• Textile Coloration and Finishing
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• v.13 no.5
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• pp.298-305
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• 2001

The Purpose of this study was to investigate spectrophotometric characteristics of Korean knotweed extracts. The properties were evaluated by it's extracting solvent, effect of metallic ion, variations of pH values and effect of light exposure. The results were as following; The highest absorbance was found in methanol extract of Korean knotweed, while the lowest absorbance was carbon tetrachloride extract. The UV-vis. spectra of Korean knotweed colors in several solvents showed hypsochromic shift of $n->\pi^*$ transition with the polarity of solvent. Absorbance and peak of UV-vis. spectra of Korean knotweed colors became lower and broader by addition of metallic ion. The light stability in irradiation with xenon ]amp of the color solution with Cu were higher than those of Al and Fe. The UV-vis. spectra of Korean knotweed extracts in various pH values showed bathochromic shift under alkaline condition, and their Peaks disappeared after 5 hours exposure.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.38 no.3 s.116
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• pp.23-28
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• 2006

Xylan in hemicellulose has been reported as one of the reasons of the yellowing of chemical pulp and paper. But little relevant information is available in literature. In this study, we examined into the influence that glucuronoxylan or glucomannan and metallic ion($Cu^{2+},\;Fe^{2+},\;Fe^{3+},\;Mn^{2+}$) residued in pulp get each or when mixed at yellowing. Filter paper was treated with each metallic ion, glucuronoxylan and the mixture of glucuronoxylan and metal ions, and brightness and CIE $L^*a^*b^*$ was measured after accelerated aging. As the results of measurements, the filter paper processed by 10% glucuronoxylan was dropped $2{\sim}3%$ on the brightness after accelerated aging for 24 hours. Also, the filter paper treated with glucuronoxylan and $Fe^{2+}$ was dropped 7% on the brightness.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2005.05a
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• pp.237-240
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• 2005

The demand of micro electrical mechanical system (MEMS) bio/chemical sensor is rapidly increasing. To prevent the contamination of sensing area, a filtration system is required in on-chip total analyzing MEMS bio/chemical sensor. A nano-filter was mainly applied in some application detecting submicron feature size bio/chemical products such as bacteria, fungi and so on. We suggested a simple nano-filter fabrication process based on replication process. The mother pattern was fabricated by holographic lithography and reactive ion etching process, and the replication process was carried out using polymer mold and UV-imprinting process. Finally the nano-filter is obtained after removing the replicated part of metal deposited replica. In this study, as a practical example of the suggested process, a nano-dot array was replicated to fabricate nano-filter fur bacteria sensor application.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2012.10a
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• pp.595-596
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• 2012

• Journal of Welding and Joining
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• v.23 no.2
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• pp.32-40
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• 2005

• Bulletin of the Korean Chemical Society
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• v.28 no.8
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• pp.1341-1345
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• 2007

The surface chemistry of D2O dosed Zircaloy-4 (Zry-4) surface followed by Ar-ion bombardment and annealing was studied by means of X-ray photoelectron spectroscopy (XPS) and Ultraviolet photoelectron spectroscopy (UPS). In the XPS study, Ar-ion bombardment caused decrease of the oxygen on the surface region of Zry-4 and therefore led to change the oxidation states of the zirconium from oxide to metallic form. In addition, oxidation states of zirconium were changed to lower oxidation states of zirconium due to depopulation of oxygen on the surface region by annealing. Up to about 787 K, the bulk oxygen diffused out to the subsurface region and after this temperature, the oxygen on the surface of Zry-4 was depopulated. UPS study showed that the valence band spectrum of the D2O exposed Zry-4 exhibited a dominant peak at around 13 eV and no clear Fermi edge was detected. After stepwise Ar+ sputtering processes, the decrease of the oxygen on the surface of Zry-4 led to suppress the dominant peak around 13 eV, the peak around 9 eV and develop a new peak of the metallic Zr 4d state (20.5-21.0 eV) at the Fermi level.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.02a
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• pp.359-359
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• 2010

Self-organized nanostructures of dots, holes or ripples produced by energetic ion bombardment have been reported in a wide variety of substrates. Ion bombardment on an alloy or compound also draws much attention because it can induce a surface composition modulation with a topographical surface structure evolution. V. B. Shenoy et al. further suggested that, in the case of alloy surfaces, the differences in the sputtering yields and surface diffusivities of the alloy components will lead to a lateral surface composition modulation [1]. In the present work, the classical molecular dynamics simulation of Ar bombardment on metallic alloys at room temperature revealed that this bombardment induces a surface composition modulation in layer-by-layer mode. In both the $Co_{0.5}Cu_{0.5}$ alloy and the CoAl B2 phase, the element of higher-sputtering yield is accumulated on the top surface layer, whereas it is depleted in lower layers. A kinetic model considering both the rearrangement and the sputtering of the substrate atoms agrees with the puzzling simulation results, which revealed that the rearrangement of the substrate atoms plays a significant role in the observed composition modulation.

• Textile Coloration and Finishing
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• v.15 no.3
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• pp.146-153
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• 2003

This article describes the metal ions adsorption of chitosan fibers. The chitosan fibers were manufactured by wet spinning using 2% acetic acid as solvent, 10% aqueous sodium hydroxide as non solvent, and 4%chitosan solution as a solvent. The adsorption characteristics of chitosan fibers towards 100ppm solutions of various metal ions such as Cu(II), Cd(II), Cr(III), Hg(II) were examined at different pH value by ICP-Atomic Emission Spectrometer. The adhesiveness of metallic ions to the chitosan fiber were increased with the increase of pH and the decrease of denier. On the other hand, from pH4, chitosan fiber that is immersed in metal ion aqueous solution of Cu(II) and Cd(II) became homogeneous solution because is dissolved. The adhesiveness of metallic ions to chitosan fiber were found to increased in a sequence of Hg(II)> Cr(III)> Cu(II)> Cd(II). The antimicrobial characteristics of the chitosan fiber by adhered metal ions, virgin chitosan fiber, and cotton fiber were evaluated. The antimicrobial activity of the fibers were increased with the decrease of denier.

• Journal of the Korean institute of surface engineering
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• v.32 no.3
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• pp.428-432
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• 1999

As metallic surface has its unique lustrous appearance and optical reflectance in visible range of light, the metallization of plastic surface has been an essential drive toward weight reduction for fuel economy and decorations in transportation industry and has been put into practiced from wet chemical-electrochemial to dry vacuum process in view of an environmental effect. Electron-beam metallization was used in this work with an aim at improving the scratchproof surface hardness of plastic substrate with metallic finish character. Thin film of Al ($1000\AA$) and $SiO_2$($7000\AA$) were metallized on substrate of PC and PMMA and the films were evaluated by pencil test for surface hardness and by cross-cut tape test for adhesion. The ion beam treatment improved around twice as hard as non-treat surface. The ion beam is effect on its hardness and adhesion to surface hardened PC substrate.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.17 no.6
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• pp.492-498
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• 1984

We have reported the seasonal and portional variation in the composition of uronic acid of alginic acid from Ecklonia cava in the previous study. In the present paper, uronic acid block structure of alginic acid from Ecklonia cave was investigated, and some related properties such as viscosity, the dependence on temperature and substitution of metallic ion were also discussed. The proportion M block was highest amnog three blocks in both of frond and stipe. The average values of M and G block ratios were $51.6|%\;and\;32.3\%$ in the frond, whereas $45.7\%\;and\;38.6\%$ in the stipe, respectively. The proportions of alternating blocks in the frond and stipe were similar, and the values were $16.1\%$ in the frond and $15.6\%$ in the stipe. The viscosity of $1\%$ sodium alginate solution was almost inversely proportional to the M/G and/or M block ratio. Viscosities were marked maximum from summer to autumn and minimum winter to spring. In the value of lower M/G and M block ratio, the viscosity seemed to have a considerable dependence on temperature. The temperature dependence was more appearant in the alginic acid from the frond (M/G ratio, 0.95; M block, $54.2\%$) collected in July and the stipe (M/G ratio, 1.61; M block $47.6\%$) in April. The affinity with metallic ion appeared higher in order of $Pb^{2+}>Cu^{2+}>Co^{2+}>Zn^{2+}$. The amounts of metallic ion exchange of the $Pb^{2+},\;Cu^{2+},\;Co^{2+}\;and\;Zn^{2+}$ were ranged from 3.4. to 4.7, 2.5 to 3.2, 1.8 to 2.2 and 1.6 to 1.7 meq/(g. sodium alginate), respectively.