• Title/Summary/Keyword: metallic structure

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Pd-based metallic membranes for hydrogen separation and production

  • Tosti, Silvano;Basile, Angelo
    • Proceedings of the Membrane Society of Korea Conference
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    • 2003.07a
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    • pp.25-28
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    • 2003
  • Low cost composite metallic membranes for the hydrogen separation and production have been prepared by using thin Pd-Ag foils reinforced by metallic (stainless steel and nickel) structures. Especially, “supported membranes” have been obtained by a diffusion welding procedure in which Pd-Ag thin foils have been joined with perforated metals (nickel) and expanded metals (stainless steel): in these membranes the thin palladium foil assures both the high hydrogen permeability and the perm-selectivity while the metallic support provides the mechanical strength. A second studied method of producing "laminated membranes" consists of coating non-noble metal sheets with very thin palladium layers by diffusion welding and cold-rolling. Palladium thin coatings over these metals reduce the activation energy of the hydrogen adsorption process and make them permeable to the hydrogen. In this case, the dense non-noble metal has been used as a support structure of the thin Pd-Ag layers coated over its surfaces: a proper thickness of the metal assures the mechanical strength, the absence of defects (cracks, micro-holes) and the complete hydrogen selectivity of the membrane. membrane.

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XPS Study of Mn 2pp and 3s Satellite Structures of Heusler Alloys: NiMnSb, ppdMnSb, pptMnSb

  • Yang, See-Hun;Oh, Se-Jung;ppark, Je-Geun
    • Proceedings of the Korean Vacuum Society Conference
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    • 1994.02a
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    • pp.50-50
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    • 1994
  • Half-metallic Heusler alloys (NiMnSb, ppdMnSb, pptMnSb) have attracted much attention due to their unique electronic and magnetic structures. Sppin-ppolarized band structure calculation ppredicts metallic behavior for the majority sppin states and semiconductor behavior for the minority sppin states. We have studied the electronic structures of these half-metallic Heusler alloys by core-level pphotoemission sppectroscoppy of Mn 2pp and 3s XppS sppectra. We found large intensities of Mn 2pp satellites and 3s exchange spplitting comppared with other metal Mn-alloys. These satellite structure can be understood by applying Anderson imppurity model. This fact supports the calculated sppin pprojected ppartial density of states which suggests that the valence electrons be highly sppin ppolarized near Fermi level and that the electrons involved with charge-transfer be mainly minority sppin ones which have semiconducting band structure. The trend of charge transfer energies Δ from ligands (Sb 5pp) to Mn 3d, obtained from our model fitting, is consistent with that calculated from sppin pprojected ppartial density of state. Also the trend of d-d electron correlation energies U calculated from Mn Auger line L3 VV by Mg $K\alpha$ source is comppatible with that resulted from our model fitting. We fitted the Mn 3s curve in the same way as for insulating Mn comppounds by using the same pparameters calculated from Mn 2pp curve fitting exceppt for the Coulomb interaction energy Q between core hole and d-electrons. The 3s sppectra were analyzed by combing the charge transfer model and a simpple model taking into account the configuration mixing effect due to the intra-shell correlation. We found that the exchange interaction between 3s hole and 3d electrons is mainly respponsible for the satellite of Mn 3s sppectra. This is consistent with the neutron scattering data, which suggests local 3d magnetic moment. We find that the XppS analysis results of Mn 2pp and 3s satellite structures of half-metallic Heusler alloys are very similar to those of insulating transition metal comppounds.

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The Study on New Radiating Structure with Multi-Layered Two-Dimensional Metallic Disk Array for Shaping flat-Topped Element Pattern (구형 빔 패턴 형성을 위한 다층 이차원 원형 도체 배열을 갖는 새로운 방사 구조에 대한 연구)

  • 엄순영;스코벨레프;전순익;최재익;박한규
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.13 no.7
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    • pp.667-678
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    • 2002
  • In this paper, a new radiating structure with a multi-layered two-dimensional metallic disk array was proposed for shaping the flat-topped element pattern. It is an infinite periodic planar array structure with metallic disks finitely stacked above the radiating circular waveguide apertures. The theoretical analysis was in detail performed using rigid full-wave analysis, and was based on modal representations for the fields in the partial regions of the array structure and for the currents on the metallic disks. The final system of linear algebraic equations was derived using the orthogonal property of vector wave functions, mode-matching method, boundary conditions and Galerkin's method, and also their unknown modal coefficients needed for calculation of the array characteristics were determined by Gauss elimination method. The application of the algorithm was demonstrated in an array design for shaping the flat-topped element patterns of $\pm$20$^{\circ}$ beam width in Ka-band. The optimal design parameters normalized by a wavelength for general applications are presented, which are obtained through optimization process on the basis of simulation and design experience. A Ka-band experimental breadboard with symmetric nineteen elements was fabricated to compare simulation results with experimental results. The metallic disks array structure stacked above the radiating circular waveguide apertures was realized using ion-beam deposition method on thin polymer films. It was shown that the calculated and measured element patterns of the breadboard were in very close agreement within the beam scanning range. The result analysis for side lobe and grating lobe was done, and also a blindness phenomenon was discussed, which may cause by multi-layered metallic disk structure at the broadside. Input VSWR of the breadboard was less than 1.14, and its gains measured at 29.0 GHz. 29.5 GHz and 30 GHz were 10.2 dB, 10.0 dB and 10.7 dB, respectively. The experimental and simulation results showed that the proposed multi-layered metallic disk array structure could shape the efficient flat-topped element pattern.

Finite Element Analysis for Pearlite Transformation of Carbon Steel (탄소강의 펄라이트 변태에 대한 유한요소 해석)

  • 탄소강
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.9 no.3
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    • pp.69-75
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    • 2000
  • The object of the research is to estimate for pearlite structure of quenched carbon steels. The effects of temperature on physical properties metallic structures and the latent heat by phase transformation were considered. In this study a set of constitutive equations relevant to the analysis of thermo-elasto plastic materials with pearlite phase transformation during quenching process way presented on the basis of continuum thermo-dynamics. The iso-thermal transformation curve of the SM50C was formlated by cubic spline curve. The formulated equations of evolution in pearlite transformation was used for structure analysis. The volume fraction of pearlite was obtained from the results of calculated metallic structure by Finite element equation.

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Magnetically Soft Nanomaterials Obtained by Devitrification of Metallic Glasses

  • Kulik, Tadeusz;Ferenc, Jaroslaw;Kowalczyk, Maciej;Xiubing, Liang;Nedelko, Natalya
    • Journal of Magnetics
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    • v.9 no.2
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    • pp.65-68
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    • 2004
  • Magnetically soft nanomaterials obtained by controlled crystallisation of metallic glasses are the newest group of materials for inductive components. In particular, research is carried out in the field of alloys for high temperature applications. This kind of materials must meet two basic requirements: good magnetic properties and stability of properties and structure. In the present work the magnetic properties and structure of Fe-Co-Hf-Zr-Cu-B (HIDTPERM-type) alloys were investigated, as well as their stability. Differential thermal analysis, (DTA), X-ray diffractometry (XRD), transmission electron microscopy (TEM), magnetometry (VSM) and quasistatic hysteresis loop recording were used to characterise structure and properties of the alloys investigated. Optimisation against properties and their stability was performed, resulting in formulation of chemical composition of the optimum alloy, as well as its heat treatment.

Fe-Based Nano-Structured Powder Reinforced Zr-Based Bulk Metallic Glass Composites by Powder Consolidation

  • Cho, Seung-Mok;Han, Jun-Hyun;Lee, Jin-Kyu;Kim, Yu-Chan
    • Korean Journal of Materials Research
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    • v.19 no.9
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    • pp.504-509
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    • 2009
  • The Zr-based bulk metallic glass matrix composites of a mixture of gas-atomized metallic glass powders and Fe-based nanostructured powders were fabricated by spark plasma sintering. The Fe-based nanostructured powders adopted for the enhancement of plasticity were well distributed in the matrix after consolidation, and the matrix remains as a fully amorphous phase. The successful consolidation of metallic glass matrix composite with high density was attributed to viscous flow in the supercooled liquid state during spark plasma sintering. Unlike other amorphous matrix composites, in which improved ductility could be obtained at the expense of their strength, the developed composite exhibited improvement both in strength and ductility. The ductility improvement in the composite was considered to be due to the formation of multiple shear bands under the presence of the Fe-based nanostructured particles.

Ant lion optimizer for optimization of finite perforated metallic plate

  • Chaleshtaria, Mohammad H. Bayati;Jafari, Mohammad
    • Structural Engineering and Mechanics
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    • v.69 no.6
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    • pp.667-676
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    • 2019
  • Minimizing the stress concentration around hypotrochoid hole in finite metallic plates under in-plane loading is an important consideration in engineering design. In the analysis of finite metallic plate, the effective factors on stress distribution around holes include curvature radius of the corner of the hole, hole orientation, plate's aspect ratio, and hole size. This paper aims to investigate the impact of these factors on stress analysis of finite metallic plate with central hypotrochoid hole. To obtain the lowest value of stress around a hypotrochoid hole, a swarm intelligence optimization method named ant lion optimizer is used. In this study, with the hypothesis of plane stress circumstances, analytical solution of Muskhelishvili's complex variable method and conformal mapping is employed. The plate is taken into account to be finite, isotropic and linearly elastic. By applying suitable boundary conditions and least square boundary collocation technique, undefined coefficients of stress function are found. The results revealed that by choosing the above-mentioned factor correctly, the lowest value of stress would be obtained around the hole allowing to an increment in load-bearing capacity of the structure.

Domestic Conditions on the Electrolytic Corrosion Protection of Buried Metallic Structures (지하매설 금속구조물의 전식방지 국내 현황)

  • Lee, Hyun-Goo;Ha, Tae-Hyun;Choi, Jeong-Hee;Jung, Ho-Sung;Bae, Jeong-Hyo
    • Journal of the Korean Institute of Gas
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    • v.13 no.2
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    • pp.1-6
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    • 2009
  • With respect to a given structure, a stray current is to be defined as a current flowing on a structure that is not part of the intended electrical circuit. Most often DC-powered traction systems like railroads and tramlines are responsible for large dynamic stray currents. This type of stray current is generally results from the leakage of return currents from large DC traction systems that are grounded or have a bad earth-insulated return path. At the place where the current leaves the rail and metallic structures, electrolytic corrosion may take place. This paper investigates the domestic conditions on the electrolytic corrosion protection of buried metallic structures adjacent to DC traction systems by survey.

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Evaluation of Degraded Materials by Automated Ball Indentation(ABI) Technique (압입법을 이용한 재료의 열화도 평가)

  • 김석민;석창성;이승석;권재도
    • Journal of the Korean Society of Safety
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    • v.15 no.1
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    • pp.28-35
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    • 2000
  • As huge energy transfer systems like a nuclear power plant, steam power plant and petrochemical plant are operated for a long time, mechanical properties are changed by degradation. The life time of the systems can be affected by the mechanical properties. So determination of the integrity of the metallic structure is required either to en4sure that failure will not occur during the service life of the components or to evaluate the lifetime extension of the structure. An automated ball indentation(ABI) method was developed as a non-destructive technique for evaluating the integrity of such metallic components. In this paper, we would like to present the aging evaluation technique by the ABI method. The five classes of the thermally aged CF8M specimens were prepared using an artificially accelerated aging method. After holding 100, 300, 900, 1800 and 3600 hours at 43$0^{\circ}C$, the specimens were cooled down using water to room temperature respectively. The tensile test, hardness test, charpy impact test, ABI test were performed. The results of the fracture test were compared with those of ABI test and the new evaluation technique of the integrity of metallic structures was developed.

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Functionally Graded Properties Induced by Direct Laser Melting of Compositionally Selected Metallic Powders (레이저 직접 용융 시 금속분말의 함량조정을 통한 경사물성 부여)

  • Han, S.W.;Ji, W.J.;Lee, C.H.;Moon, Y.H.
    • Transactions of Materials Processing
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    • v.23 no.5
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    • pp.303-310
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    • 2014
  • Functionally graded properties are characterized by the gradual variation in composition and structure through the volume of the material, resulting in corresponding gradation in properties of the material. Direct laser melting (DLM) is a prototyping process whereby a 3-D part is built layer-wise by melting metal powder with laser scanning. Studies have been performed on the functionally graded properties induced by direct laser melting of compositionally selected metallic powders. For the current study, quadrangle structures were fabricated by DLM using Fe-Ni-Cr powders having variable compositions. Hardness and EDX analysis were conducted on cross-sections of the fabricated structure to characterize the properties. From the analysis, it is shown that functionally graded properties can be successfully obtained by DLM of selected metallic powders with varying compositions.