• Journal of Powder Materials
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• v.27 no.4
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• pp.311-317
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• 2020

In this study, the effects of Co content on the microstructure and Charpy impact properties of Fe-Cr-W ferritic/martensitic oxide dispersion strengthened (F/M ODS) steels are investigated. F/M ODS steels with 0-5 wt% Co are fabricated by mechanical alloying, followed by hot isostatic pressing, hot-rolling, and normalizing/tempering heat treatment. All the steels commonly exhibit two-phase microstructures consisting of ferrite and tempered martensite. The volume fraction of ferrite increases with the increase in the Co content, since the Co element considerably lowers the hardenability of the F/M ODS steel. Despite the lowest volume fraction of tempered martensite, the F/M ODS steel with 5 wt% Co shows the highest micro-Vickers hardness, owing to the solid solution-hardening effect of the alloyed Co. The high hardness of the steel improves the resistance to fracture initiation, thereby resulting in the enhanced fracture initiation energy in a Charpy impact test at - 40℃. Furthermore, the addition of Co suppresses the formation of coarse oxide inclusions in the F/M ODS steel, while simultaneously providing a high resistance to fracture propagation. Owing to these combined effects of Co, the Charpy impact energy of the F/M ODS steel increases gradually with the increase in the Co content.

• Journal of Korea Foundry Society
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• v.17 no.4
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• pp.356-364
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• 1997

In order to study effects of Cu and Be on the microstructure and tensile properties of rapidly solidified Al-Mg alloys, Al-Mg-Cu-Be alloys have been rapidly solidified by inert gas atomization process. Microstructure of rapidly solidified Al-Mg-Cu-Be powders exhibited refinement and good dispersion of Be particles as increasing of solidification rate. Solidification rate of atomized powders was estimated to be about $5{\times}10^{3{\circ}}C/s$. Inert gas atomized Al-Mg-Cu-Be powders were hot-processed by vacuum hot pressing at $450^{\circ}C$ under 100 MPa and hot extruded with reduction ratio in area of 25: 1 at $450^{\circ}C$. The extruded Al-Mg-Cu-Be powders consisted of recrystallized fine Al grains and homogeneously dispersed fine Be particles, and exhibited improved tensile properties with increase in Cu content. $Al_2CuMg$ compounds precipitated in grain and grain boundaries of Al-Mg-Cu-Be alloys with aging heat treatment after solution treatment. Hardness and tensile properties were improved by increasing Cu content and Be addition. Compared with extruded Al-Mg-Cu powders, the extruded Al-Mg-Cu-Be powders exhibited finer recrystallized grains and improved tensile properties by dispersion hardening of Be and subgrain boundaries pinned by fine Be particles. After aging treatment, hardness and tensile properties were improved due to restricted precipitation by increasing of dislocation density around Be particles in matrix.

• Journal of the Korean institute of surface engineering
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• v.38 no.3
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• pp.100-105
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• 2005

Cr-Si-C-N coatings were deposited on steel substrate (SKD 11) by a hybrid system of arc ion plating (AIP) and sputtering techniques. From XRD, XPS, and HRTEM analyses, it was found that Cr-Si-C-N had a fine composite microstructure comprising nano-sized crystallites of Cr(C, N) well distributed in the amorphous phase of $Si_3N_4/SiC$ mixture. Microhardness of Cr(C, N) coatings and Cr-Si-N coatings were reported about $\~22 GPa$ and $\~35 GPa$, respectively. As the Si was incorporated into Cr(C, N) coatings, The Cr-Si-C-N coatings having a Si content of $9.2 at.\%$ showed the maximum hardness value. As increased beyond Si content of $9.2 at.\%$, the interaction between nanocrystallites and amorphous phase was gone, the hardness was reduced as dependent on amorphous phase of $Si_3N_4/SiC$. In addition, the average coefficient of Cr-Si-C-N coatings largely decreased compared with Cr(C, N) coatings.

• Journal of Korea Foundry Society
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• v.39 no.2
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• pp.21-25
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• 2019

Microstructural and corresponding hardness changes of TiFe compounds with Zr (0~6 at%) or Ce (0~3 at%) were studied using samples prepared at different solidification rates. In arc-melted (TiFe)-Zr samples, the $Fe_{23}$ $Zr_6$ and $(Ti,\;Zr)_2Fe$ phases formed in the TiFe matrix, while in the (TiFe)-Ce sample, the $CeO_2$ phase formed along the grain boundary of the TiFe matrix. As the Zr content was increased, the volume fractions of the $Fe_{23}$ $Zr_6$ and $(Ti,\;Zr)_2Fe$ phases increased, forming a network structure. Accordingly, the hardness values of the samples also increased. With a small addition of Ce of approximately 0.1 at%, the as-cast microstructure could be effectively refined, reducing the average grain boundary diameter from ${\sim}100{\mu}m$ to ${\sim}14{\mu}m$. In the rapidly solidified sample prepared through a melt-spinning method, the constituent phases were identical to those of the arc-melted samples while the grains were refined. The microstructural changes of TiFe alloys can affect the hydrogen storage ability as well as the mobility of the hydrogen atoms in the alloys.

• Korean Journal of Materials Research
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• v.29 no.4
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• pp.211-220
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• 2019

In this study, three kinds of bainitic steel plates are manufactured by varying the chemical compositions and their microstructures are analyzed. Tensile and Charpy impact tests are performed at room and low temperature to investigate the correlation between microstructure and mechanical properties. In addition, heat affected zone (HAZ) specimens are fabricated by a simulation of welding processes, and the HAZ microstructure is analyzed. The base steel that has the lowest carbon equivalent has the highest volume fraction of acicular ferrite and the lowest volume fraction of secondary phases, so the strength is the lowest and the elongation is the highest. The Mo steel has a higher volume fraction of granular bainite and more secondary phases than the base steel, so the strength is high and the elongation is low. The CrNi steel has the highest volume fraction of the secondary phases, so the strength is the highest and elongation is the lowest. The tensile properties of the steels, namely, strength and elongation, have a linear correlation with the volume fraction of secondary phases. The Mo steel has the lowest Charpy impact energy at $-80^{\circ}C$ because of coarse granular bainite. In the Base-HAZ and Mo-HAZ specimens, the hardness increases as the volume fraction of martensite-austenite constituents increases. In the CrNi-HAZ specimen, however, hardness increases as the volume fraction of martensite and bainitic ferrite increases.

• Korean Journal of Metals and Materials
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• v.50 no.10
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• pp.735-743
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• 2012

The aim of this study was to analyze the effect of the cooling rate after heat treatment on the microstructure and mechanical properties of 2507 duplex stainless steels. Heat treatment was carried out at $1050^{\circ}C$ for 1 hr, followed by controlled cooling. The cooling rates were $175.6{\times}10^{-3}^{\circ}C/s$, $47.8{\times}10^{-3}^{\circ}C/s$, $33.3{\times}10^{-3}^{\circ}C/s$, $16.7{\times}10^{-3}^{\circ}C/s$, $11.7{\times}10^{-3}^{\circ}C/s$, $5.8{\times}10^{-3}^{\circ}C/s$ and $2.8{\times}10^{-3}^{\circ}C/s$, which resulted in variations of the microstructure, such as the fractional change of the ferrite phase and sigma phase formation. Fatigue, hardness, impact and tensile tests were performed on the specimens with different cooling rates. The precipitation of the ${\sigma}$ phase caused a hardness increase and a sharp decrease of toughness and tensile elongation. The fatigue limit of the sample with a cooling rate of $5.8{\times}10^{-3}^{\circ}C/s$ was 26 MPa higher than that of the sample with a cooling rate of $175.6{\times}10^{-3}^{\circ}C/s$. Our observations of the fracture surface confirmed that the higher fatigue resistance of the specimen with a cooling rate of $5.8{\times}10^{-3}^{\circ}C/s$ was caused by the delay of the fatigue crack growth, in addition to higher yield strength.

• 보존과학연구
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• s.22
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• pp.115-132
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• 2001

No. 3 Tomb of Bogam-ri, in Naju City, Chollanam-do Province, was a site excavated and inspected from 1996 to 1998 and had a various grave forms, including jar-coffins, stone-chambers and stone-cists. Although most of the metal artifacts excavated from it were severely corroded, we could implement microstructure investigation by collecting samples from the iron axes, iron coffin-nails and iron clamps in which the metal parts were remained. The metal structures were inspected by using metallographic microscope and SEM, and fine components analysis was implemented by ICP. To examine the hardness differences in accordance with the structure distribution, we measured the hardness by structures with Vickers hardness testing machine. As a result of the metal structure inspection, most of them were pure iron, ferrite, and also pearlite, cementite and widmannstaten structures were displayed. We could confirm carbonization was formed on the surface of the iron axes-B, iron coffin-nails-B, and iron clamps-A. There was no carbonization in the rest of the artifacts, and it is not certain that whether the carbonized parts were peeled off through extreme corrosion or they were not carbonized when they were made. In the particular part of a blade, the quality of the material was strengthened through processing. Due to the processing re-grain was caused and fine grain particles were formed. As a result of the ICP component analysis, there were no addition atoms because pure irons were used as materials. In the mean time, No. 17 jar-coffin where the iron axes-A are excavated, is chronologically ordered as from the late-fourth century to the mid-fifth century, and No. 1 and No. 2 stone chambers, where the rest of the artifacts were excavated, as the early-sixth century. It was difficult to relate the periodic differences with the manufacture technique artifacts which we inspected because there were no distinct characteristics of the manufacture technique of the metal structures and it is impossible to conclude the artifacts and sites are at the same period although their periods are different.

• Transactions of the Korean Society of Machine Tool Engineers
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• v.15 no.1
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• pp.63-69
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• 2006

This study deals with the friction welding of A2024- T6 to A6061- T6; The friction time was variable conditions under the conditions of spindle revolution of 2000rpm, friction pressure of 50MPa, upset pressure of 100MPa, and upset time of 5.0seconds. Under these conditions, the microstructure of weld interface, tensile fracture surface and mechanical tests were studied, of friction weld, and so the results were as follows. 1. When the friction time was 1.5seconds under the conditions, the maximum tensile strength of the friction weld happened to be 292MPa, which is $94.2\%$ of the base material's tensile strength(310MPa). At the same condition, the maximum shear strength was 2l2MPa, which is equivalent to $103\%$ of the base material's shear strength (205MPa). 2. At the same condition, the maximum vickers hardness was Hv 146 at A2024- T6 nearby weld interface, which is higher Hv3 than condition of the friction time 0.5seconds, and the maximum vickers hardness was Hvl20 from weld interface of A6061-T6, which is higher Hv28 then base material's. 3. The results of microstructure analysis show that the structures of two base materials have fractionized and rearranged along a column due to heating and axial force during friction, which has affected in raising hardness and tensile strength.

• Transactions of the Korean Society of Mechanical Engineers
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• v.16 no.10
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• pp.1861-1868
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• 1992

Laser beam hardening of 12%-Cr steel has been evaluated by using a continuous wave 3kW co$_{2}$ laser with a hardening mirror set. Experiment was performed on the hardening condition with a laser power of 2.85kW and travel speed of 1.0 and 1.5m/min. Multi passes have been also tried to find the hardening characteristics of partly overlapped zone. The black paint to use at high temperature was adopted to increase the absorptivity of laser beam energy with the wavelength of 10.6.mu.m at the surface of base metal. The microstructure of the hardened layers was observed by using a light microscopy, SEM and TEM. A fine Lamellar martensite formed in the hardened zones exhibits very high Vickers microhardness of 600Hv, whereas the tempered martensite distributes in the base metal with Vickers microhardness of 240Hv.It has been found that laser hardening with multi passes showed no significant drop of the hardness between adjacent passes.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.94-94
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• 2013

The Cr-Zr-N films have much improved mechanical properties and very smooth surface roughness. However, in spite of their outstanding properties, the Cr-Zr-N coatings revealed their mechanical properties deteriorated severely with increasing Zr content at $500^{\circ}C$ ecause of very rapid oxidation. Recently oxynitride films have been widely studied due to their excellent unique mechanical properties and oxidation resistance. In this work, CrZr-O-N films with various O contents were synthesized by unbalanced magnetron sputtering with Cr-Zr segment targets (Cr:Zr volume ratios is 1：1) and all films were prepared in a nitrogen rich mixture of N2 and O2. Characteristics such as crystalline structure, hardness and chemical composition as a function of the O content were investigated by X-ray diffraction (XRD), field emission scanning electron microscope (FE-SEM), microhardness testing system and energy dispersive spectroscopy (EDS). Results showed that the thin films had dense and compact microstructure as O content in the films increases. The microstructure of the thin films consisted of mainly crystalline Cr (Zr)N phase and Cr2O3 phase. The maximum hardness and elastic modulus of the films was measured to be approximately 33.2 GPa and 280.6 GPa from the films with low content of O elements. Detailed experimental results will be presented.