• Title/Summary/Keyword: methanol resistance

Search Result 104, Processing Time 0.026 seconds

Sensing Properties of Porous Silicon Layer for Organic Vapors (다공질 실리콘의 유기가스 검지 특성)

  • 김성진;이상훈;최복길
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.15 no.11
    • /
    • pp.963-968
    • /
    • 2002
  • In this work, porous silicon (PS) layer is investigated as a sensing material to detect organic vapors such as ethanol (called alcohol), methanol, and acetone in low concentrations. To do this, PS sensors were fabricated. They have a membrane structure and comb-type electrodes were used to detect the change of electrical resistance effectively. PS layer on Si substrates was formed by anodization in HF solution of 25%. From fabricated sensors, current-voltage (Ⅰ-Ⅴ) curves were measured for gases evaporated from 0.1 to 0.5% organic solution concentrations at 36$\^{C}$. As the result, all curves showed rectifying behavior due to a diode structure between Si and the PS layer. The conductance of most sensors increased largely at high voltage of 5V, but the built-in potential on the measured Ⅰ-Ⅴ curve was lowered inversely by the adsorption effect of the organic vapors with high dipole moment.

A Study on the Properties of sPEEK Electrolytic Membranes using Physical Crosslinking (물리적 가교결합을 이용한 sPEEK 전해질막의 특성에 관한 연구)

  • Oh, Sae-Joong
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.17 no.1
    • /
    • pp.433-440
    • /
    • 2016
  • Composite membranes were prepared by the solution casting method from sulfonated poly(etheretherketone)(sPEEK) and imidazole and phosphotungstic acid(PWA) to enhance the electrolytic properties of the membrane. TGA measurements showed that physical crosslinking due to acid-base interactions improved the thermal resistance to the desulfonation of sulfonic acid groups of the composite membrane and the addition of PWA enhanced the resistance to thermal decomposition of the composite membrane. The acid-base interaction decreased the water uptake, proton conductivity and methanol permeability of the sPEEK/imidazole composite membranes. The addition of PWA increased the proton conductivities while it decreased the water uptake and methanol permeability of sPEEK/imidazole/PWA composite membranes. Therefore, the selectivity of the composite membranes was enhanced by the addition of PWA.

Multidrug-resistance Reversing Activity of Medicinal Plants (약용 식물의 암세포 다제내성 조절 활성 검색)

  • Kim, Se-Eun;Hwang, Bang-Yeon;Kim, Young-Ho;Kim, Young-Choong;Lee, Kyong-Soon;Lee, Jung-Joon
    • Korean Journal of Pharmacognosy
    • /
    • v.28 no.4
    • /
    • pp.174-178
    • /
    • 1997
  • Methanol extracts from 450 plants were screened for muttidrug-resistance reversing activity using drug sensitive KB-3-1 and multidrug-resistant KB-Vl cells. Among them, the extracts of Cynanchum wilfordii, Torilis japonica, Celastrus orbiculatus, Melia toosendan and Teminialia chebula strongly potentiated vinblastine cytotoxicity in KB-Vl cells. But their cytotoxicities to both sensitive KB-3-1 and resistant KB-Vl cells were in the same order of magnitude. These results indicate that the above samples would contain the active principles which do not exert their ativity solely by cytotoxicity.

  • PDF

A study on the Thermopneumatic Actuator with Phase Change for Micro Pump (상변화를 이용한 열공압형 마이크로 펌프용 액츄에이터 성능에 관한 연구)

  • Park, S.;Hwang, J.Y.;Lee, S.;Kang, K.;Kang, H.;Jang, J.;Lee, H.;Kang, S.
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2006.11a
    • /
    • pp.425-428
    • /
    • 2006
  • Recently, Direct Methanol Fuel Cell (DMFC) for portable devices has been received much attention because DMFC has a possibility of higher energy density than electrical batteries and smaller size than other fuel cells. This paper presents the fabrication and test of a thermopneumatic microactuator with a phase change for DMFC. A microactuator consists of an inlet an outlet a chamber, a heater and a sensor of resistance temperature detector(RTD). The micoractuator is fabricated by the spin-coating process, the lithograph process, the deep RIE process and so on. The total size of microactuator is $20{\times}20{\times}0.53mm^3$. When the current is applied, the heater heats liquid in chamber. As a result the liquid vaporizes. The response of temperature in the chamber was measured using thermocouple The changed temperature is $3^{\circ}C$ for 5 sec at 0.032W.

  • PDF

A comparative study on the flow patterns in closed loop pulsating heat pipe charged with various working fluids (다양한 작동유체로 충전된 폐쇄 루프 맥동 히트파이프 내부 유동패턴 비교)

  • Kang, Seok Gu;Kim, Seong Keun;Ahmad, Hibal;Jung, Sung Yong
    • Journal of the Korean Society of Visualization
    • /
    • v.17 no.3
    • /
    • pp.52-58
    • /
    • 2019
  • Thermal performance and flow patterns inside the closed loop pulsating heat pipe (CLPHP) were experimentally investigated. For investigating the effect of working fluids, CLPHP was filled with various working fluids including methanol, acetone and ethanol. The thermal resistance was calculated by temperatures in evaporator and condenser and flow patterns were visualized by a digital camera. The thermal resistances for all fluids were decreased as the heat increases. Flow patterns change from static slug to elongated slug flows, bulk circulation and annular flows as the heat increases. Dry-out occurs after annular flows. For reasonable comparison of thermal performances, normalized CHF, Kutateladze number (Ku), was compared. Even though ethanol has smallest CHF, Ku of ethanol is similar with that of methanol. In addition, acetone has the highest Ku that means CLPHP with acetone provides the higher thermal performance compared with CLPHP with other fluids.

Metabolite analysis in the type 1 diabetic mouse model

  • Park, Sung Jean
    • Journal of the Korean Magnetic Resonance Society
    • /
    • v.25 no.3
    • /
    • pp.33-38
    • /
    • 2021
  • Type 1 diabetes mellitus (T1DM) is caused by insufficient production of insulin, which is involved in carbohydrate metabolism. Type 2 diabetes mellitus (T2DM) has insulin resistance in which cells do not respond adequately to insulin. The purpose of this study was to estimate the characteristics of type 1 diabetes using streptozotocin-treated mice (STZ-mouse). The sera samples were collected from the models of hyperglycemic mouse and healthy mouse. Based on the pair-wise comparison, five metabolites were found to be noticeable: glucose, malonic acid, 3-hyroxybutyrate, methanol, and tryptophan. It was very natural glucose was upregulated in STZ-mouse. 3-hyroxybutyrate was also increased in the model. However, malonic acid, tryptophan, and methanol was downregulated in STZ-mouse. Several metabolites acetoacetate, acetone, alanine, arginine, asparagine, histidine, lysine, malate, methionine, ornithine, proline, propylene glycol, threonine, tyrosine, and urea tended to be varied in STZ-mouse while the statistical significance was not stratified for the variation. The multivariate model of PCA clearly showed the group separation between healthy control and STZ-mouse. The most significant metabolites that contributed the group separation included glucose, citrate, ascorbate, and lactate. Lactate did not show the statistical significance of change in t-test while it tends to down-regulated both in DNP and Diabetes.

HNS Detection Properties of Printed Ag:CNT Film as Liquid Sensor (Ag:CNT 인쇄박막 액체 센서의 위험유해물질 검출 특성)

  • Ko, Dongwan;Choi, Junseck;Lee, Sangtae;Chang, Jiho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.32 no.3
    • /
    • pp.223-228
    • /
    • 2019
  • We fabricated a printed Ag:CNT film as a liquid sensor for the detection of HNS (hazardous and noxious substances) in seawater. The paste required for printing was prepared using Ag powder, MWCNTs (multi-walled carbon nanotubes), and an organic binder. The heat treatment process for binder removal was optimized. In order to confirm that the sensor was operational, the resistance change characteristics in brine (3.5%) and methanol (99.8%) were assessed at $20^{\circ}C$. EDL (electrical double layer) formation and redox reactivity were confirmed as the most important reactions affect each electrical property of sensor in brine and methanol. From these results, it was determined that printed Ag:CNT film can be applied as a sensor to detect HNS in seawater.

Inhibition of Quorum Sensing Regulated Virulence Factors and Biofilm Formation by Eucalyptus globulus against Multidrug-Resistant Pseudomonas aeruginosa

  • Sagar, Pankaj Kumar;Sharma, Poonam;Singh, Rambir
    • Journal of Pharmacopuncture
    • /
    • v.25 no.1
    • /
    • pp.37-45
    • /
    • 2022
  • Objectives: The quorum-sensing-inhibitory and anti-biofilm activities of the methanol extract of E. globulus leaves were determined against clinically isolated multidrug-resistant Pseudomonas aeruginosa. Methods: The preliminary anti-quorum-sensing (AQS) activity of eucalyptus was investigated against a biosensor strain Chromobacterium violaceum ATCC 12472 (CV12472) by using the agar well diffusion method. The effect of sub-minimum inhibitory concentrations (sub-MICs) of the methanol extract of eucalyptus on different quorum-sensing-regulated virulence factors, such as swarming motility, pyocyanin pigment, exopolysaccharide (EPS), and biofilm formation, against clinical isolates (CIs 2, 3, and 4) and reference PA01 of Pseudomonas aeruginosa were determined using the swarm diameter (mm)-measurement method, chloroform extraction method, phenol (5%)-sulphuric acid (concentrated) method, and the microtiter plate assay respectively, and the inhibition (%) in formation were calculated. Results: The preliminary AQS activity (violacein pigment inhibition) of eucalyptus was confirmed against Chromobacterium violaceum ATCC 12472 (CV12472). The eucalyptus extract also showed concentration-dependent inhibition (%) of swarming motility, pyocyanin pigment, EPS, and biofilm formation in different CIs and PA01 of P. aeruginosa. Conclusion: Our results revealed the effectiveness of the E. globulus extract for the regulation of quorum-sensing-dependent virulence factors and biofilm formation at a reduced dose (sub-MICs) and suggest that E. globulus may be a therapeutic agent for curing and controlling bacterial infection and thereby reducing the possibility of resistance development in pathogenic strains.

MEMS-based Direct Methanol Fuel Cells and Their Stacks for the Reduction of Cell-to-Cell Deviation and Interconnection Voltage Drop (단위 셀간 성능편차 및 접속접안 강하 초소화를 위한 극소형 직접메탄올 연료전지 스택의 설계 및 제작)

  • Seo, Young-Ho;Cho, Young-Ho
    • Transactions of the Korean Society of Mechanical Engineers A
    • /
    • v.31 no.10
    • /
    • pp.981-985
    • /
    • 2007
  • We present a MEMS-based portable Direct Methanol Fuel Cell (micro-DFMC), featured by a platinum sputtered microcolumn electrode and a built-in fuel chamber containing a limited amount of methanol fuel. Also presented is a micro-DMFC stack structure having a common electrolyte sandwiched by the microcolumn electrodes. The single cells with ME16 and PE16 electrodes show the maximum power densities of $31.04{\pm}0.29{\mu}W/cm^2$ and $9.75{\pm}0.29{\mu}W/cm^2$, respectively; thus indicating the microcolumn electrode (ME16) generates the power density (3.2 times) higher than the planar electrode (PE16). The single cell tests of ME16 and ME4 electrodes (Fig.8) show the maximum power of $31.04{\pm}0.29{\mu}W/cm^2$, and $25.23{\pm}2.7{\mu}W/cm^2$, respectively; thus demonstrating the increased window frame reduces the normalized standard power deviation (standard deviation over the average power). The normalized deviation of 0.11 in ME4 cell has been reduced to 0.01 in ME16 cell due to the increased window frames. The maximum power density of 4-cell stack is 15.7 times higher than that of the single cell. 4-cell stack produces the power capacity of 20.3mWh/g during 980min operation at the voltage of 450mV with the load resistance of $800{\Omega}$.

A Study on Developing of Soldering Flux (납땜 플럭스 개발에 관한 연구)

  • 이통영
    • Fire Science and Engineering
    • /
    • v.14 no.2
    • /
    • pp.33-38
    • /
    • 2000
  • Flux, essentially used in soldering process of PCB (Printed Circuit Board) in electronics industry, contains IPA (Isopropyl alcohol) and methanol, which are highly inflammable and explosive. Hazard Chemical Controlling Law classified methanol as toxic material and Environmental Law classified methanol as VOC (Volatile Organic Compound). So there have been pressing needs of developing substitutes for the existing Flux. New solvent which is non-flammable and main component is DCP having same specific character of the existing Flux. It's been combirated with proper composition ratio adding stabilizer. As a result, it relieved working Environment Allowance thickness 200 ppm to 470 ppm, chance of not been soldered 0.083% to 0%, spread 85% to 87%, power saving resistance 1.0$\times$$10^{12}$$\Omega$ to 6.9$\times$$10^{12}$$\Omega$, which means a lot better than the existing Flux. Therefore, Flux confirmed the chance of improving productivity, safety, environment safety and quality. Also, Flux got a satisfied result after product quality test and product reliability test.

  • PDF