• 제목/요약/키워드: metallic ion

검색결과 225건 처리시간 0.024초

Energy Gap of $MgB_2$ from Point Contact Spectroscopy

  • Lee, Suyoun;Yonuk Chong;S. H. Moon;Lee, H. N.;Kim, H. G.
    • Progress in Superconductivity
    • /
    • 제3권2호
    • /
    • pp.146-150
    • /
    • 2002
  • We performed the point contact spectroscopy on newly discovered superconductor $MgB_2$ thin films with Au tip. In the point contact spectroscopy of the metallic Sharvin limit, the differential conductance below the gap is twice as that above the gap by virtue of Andreev Reflection. After some surface cleaning processes of sample preparation such as ion-milling and wet etching, the obtained dI/dV versus voltage curves are relatively well fitted to the Blonder-Tinkham-Klapwijk (BTK) formalism. Gaps determined by this technique were distributed in the range of 3meV~ 8meV with the BCS value of 5.9meV in the weak coupling limit. We attribute these discrepancies to the symmetry of the gap parameter and the degradation of the surface of the sample. We also present the temperature dependence of the conductance vs voltage curve and thereby the temperature dependence of the gap.

  • PDF

스틸렌-DVB 수지 에 의한 U(VI), Mn(II), Gd(III) 이온들의 흡착 (Adsorption of U(VI), Mn(II), Gd(III) lons on the Styrene - DVB Resin)

  • 강영식;김준태
    • 환경위생공학
    • /
    • 제17권3호
    • /
    • pp.31-36
    • /
    • 2002
  • The effects of pH, time, dielectric constant of solvent and crosslink on adsorption of metal ions by resin(cryptand resin) adsorbent were investigated. The metal ions were showed fast adsorption on the resins in over pH 3. The equilibrium time for adsorption of metallic ions was about two hours and the adsorption selectivity determined in methanol was in increasing order $UO^{2+}$ > $Mn^{2+}$ > $Gd^{3+}$ ion. The adsorption was in the order of 1%, 2% and 5% crosslink resin and adsorption of resin decreased in proportion to the order of dielectric constant of solvents.

"Crystallized Quantum Dot (Ge)" in Dielectric Matrix Synthesised by Metallic Ion Implantation

  • 전준홍;최진영;박원웅;임상호;한승희
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2010년도 제39회 하계학술대회 초록집
    • /
    • pp.270-270
    • /
    • 2010
  • 4족 반도체 원소 양자점들은 원소가 가지고 있는 반도체적 성질과, 양자점에서 나타나는 quantum confinements 적인 특성 때문에 전자재료나 광학적 분야, 특히 태양전지 분야에서 그 쓰임이 대두되고 있다. 이러한 4족 반도체 원소의 양자점들을 만들기 위한 여러 방법들이 시도되고 있는데, 그 중에서 특히 절연체 박막에 4족 반도체 원소의 양자점들을 만드는 방법에는 이온주입, PVD, 그리고 CVD 를 통한 multi-layer 증착후 열처리 과정을 반드시 포함하는 Stranski- krastanov 방법이 주로 사용되고 있다. 본 실험에서는 고체원소 이온주입이라는 방법을 통해 절연체 박막의 증착과 이온주입이 한 진공용기 내에서 연속공정으로 이루어 지면서, 별도의 열처리 과정 없이 결정화된 게르마늄 양자점을 만들어 보았다. 이는 (X-ray diffraction) XRD와 Raman spectroscopy로 결정화된 게르마늄을 확인할 수 있었으며, (X-ray photoelectron spectroscopy)XPS 데이터로도 순수한 게르마늄이 표면에서 깊이 방향으로 약 $1,000\;{\AA}$ 만큼 게르마늄 양자점들이 만들어 짐을 알 수 있었다. 마지막으로 (High resolution transmittance electron microscopy) HRTEM으로 그 양자점의 크기와 분포도 그리고 결정성을 알아 보았다.

  • PDF

Electrochemical Study of Poly(aniline N-alkylsulfonate)s

  • Kim, Eunkyoung;Rhee, Suh Bong
    • 분석과학
    • /
    • 제8권4호
    • /
    • pp.631-636
    • /
    • 1995
  • Electrochemical properties of self-dopable poly(aniline N-butylsulfonate)s in various acidic medium were investigated by spectroelectrochemical techniques. Cyclic voltammetric study showed more than two reversible process of one electron transfer, the potential and peak intensity of which were dependent on the acid concentration and dopant ion. Spectroscopic study at different oxidation level indicated that the electrochromic switching of the poly(aniline N-alkylsulfonate)s film involves structural changes from benzenoid ring to quinoid ring. Spectrocyclic voltammetry together with impedance spectra of the PANBUS film in 0.1 M $LiClO_4$ solution of acetonitrile containing 0.46 M of perchloric acid showed two types of highly conductive states at the intermediate oxidation levels, which can be related to the metallic polaron states doped by two different process.

  • PDF

이산화탄소 포획 원료용 사문석의 수용액 전처리 평가 (Characterization of Aqueous Solution Pretreatment for Serpentine Used Carbondioxide Sequestration Material)

  • 최원경
    • 한국수소및신에너지학회논문집
    • /
    • 제19권4호
    • /
    • pp.340-347
    • /
    • 2008
  • Dissolution process of serpentine in distilled water was systematically investigated for study on pre-treatment of serpentine which was a candidate material for carbon dioxide sequestration. The metallic ions(Ca, Si, Mg etc.) were dissolved in distilled water at ambient condition and their concentrations were changed with dissolution time. The precise evaluation of dissolution process for serpentine dissolved solvent was performed by ion conductivity and pH measurement. Serpentine dissolution in distilled water was evaluated as a stable pre-treatment process without changes of crystallographic structure and chemical structure changes.

TRACKING 파괴(破壞)에 미치는 계면활성(界面活性)의 영향 (THE EFFECT OF THE INTERFACE ACTIVE MATERIAL ON THE TRACKING FAILURE)

  • 이보호;박동화;고인환
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 1987년도 정기총회 및 창립40주년기념 학술대회 학회본부
    • /
    • pp.486-488
    • /
    • 1987
  • Studine the characteristic or C.T.I affectine on the tracking failure when interface active materials are diffused into the phenolic resin. we conclude as follow: 1) As the density of $NH_4Cl$ increase the quality or sludge increase the value of C.T.I decreases. 2) The materal of ion absorption can make the period of sludge metallic matal generation delay more than times and the value of C.T.I increase. 3) By addition of interface active material that makes forming period delay, the starting voltage of corona blackdown id delayed and the value of C.T.I is increased.

  • PDF

2$\times$2 InGaAsP/InP LD-gate 광스위치 연구

  • 오광룡;안주헌;김홍만;편광의
    • 한국광학회:학술대회논문집
    • /
    • 한국광학회 1995년도 광학 및 양자전자학 워크샵 논문집
    • /
    • pp.18-23
    • /
    • 1995
  • 광도파로와 반도체 광증폭기를 직접하여 1.3$\mu$m 과장대에서 동작하는 2x2 InGaAsP/InP LD-gate형 광스위치를 제작하였다. 광스위치의 특성으로 광섬유 입출력간의 총삽입 손실이 6~10dB 이었고, 소광비가 40dB 이상으로서 세계적인 수준의 양호한 결과를 얻었다. 제작된 광스위치는 광도파로와 반도체 광증폭기 간의 높은 광 결합 효율을 얻기 위하여 RIE(Reactive Ion Etching) 에 의한 건식 식긱과 4회에 걸친 OMVPE(Organo Metallic Vapor Phase Epitaxy) 결정 성장을 이용하였으녀, 수동 도파로와 LD 사이의 광 결합 효율이 '90% 이상이 됨을 확인하였다. d;라힌 결과는 광집적화의 연구에 상당한 기에를 할 것으로 기대된다.

  • PDF

탕그스텐의 용량분석법에 관하여 -Pb 아말감법 (Volumetric Determination of Tungsten Lead Amalgam Method)

  • 최규원;민경록
    • 대한화학회지
    • /
    • 제7권2호
    • /
    • pp.186-188
    • /
    • 1963
  • An attempt to improve the method of volumetric determination of tungsten developed by Luke has been made successfully. Using amalgam coated lead instead of pure metallic lead in the reduction procedure. W(VI)-W(III) reduction has been found to be quantitative in rather concentrated hydrochloric acid. Since there was no excessive dissolution of lead via reduction of hydrogen ion, lead surface was totally accessible for the reduction of tungsten and no trouble was caused by dereposition of $PbCl_2$ crystals at the nozzle of Jones reductor. Furthermore, it has been confirmed that almost 100 mg. of $WO_3$ can be handled easily if the chloride concentration of the HCl is increased by adding solid $NH_4Cl$.

  • PDF

AB INITIO CALCULATIONS OF STRONGLY CORRELATED ELECTRONS: ANTIFERROMAGNETIC GROUND STATE OF $UO_2$

  • YUN YOUNSUK;KIM HANCHUL;KIM HEEMOON;PARK KWANGHEON
    • Nuclear Engineering and Technology
    • /
    • 제37권3호
    • /
    • pp.293-298
    • /
    • 2005
  • We have performed the density functional theory calculations of $UO_2$ using the spin-polarized generalized gradient approximation (SP-GGA) and the SP-GGA+U approach. The SP-GGA+U approach correctly predicts the insulating electronic structure with antiferromagnetic ordering, but the SP-GGA calculations predict metallic behavior. The cohesive properties obtained from the SP-GGA+U calculations are in good agreement with the available experimental results and previous calculations. The spin-polarized local density of states shows that the antiferromagnetic ordering of $UO_2$ is governed by 5f orbitals of uranium ion. Our calculations demonstrate that the strong correlation of U 5f electrons should be taken into account for a reliable description of $UO_2$ physics.

표면 착색용 산화제를 이용한 컬러 콘크리트의 기초 연구 (A Fundamental Study on the Properties of Color concrete Using Stained Agent)

  • 박효진;이원영;이경현;최덕진;강철;김진만
    • 한국건축시공학회:학술대회논문집
    • /
    • 한국건축시공학회 2009년도 추계 학술논문 발표대회
    • /
    • pp.77-80
    • /
    • 2009
  • Because buildings which apply color that is various to concrete recently are introduced, value as design element of building is rising gradually in townscape. Even if expense is increased according as importance of concrete that have variety of design because do such social background and connection is emphasized, development of color concrete is pressing. Therefore, in this research, examined concrete physical & chemical characteristics by use of acid agent as part of research to embody diverse surface color of cement material. Here, embodiment of various color by unique color that stained hydrate has as that Color Concrete forms stained oxide that react with hydrate within concrete spreading stained agent that contain acid and metallic-ion in matrix that have cement ingredient on the surface is available.

  • PDF