• Title/Summary/Keyword: mica

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Mineralogy of Clay Minerals from the Sarisan Mine, Korea (麗州 싸리산 鑛山에서 産出하는 粘土鑛物에 對한 鑛物學的 硏究)

  • Kim, Geon-Young;Kim, Soo-Jin
    • Journal of the Mineralogical Society of Korea
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    • v.5 no.2
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    • pp.79-92
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    • 1992
  • The Sarisan clay deposits of hydrothermal origin are found in the intensely weathered wto-mica granite in Yeoju area. The major clay minerals of the Sarisan mine are illite and montmorillonite with minor disordered kaolinite, vermiculite, and some interstratified mineral. Clay minerals were studied using various methods including X-ray diffraction, infrared absorption spectroscopy, electron microscopy, and thermal and chemical analyses. Illites occur as discrete illite or highly illitic interstratified mineral. They are of 1M and $2M_1$ polytypes and characterized by a low lattice charge (1.768-0.926 per unit formula), low $K^+$ content (0.741-0.902 per unit formula), and high Si/Al ratio (1.154-1.293) as compared with muscovite. Montmorillonites are highly negative charged and occasionally random-interstratified as I/S with 80-98% smectite. Hydrothermal alteration is more important than later weathering alteration for the formation of illite and montmorillonite clay minerals. The hydrothermal alteration took place through two stages; the formation of illite in the early stage and the formation of montmorillonite in the late stage. Disordered kaolinite and vermiculite are the weathering products of plagioclase and biotite, respectively.

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Geological Structures of the Southern Jecheon, Korea: Uplift Process of Dangdusan Metamorphic Complex and Its Implication (옥천대 제천 남부의 지질구조: 당두산변성암복합체의 상승과정과 그 의미)

  • Kihm, You-Hong;Kim, Jeong-Hwan;Cheong, Sang-Won
    • Journal of the Korean earth science society
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    • v.21 no.3
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    • pp.302-314
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    • 2000
  • Keumseong area in the southern part of the Jecheon city, the Ogcheon Belt, consists of Precambrian Dangdusan Metamorphic Complex, Dori Formation of the Choseon Supergroup, and Jurassic Jecheon Granite. The Dangdusan Metamorphic Complex consists of quartz schist, mica schist. quartzite and pegmatite. The Dori Formation is composed of mainly laminated limestone. The rocks in the study area have been undergone at least three phases of deformations since Paleozoic period. The Dangdusan Metamorphic Complex is outcrop at three areas in the study area, which are exposed along the faults and occurred as inlier within the Dori Formation. Previous authors interpreted the uplift of the Dangdusan Metamorphic Complex by the Dangdusan Fault, but we could not find any evidences related to the Dangdusan Fault. Thus, we interpret the uplift of the Dangdusan Metamorphic Complex due to the D$_2$ Weolgulri and Dangdusan thrusts and post-D$_2$ Jungbodeul, Kokyo and Jungjeonri faults. The uplift of the Busan Metamorphic Complex to the west of the study area was interpreted by ductile deformation. However, the Dangdusan Metamorphic Complex is formed by brittle thrusts and faults in this study. According to deformation sequence, the characters of deformations in the Choseon and Ogcheon suprergroups had been changed from ductile to brittle deformations through the time. Therefore, we interpret the Dangdusan Metamorphic Complex is exposed later than the Busan Metamorphic Complex.

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Geochemical Characteristics of Soils and Sediments at the Narim Mine Drainage, Korea: Dispersion, Enrichment and Origin of Heavy Metals (나림광산 수계의 토양과 퇴적물에 관한 지구화학적 특성: 중금속 원소의 분산, 부화 및 기원)

  • Lee, Chan Hee;Lee, Hyun Koo;Lee, Jong Chang
    • Economic and Environmental Geology
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    • v.31 no.4
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    • pp.297-310
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    • 1998
  • Geochemical characteristics of environmental toxic elements at the Narim mine area were investigated on the basis of major, minor, rare earth element geochemistry and mineralogy. Ratios of $Al_2O_3/Na_2O$ and $K_2O/Na_2O$ in soils and sediments range from 11.57 to 22.21 and from 1.86 to 3.93, and are partly negative and positive correlation against $SiO_2/Al_2O_3$ (3.41 to 4.78), respectively. These suggested that sediment source of host granitic gneiss could be due to rocks of high grade metamorphism originated by sedimentary rocks. Characteristics of some trace and rare earth elements of V/Ni (0.33 to 1.95), Ni/Co (2.00 to 6.50), Zr/Hf (11.27 to 53.10), La/Ce (0.44 to 0.55), Th/Yb (4.07 to 7.14), La/Th (2.35 to 3.93), $La_N/Yb_N$ (6.58 to 13.67), Co/Th (0.63 to 2.68), La/Sc (3.29 to 5.94) and Sc/Th (0.49 to 1.00) are revealed a narrow range and homogeneous compositions may be explained by simple source lithology. Major elements in all samples are enriched $Al_2O_3$, MgO, $TiO_2$ and LOI, especially $Fe_2O_3$ (mean=7.36 wt.%) in sediments than the composition of host granitic gneiss. The average enrichment indices of major and rare earth elements from the mining drainage are 2.05 and 2.91 of the sediments and are 2.02 and 2.60 of the soils, normalizing by composition of host granitic gneiss, respectively. Average composition (ppm) of minor and/or environmental toxic elements in sediments and soils are Ag=14 and 1, As=199 and 14, Cd=22 and 1, Cu=215 and 42, Pb=1770 and 65, Sb=18 and 3, Zn=3333 and 170, respectively, and extremely high concentrations are found in the subsurface sediments near the ore dump. Environmental toxic elements were strongly enriched in all samples, especially As, Cd, Cu, Pb, Sb and Zn. The level of enrichment was very severe in mining drainage sediments, while it was not so great in the soils. Based on the EPA value, enrichment index of toxic elements is 8.63 of mining drainage sediments and 0.54 of soils on the mining drainage. Mineral composition of soils and sediments near the mining area were partly variable being composed of quartz, mica, feldspar, amphibole, chlorite and clay minerals. From the gravity separated mineralogy, soils and sediments are composed of some pyrite, arsenopyrite, chalcopyrite, sphalerite, galena, goethite and various hydroxide minerals.

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Material Characteristics and Clay Source Interpretation of Crucibles in Baekje Kingdom Excavated from the Ssangbukri Site in Buyeo, Korea (부여 쌍북리 유적 출토 백제 도가니의 재료학적 특성과 원료의 산지해석)

  • Kim, Ji-Young;Park, Jin-Young;Park, Dae-Sun;Lee, Chan-Hee
    • Journal of Conservation Science
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    • v.26 no.1
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    • pp.1-12
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    • 2010
  • The crucibles of Baekje Kingdom from the Ssangbukri Site which were used for glass and metal melting had light brown, grayish blue and grayish brown colored bodies. In thin section, the crucibles contained numerous quartz grains and pottery fragments. The surface was covered with fine grained quartz for thermal resistance. Based on decomposition of mica group minerals and formation of mullite detected by X-ray diffraction analysis, it was inferred that all crucibles have been fired over $1,000^{\circ}C$. It was also found that firing temperature has exceeded $1,100^{\circ}C$ in some crucibles because feldspar was not detected. The maximum temperature was assumed at $1,200^{\circ}C$. The magnetic susceptibility values and geochemical characteristics sorted out the crucibles into two groups that differed from the characteristics of the local soils. This reflected geological setting of the site where the alluvium was formed from two kinds of surrounding rock masses, granite gneiss and biotite granite. However, the local soils had similarities with the crucibles in weathering degree and geochemical behavior of major elements. In consequence, it was considered that the raw clay of the crucibles was supplied from the local area of the site.

Design of Partial Discharge Pattern Classifier of Softmax Neural Networks Based on K-means Clustering : Comparative Studies and Analysis of Classifier Architecture (K-means 클러스터링 기반 소프트맥스 신경회로망 부분방전 패턴분류의 설계 : 분류기 구조의 비교연구 및 해석)

  • Jeong, Byeong-Jin;Oh, Sung-Kwun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.67 no.1
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    • pp.114-123
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    • 2018
  • This paper concerns a design and learning method of softmax function neural networks based on K-means clustering. The partial discharge data Information is preliminarily processed through simulation using an Epoxy Mica Coupling sensor and an internal Phase Resolved Partial Discharge Analysis algorithm. The obtained information is processed according to the characteristics of the pattern using a Motor Insulation Monitoring System program. At this time, the processed data are total 4 types that void discharge, corona discharge, surface discharge and slot discharge. The partial discharge data with high dimensional input variables are secondarily processed by principal component analysis method and reduced with keeping the characteristics of pattern as low dimensional input variables. And therefore, the pattern classifier processing speed exhibits improved effects. In addition, in the process of extracting the partial discharge data through the MIMS program, the magnitude of amplitude is divided into the maximum value and the average value, and two pattern characteristics are set and compared and analyzed. In the first half of the proposed partial discharge pattern classifier, the input and hidden layers are classified by using the K-means clustering method and the output of the hidden layer is obtained. In the latter part, the cross entropy error function is used for parameter learning between the hidden layer and the output layer. The final output layer is output as a normalized probability value between 0 and 1 using the softmax function. The advantage of using the softmax function is that it allows access and application of multiple class problems and stochastic interpretation. First of all, there is an advantage that one output value affects the remaining output value and its accompanying learning is accelerated. Also, to solve the overfitting problem, L2-normalization is applied. To prove the superiority of the proposed pattern classifier, we compare and analyze the classification rate with conventional radial basis function neural networks.

Potential repository domain for A-KRS at KURT facility site (KURT 부지 조건에서 A-KRS 입지 영역 도출)

  • Kim, Kyung-Su;Park, Kyung-Woo;Kim, Geon-Young;Choi, Heui-Joo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.10 no.3
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    • pp.151-159
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    • 2012
  • The potential repository domains for A-KRS (Advanced Korean Reference Disposal System for High Level Wastes) in geological characteristics of KURT (KAERI Underground Research Tunnel) facility site were proposed to develop a repository system design and to perform the safety assessment. The host rock of KURT facility site is one of major Mesozoic plutonic rocks in Korean peninsula, two-mica granite, which was influenced by hydrothermal alteration. The topographical features control the flow lines of surface and groundwater toward south-easterly and all waters discharge to Geum River. Fracture zones distributed in study site are classified into order 2 magnitude and their dominant orientations are N-S and E-W strike. From the geological features and fracture zones, the potential repository domains for A-KRS were determined spatially based on the following conditions: (1) fracture zone must not cross the repository; and (2) the repository must stay away from the fracture zones greater than 50 m. The western region of the fracture zones in the N-S direction with a depth below 200 m from the surface was sufficient for A-KRS repository. Because most of the fracture zones in N-S direction were inclined toward the east, we expected to find a homogeneous rock mass in the western region rather than in the eastern region. The lower left domain of potential domains has more suitable geological and hydrogeological conditions for A-KRS repository.

Comparison of pigment in automotive solid color paints by FT-IR and XRF spectroscopy for forensic aspect (법과학적 관점에서 FT-IR과 XRF를 이용한 단색 페인트의 안료 비교)

  • Park, Ha-Sun;Kim, Ki-Wook;Heo, Sangcheol;Ryu, Seung-Jin;Lee, Hyunik;Min, Ji-Sook
    • Analytical Science and Technology
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    • v.26 no.4
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    • pp.245-255
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    • 2013
  • Identification of paint on victim's clothing and a vehicle are valuable for forensic examination when investigating hit-and-run accidents. Automotive paints on clothes are used to prove a victim caused by traffic accident and to identify a suspected vehicle. The comparison of transferred paints between victim's vehicle and suspected vehicle can be an important evidence in reconstructing the accident situation and in discovering the truth. The paints such as white, yellow, red, blue, or black are hard to examine particle shape under a stereomicroscope because of it is not included aluminum, pearl, and mica flakes in the pigments. The aim of this study under forensic aspect is to compare pigment among basecoat layers of solid paints by identifying inorganic elemental compositions and binder resins of pigments using by micro-FT-IR and micro-XRF spectrometer. The pigment samples were analyzed by using two methods of FT-IR: Reflectance and ATR method. Two methods of FT-IR were useful in discriminating binder resins of pigments by comparing characteristic peaks and patterns of spectra. Also, XRF spectrometer could identify the elemental compositions in inorganic pigments of trace paints which are difficult to compare the identification by FT-IR.

Evaluation of Hot Mix Asphalt Properties using Complex Modifiers (복합개질제를 이용한 아스팔트 혼합물의 물성 평가)

  • Lee, Kwan-Ho;Kim, Seong-Kyum
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.5
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    • pp.146-152
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    • 2018
  • In this study, to improve the performance of asphalt mixtures for plastic deformation occurring mainly in Korea, complex modifiers were prepared by mixing powders and liquid type modifiers. The main constituents were powdery diatomaceous earth, mica and carbon black, and liquid type solid 70% SBR latex. The tensile strength ratios for the two asphalt mixtures used in the test were above 0.80 for the Ministry of Land Transportation (2017) asphalt mixture production and construction guidelines. The effects of increasing the tensile strength in the dry state was more than 14% when the composite modifier was added. The deformation rate per minute by the wheel tracking test load was an average of 0.07 to 0.147 for each mixture. The strain rate per minute was improved by the modifier, and the dynamic stability was improved by almost 100% from 295 to 590. In addition, the final settling was reduced from 11.38 mm to 9.57 mm. A plastic deformation test using the triaxial compression test showed that the amount of deformation entering the plastic deformation failure zone at the end of the second stage section and in the third stage plastic deformation section was 1.76 mm for the conventional mixture and 1.50 mm for the complex modifier mixture. The average slope of the complex modifier asphalt mixture mixed with the multi-functional modifier was 0.005 mm/sec. The plastic deformation rate is relatively small in the section where the road pavement exhibits stable common performance, i.e. the traffic load.

Low-temperature Hydrothermal Synthesis of Organic Smectite from Siliceous Mudstone (규질 이암으로부터 유기 스멕타이트의 저온 수열합성)

  • 노진환
    • Journal of the Mineralogical Society of Korea
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    • v.17 no.1
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    • pp.49-59
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    • 2004
  • Organic smectite was hydrothermally synthesized by treating the opal-rich siliceous mudstone from the Pohang area with TMAOH solutions and 1:1 solutions of TMAOH+NaOH at $80^{\circ}C$ and concentrations ranging 10∼15%. Smectite was solely formed without accompanying any mineral products in case of TMAOH, whereas NaP and hydroxysodalite was synthesized together with smectite under the blending solution of TMAOH+NaOH. The synthesized smectite is identified as an organic smectite intercalating $TMA^{+}$ within its interlayer site, specifically corresponding to monmorillonite species, through mineralogical characterization by XRD, DTA, and IR analyses. The experimental results indicate that main precursor of the synthesized smectite is undoubtedly opal-CT, and the original sedimentary smectite included as considerable amounts in the mudstone seems to play a major role as Al-sources necessary far the smectite formation. Original inert components such as quartz and mica do not affect mostly to the synthesis reaction, and thus, are resultantly found as impurities in the synthetic products. These experimental results may imply that a new effective method for the low-temperature (less than $100^{\circ}C$) hydrothermal synthesis of organic smectite will be established if some Al-sources adequate for this synthetic system are available.

Mineralogical Characteristics and Genesis of Phlogopite in the Talc Deposits of the Chungnam Area, Korea (충남지역 활석광상에서 산출되는 금운모의 광물특성 및 기원)

  • Kim Geon-Young;Kim Soo Jin;Koh Yong Kwon;Bae Dae Seok
    • Journal of the Mineralogical Society of Korea
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    • v.17 no.3
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    • pp.221-233
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    • 2004
  • Mineralogical characteristics and genesis of phlogopite in the talc deposits of the chungnam area were studied. Mica is one of the major impurity of talc ores in the study area. Talc-related micas show typical phlogopite composition, whereas talc-unrelated micas show wide compositional variations between biotite and phlogopite. Phlogopite mainly occurs in the black-wall type zone, especially in the nodular talc ores near the outer part of talc ore bodies. Interleaving textures of phlogopite and chlorite are easily observed under the optical microscope and back-scattered electron images. Interleaving textures of phlogopite and talc are observed also. Examination of the phlogopite by transmission electron microscope reveals that 14 $\AA$ layers of chlorite are randomly interlayered within the 10 $\AA$ layers of phlogopite, which suggests that the genesis of phlogopite is closely related to chlorite. Considering the occurrence and mineralogical characteristics of phlogopite, and the possible origin of K for the formation of phlogopite, phlogopite of the study area was formed by interaction between talc ore body and hydrothermal solution containing sufficient K at the late stage of talc formation. K might be introduced from the granitic gneiss at the contact zone between the talc ore body and the granitic gneiss under favorable structural condition for the potash metasomatism.