이산화탄소 포획 원료용 사문석의 수용액 전처리 평가

Characterization of Aqueous Solution Pretreatment for Serpentine Used Carbondioxide Sequestration Material

  • 발행 : 2008.08.30

초록

Dissolution process of serpentine in distilled water was systematically investigated for study on pre-treatment of serpentine which was a candidate material for carbon dioxide sequestration. The metallic ions(Ca, Si, Mg etc.) were dissolved in distilled water at ambient condition and their concentrations were changed with dissolution time. The precise evaluation of dissolution process for serpentine dissolved solvent was performed by ion conductivity and pH measurement. Serpentine dissolution in distilled water was evaluated as a stable pre-treatment process without changes of crystallographic structure and chemical structure changes.

키워드

참고문헌

  1. C. Schmidt, S. Klara and R. Srivastava, "DOE Carbon Sequestration Program", US Department of Energy. Proceeding of the Electric Utilities Environmental Conference, Tucson, Arizona. 2002
  2. E. Bryant, "Climate process and change", Cambridge, UK: Cambridge University Press, 1997. p. 209
  3. 김미선, 윤영수, 심상준, 박태현, 이정국, "각종 현기성 미생물 발효에 의한 유기산 및 수소생산", 한국수소 및 신에너지학회 논문집, Vol. 13, No. 4, 2002, p. 330
  4. 심규성, 김창희, 박기배, "물의 전기분해에 의한 수소 제조기술과 경제성 분석", 한국수소 및 신에너지학회 논문집, Vol. 15, No. 4, 2004, p. 324
  5. K. S. Lackner, D. P. Butt and C. H. Wendt, "Progress on binding CO2 in mineral substrates", Energy Convers Manage, Vol. 38, 1997, pp. 259-264 https://doi.org/10.1016/S0196-8904(96)00279-8
  6. K. S. Lackner, C. H. Wendt, D. P. Butt, E. L. Joyce and D. H. Sharp, "Carbon dioxide disposal in carbonate minerals", Energy, Vol. 20, Issues 11, 1995, pp. 1153-1170 https://doi.org/10.1016/0360-5442(95)00071-N
  7. J. L. Post and L. Borer, "High-resolution infrared spectra, physical properties, and micromorphology of serpentines", Applied Clay Science, Vol. 16, Issues 1-2, 2000, pp. 73-85 https://doi.org/10.1016/S0169-1317(99)00047-2
  8. R. W. Luce, R. W. Bartlett, G. A Parks. "Dissolution kinetics of magnesium silicates", Geochimica et Cosmochimica Acta, Vol. 36, Issue 1, 1972, pp. 35-50 https://doi.org/10.1016/0016-7037(72)90119-6
  9. F.-C. Lin, C. V. Clemency. "The dissolution kinetics of brucite, antigorite, talc, and phlogopite at room temperature and pressure". American Mineralogist, Vol. 66, 1981, pp. 801-806
  10. P. Tartaj, A. Cerpa, M. T. García-González, C. J. Serna, "Surface instability of serpentine in aqueous suspensions", J. Colloid Interface Sci, Vol. 231, Issue 1, 2000, pp. 176-181 https://doi.org/10.1006/jcis.2000.7109
  11. 藤嶋昭, 相澤益男, 井上徹, 電氣化學測定法, 東京: 技報堂, 1994
  12. 逢坂 哲彌, 小山 昇, 大坂 武男, 電氣化學法 : 基礎測定マニュアル 東京 : 講談社, 1994
  13. 최원경, 문승현, 조태환, 이재근, "이산화탄소 탄산염광물화용 사문석의 열처리 및 특성평가", 한국수소 및 신에너지학회 논문집, Vol. 16, No. 1, 2005, pp. 74-81
  14. 최원경, 조태환, "이산화탄소 포획을 위한 serpentine의 열처리와 물리화학적 특성 변화 연구", 한국수소 및 신에너지학회 논문집, Vol. 18, No. 3, 2007, pp. 3016-308
  15. Wilson, M. Jeffrey, "A Handbook of Determinative Methods in Clays Mineralogy", Chapman and Hall, New York, 1987
  16. R. K. Schulze, M. A. Hill, Robert D. Field, P. A. Papin, Robert J. Hanrahan, D. D. Byler, "Characterization of carbonated serpentine using XPS and TEM", Energy Conversion and Management, Vol. 45, Issue 20, 2004, pp. 3169-3179 https://doi.org/10.1016/j.enconman.2004.02.003