives, hydrogen peroxide ($H_2O_2$) and Tween-80 were used at oxidizer and nonionic surfactant, respectively. In experiments, sediments was mixed with sea water at the ratio of 1 : 3 than $H_2O_2$ (1 M, 3 M, 4 M, 5 M) and Tween-80 (0.05%) were added. Samples were gathered at following reaction time (10, 20, 30, 40, 50, 60, 70, 80 min and 24 h). Total Organic Carbon (TOC) was 55.2% at the conditions of 5 M $H_2O_2+0.05%$ Tween-80 24 h. Hence total heavy metals were Cu 29.5%, Zn 42.3%, Cd 73.0% and bioavailable heavy metals were Cu 60.0%, Zn 77.7%, Cd 90.2% at the conditions of 5 M $H_2O_2+0.05%$ Tween-80 10 min. The correlations for between bioavailable metals (Cu, Zn, Cd) and TOC were significant (Cu, Zn, Cd; $r^2=0.94$, 0.85, 0.69, respectively).

A Study on the Removal of Heavy Metals by Microorganism in the Biological Wastewater Treatment (생물학적 폐수처리 공정에서의 미생물에 의한 중금속 제거에 관한 연구)

  • Choung, Youn Kyoo;Min, Byeong Heon;Park, Joon Hwon
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.10 no.2
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    • pp.137-145
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    • 1990
  • In this research, biological uptake of heavy metals(Cd(II), Cu(II), Zn(II)) was measured under various conditions ; pH, initial heavy metal concentration, temperature, contact time and the amount of biomass through batch test. From this research, it was found that heavy metals might be removed through adsorption and accumulation in activated sludge process. Heavy metals were highly concentrated by microbial floc in activated sludge. Also, the removal efficiency was reached up to 80~90% within and after 1 hour the increase of removal efficiency was minimal. The order of accumulation efficiency was Cu(II)>Zn(II)>Cd(II), and the bonding strength between heavy metals and microbial floc may be expressed in order of Cu(II)>Zn(II)>Cd(II).

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The protective effect of anti-oxidant in cadmium-induced hair cell death

  • Kim, Su-Jin;Myung, No-Yil;Jeong, Hyun-Ja;Um, Jae-Young;Kim, Hyung-Min;Hong, Seung-Heon
    • Advances in Traditional Medicine
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    • v.9 no.4
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    • pp.285-291
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    • 2009
  • Cadmium ($Cd^{2+}$) is a heavy metal and a potent carcinogen implicated in tumor development through occupational and environmental exposure. However, the auditory effect of $Cd^{2+}$ is not poorly understood. The purpose of the present study was to investigate whether prevent the ototoxic effects of $Cd^{2+}$ by antioxidnat in auditory cell line, HEI-OC1. Rosmarinic acid is a naturally occurring phenolic compound and also known to possess marked antioxidant properties. We showed that antioxidnat inhibited the the cytochrome c release induced by $Cd^{2+}$. In addition, we showed that the regulatory effect of antioxidnat on apoptosis is through the caspase-9 activation, and extracellular signal-regulated kinase activation in auditory cells. These results suggested antioxidnat its therapeutic usefulness, against $Cd^{2+}$ induced activation of caspase-9 and ERK.

Preparation of CdS-AC/TiO2 Composites Designed for a High Photonic Effect and their Photocatalytic Activity Under Visible Light

  • Park, Chong-Yeon;Choi, Jong-Geun;Ghosh, Trisha;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.48 no.5
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    • pp.433-438
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    • 2011
  • In this study, CdS combined activated carbon/$TiO_2$ (CdS-AC/$TiO_2$) composites were prepared by a sol-gel method to improve the photocatalytic performance of $TiO_2$. These composites were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX) and UV-vis analysis. The photocatalytic activities were examined by the degradation of methylene blue (MB) under visible light irradiation. The photodegradation rate of MB under visible light irradiation reached 90.1% in 120 min. The kinetics of MB degradation was plotted alongside the values calculated from the Langmuir-Hinshelwood equation. The 0.2 CAT sample showed the best photocatalytic activity, which might be due to an increase in the photo-absorption effect by activated carbon and the cooperative effect of CdS.

Induction of Oxidative Stress and Cytoskeleton Damage by Cadmium in WB-F344 Rat Liver Epithelial Cells (랫드간장상피세포에서 카드뮴에 의한 산화적 스트레스 및 Cytoskeleton 손상 유발에 관한 연구)

  • 정상희;조명행;조준형
    • Toxicological Research
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    • v.14 no.4
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    • pp.577-585
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    • 1998
  • Cadmium is an important industrial and environmental pollutant and has adverse effects on cell growth and metabolism, although the mechanisms of its cellular toxicity are still unclear. This study was performed to elucidate the cytotoxic mechanism of cadmium in the viewpoint of oxidative stress and cytoskeleton alterations in WB-F344 rat liver epithelial cells. 200 $\mu\textrm{M}$ $CdCl_2$ caused a severe disassembling of microtubule and micro filament and an apparent cell retraction under an observation with fluorescence micoscope. (equation omitted)-tubulin and F-actin protein were highly thiolated at 20 min and then disappeared from 1 hour after the treatment of 200 $\mu$M CdCl$_2$in the immunoblot analysis. Intracellular GSH was decreased from 1hr to 24 hrs by 66.6 or 200 $\mu\textrm{M}$ of $CdCl_2$. Intracellular protein thiol was also decreased by 22.2, 66.6 and 200 $\mu\textrm{M}$ of $CdCl_2$ at 1 hour after its treatment. The product of lipid peroxidation (malondialdehyde) was increased from 4 hrs by 66.6 and 200$\mu\textrm{M}$ of $CdCl_2$. These data indicate that cadmium induces oxidative stress involving disassembling of microtubule and micro filament, thiolation of (equation omitted)-tubulin and actin protein, depletion of GSH and protein thiol, and increase of lipid peroxidation.

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Optical and structural properties of Al-doped CdZnO thin films with different Al concentrations (Al 도핑 농도에 따른 Al-doped Cd0.5Zn0.5O 박막의 광학적·구조적 특성)

  • Park, Hyeong-Gil;Nam, Gi-Ung;Yun, Hyeon-Sik;Kim, So-A-Ram;Kim, Min-Su;Im, Jae-Yeong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.05a
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    • pp.245-246
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    • 2012
  • Al 농도를 0 부터 2 at.% 까지 조절하여 도핑된 $Cd_{0.5}Zn_{0.5}O$ 박막을 석영 기판 위에 성장하였다. Al 도핑된 $Cd_{0.5}Zn_{0.5}O$ 박막의 구조적, 광학적 특성을 조사하기 위해 field-emission scanning electron microscopy, X-ray diffraction (XRD), photoluminescence (PL), 그리고 ultraviolet-visible (UV) spectroscopy을 사용하였다. 광학적 밴드갭은 Al 도핑 농도가 증가함에 따라 2.874 (0 at.%), 2.874 (0.5 at.%), 3.029 (1.0 at.%), 3.038 (1.5 at.%), 3.081 eV (2.0 at.%)로 증가하였다. Urbach energy는 도핑 농도에 따라 각각 464 (0 at.%), 585 (0.5 at.%), 571 (1.0 at.%), 600 (1.5 at.%), 470 meV (2.0 at.%)이었다. 또한, Al 농도가 증가함에 따라 $Cd_{0.5}Zn_{0.5}O$ 박막의 표면, 구조적 및 광학적 특성이 크게 변화되었다.

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