• 제목/요약/키워드: microscopic analysis

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새로운 수용성 하이드레이트 시스템에 대한 미세 분광학적 분석연구 (Microscopic Analysis on New Water-soluble Hydrate Systems)

  • 이종원
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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    • pp.215.1-215.1
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    • 2010
  • 가스 하이드레이트는 작은 고체 부피 내에 막대한 양의 가스를 저장할 수 있다는 특성으로 인하여, 최근 천연가스 혹은 메탄의 저장 매체로 활용하기 위한 연구가 활발히 진행중에 있다. 하지만 실제 응용을 위해서는 미세구조 분석이 수행되어 하이드레이트 형태로 저장할 수 있는 정확한 저장 용량을 파악할 필요가 있다. 본 연구에서는 여러가지의 고리형 에테르, 고리형 에스테르 및 고리형 케톤 화합물들을 테스트하여 메탄 가스와 반응하는 6가지의 새로운 sII 혹은 sH 하이드레이트 형성제를 파악하였다. 또한 새로이 발견된 형성제 모두에 대하여 하이드레이트 상평형도 측정하였다. 얻어진 상평형 데이터는 하이드레이트 안정영역과 게스트 분자 크기 간에 뚜렷한 상관관계가 있음을 입증하였다. 아울러 형성된 하이드레이트 샘플은 고체 분말 X-선 회절과 고체상 13C NMR 분석을 수행하여 하이드레이트 구조와 게스트 포집률을 조사하였다. 마지막으로, 비슷한 화학 구조식을 갖고 있음에도 2-methyltetrahydrofuran과 3-methyltetrahydrofuran, 혹은 4-methyl-1,3-dioxane과 4-methyl-1,3-dioxolane은 서로 다른 하이드레이트 결정 구조를 보여 주었는데, 이러한 차이는 하이드레이트 결정 구조를 결정짓는 게스트 분자 크기, 즉 임계 게스트 분자 크기를 파악하는 데에도 매우 유용한 정보를 제공할 수 있을 것이라 판단된다.

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The effects of Graphene Oxide flakes on the mechanical properties of cement mortar

  • Kim, Boksun;Taylor, Lawrence;Troy, Andrew;McArthur, Matthew;Ptaszynska, Monika
    • Computers and Concrete
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    • 제21권3호
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    • pp.261-267
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    • 2018
  • This paper discusses a study of cement mortar reinforced with Graphene Oxide (GO) flakes carried out at the University of Plymouth. Over 60 specimens were prepared and tested to obtain the tensile, compressive and flexural strengths of cement mortar with/without 0.5% GO flakes by weight of cement. The dispersion of the GO flakes and the effect of the use of polycarboxylate ether superplasticizer (0.2% by weight of cement) on the material strength are discussed. Images of the particle sizes of GO are presented from the transmission electron microscopy analysis. In addition, the images from the field emission scanning electron microscope analysis are also presented to show the difference of the microscopic structure of cement mortar with/without GO. The results of the strength tests are presented. It is shown that the inclusion of the GO flakes in general led to positive results, which suggest that GO improved the tensile, compressive and flexural strengths of cement mortar.

섬유 보강 복합재료의 미시역학적 거동 해석 (Analysis of Micromechanical Behavior for Fiber-Reinforced Composites)

  • 정재연;하성규
    • 대한기계학회논문집A
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    • 제28권10호
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    • pp.1435-1450
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    • 2004
  • The investigation, which includes the material homogenization and the calculation of local stress concentration of long-fibrous composites in a microscopic level, has been performed to analyze the behavior of fiber-reinforced composites by using finite element method. In order to carry out this study, the finite element models of composites have been generated by the idealized arrays as square and hexagonal-packed type. In the FE analysis, the boundary conditions of micromechanical finite element method(MFEM) have been defined and verified by comparing with the results from multi-cells, and the effective material properties of composites composed of graphite/epoxy have been also evaluated by rules of mixture. For acquiring the relation between the global and local behaviors of composites, the magnifications of strain, stress, and interfacial stress of composites subjected to a longitudinal and transverse loading respectively have been calculated. And the magnifications have been proposed as the stress concentration in the microscopic level at composite material.

주라기 화강암에 발달하는 결의 현미경학적 분석 (Microscopic Analysis of the Rock Cleavage for Jurassic Granite in Korea)

  • 박덕원;서용석;정교철;김영기
    • 지질공학
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    • 제11권1호
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    • pp.51-62
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    • 2001
  • 본 연구에서는 포천, 거창, 합천 지역에 분포하는 주라기 화강암의 결의 특성을 분석하기 위하여 결을 따라 제작된 박편의 편광현미경 관찰을 수행하였다. 또한 조사선법을 이용하여 미세균열의 방향성, 길이 및 간격을 측정하였다. 그 결과를 보면 석영과 장석 내에 분포하는 미세균열의 선택적 방향성이 결의 방향과 일치하고 있으며, 균열의 길이는 화강암을 구성하는 광물의 입자가 클수록 크게 나타났다. 또한 선택적 배향성을 보이는 미세균열은 rift, grain, hardway 면 순으로 발생빈도, 길이 및 밀도가 잘 발달되어 있다.

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Alloy 617 확산용접재의 고온 인장강도 (High-Temperature Tensile Strengths of Alloy 617 Diffusion Weldment)

  • 사인진;황종배;김응선
    • 한국압력기기공학회 논문집
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    • 제14권1호
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    • pp.15-23
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    • 2018
  • A compact heat exchanger is one of critical components in a very high temperature gas-cooled reactor (VHTR). Alloy 617 (Ni-Cr-Co-Mo) is considered as one of leading candidates for this application due to its excellent thermal stability and strengths in anticipated operating conditions. On the basis of current ASME code requirements, sixty sheets of this alloy are prepared for diffusion welding, which is the key technology to have a reliable compact heat exchanger. Optical microscopic analysis show that there are no cracks, incomplete bond, and porosity at/near the interface of diffusion weldment, but Cr-rich carbides and Al-rich oxides are identified through high resolution electron microscopic analysis. In high-temperature tensile testing, superior yield strengths of the diffusion weldment compared to the code requirement are obtained up to 1223 K ($950^{\circ}C$). However, both tensile strength and ductility drop rapidly at higher temperature due to the insufficient grain boundary migration across the interface of diffusion weldment. Best fit curves for minimum yield strength and average tensile strength are drawn from the experimental tensile results of this study.

Clinical and scanning electron microscopic analysis of fractured dental implants: a retrospective clinical analysis

  • Kwon, Kyung-Hwan;Sim, Kyu-Bong;Cha, Jae-Won;Kim, Eun-Ja;Lee, Jae-Min
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • 제38권6호
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    • pp.371-378
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    • 2012
  • Many longitudinal studies have reported the successful osseointegration of dental implants, with survival rates approaching 90-95%. However, implants regarded as a "success" may have also failed to undergo osseointegration. A variety of complications and failures have been observed, including implant fracture - a rare and delayed biomechanical complication with serious clinical outcomes. Given the increasing popularity of dental implants, an increase in the number of failures due to late fractures is expected. This study sought to determine the rate of implant fractures and factors associated with its development. This retrospective evaluation analyzed implants placed at Wonkwang Dental Hospital (from 1996 to the present). In our study we found that the frequency of dental implant fractures was very low (0.23%, 8 implant fractures out of 3,500 implants placed). All observed fractures were associated with hybrid-surface threaded implants (with diameter of 4.0 or 3.75 mm). Prosthetic or abutment screw loosening preceded implant fracture in a majority of these cases.

Mini-pig 하악골에서 저강도진동초음파가 골형성에 미치는 영향 (The Effect of Low-intensity Pulsed Ultrasound on Osteogenesis in Mini-pig Mandibles)

  • 윤영은;이준;민승기;김상중
    • Maxillofacial Plastic and Reconstructive Surgery
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    • 제33권6호
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    • pp.467-477
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    • 2011
  • Purpose: The objective of this study was to examine the affected period and the amount of bone formation during osteogenesis of intramembranous bone using low-intensity pulsed ultrasound (LPUS) $in$ $vivo$. Methods: Xeno-bone (Bio-oss) and autogenous bone were grafted bilaterally into mini-pig mandibles. The left mandible served as the control and the other mandible was treated with 3 MHz, 160 mW (output, 0.8 mW) ultrasound stimulation for 7 days 15 minutes per day. The mini-pigs were sacrificed at 1, 2, 4, and 8 weeks, and micro computed tomography (${\mu}CT$), a microscopic examination, and a statistical analysis were performed on the specimens. Results: Based on a computerized image analysis of the ${\mu}CT$ scans, the experimental group had an average 150% more new bone formation than that in the control group. The effect of LPUS continued during the post operative 2 weeks. The histomorphological microscopic examination showed similar results. Conclusion: Our results suggest the LPUS had an effect on early intramembranous bone formation in vivo.

역확산을 고려한 이원합금의 비평형 수지상응고 해석 (Analysis on the non-equilibrium dendritic solidification of a binary alloy with back diffusion)

  • 정재동;유호선;이준식
    • 대한기계학회논문집B
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    • 제20권10호
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    • pp.3361-3370
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    • 1996
  • Micro-Macro approach is conducted for the mixture solidification to handle the closely linked phenomena of microscopic solute redistribution and macroscopic solidification behavior. For this purpose, present work combines the efficiency of mixture theory for macro part and the capability of microscopic analysis of two-phase model for micro part. The micro part of present study is verified by comparison with experiment of Al-4.9 mass% Cu alloy. The effect of back diffusion on the macroscopic variables such as temperature and liquid concentration, is appreciable. The effect, however, is considerable on the mixture concentration and eutectic fraction which are indices of macro and micro segregation, respectively. According to the diffusion time, the behavior near the cooling wall where relatively rapid solidification permits short solutal diffusion time, approaches Scheil equation limit and inner part approaches lever rule limit.

Bacterial Surface Display of $GFP_{UV}$ on Bacillus subtilis Spores

  • Kim, Jung-Hyung;Roh, Chang-Hyun;Lee, Chang-Won;Kyung, Do-Hyun;Choi, Soo-Keun;Jung, Heung-Chae;Pan, Jae-Gu;Kim, Byung-Gee
    • Journal of Microbiology and Biotechnology
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    • 제17권4호
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    • pp.677-680
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    • 2007
  • To analyze a cotG-based Bacillus subtilis spore display system directly, $GFP_{UV}$ was expressed on the surface of Bacillus subtilis spores. When $GFP_{UV}$ was fused to the C-terminal of the cotG structural gene and expressed, the existence of a $CotG-GFP_{UV}$ fusion protein on the B. subtilis spore was confirmed by flow cytometry confocal microscopic analysis. When the cotG anchoring motif was deleted, no fluorescence emission was observed under flow cytometry and confocal microscopic analysis from the purified spore, confirming the essential role of CotG as an anchoring motif. This $GFP_{UV}$ displaying spore might be used for another signaling application triggered by intracellular or extracellular stimuli.