• Progress in Superconductivity
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• v.3 no.2
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• pp.146-150
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• 2002

We performed the point contact spectroscopy on newly discovered superconductor $MgB_2$ thin films with Au tip. In the point contact spectroscopy of the metallic Sharvin limit, the differential conductance below the gap is twice as that above the gap by virtue of Andreev Reflection. After some surface cleaning processes of sample preparation such as ion-milling and wet etching, the obtained dI/dV versus voltage curves are relatively well fitted to the Blonder-Tinkham-Klapwijk (BTK) formalism. Gaps determined by this technique were distributed in the range of 3meV~ 8meV with the BCS value of 5.9meV in the weak coupling limit. We attribute these discrepancies to the symmetry of the gap parameter and the degradation of the surface of the sample. We also present the temperature dependence of the conductance vs voltage curve and thereby the temperature dependence of the gap.

• Journal of environmental and Sanitary engineering
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• v.17 no.3
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• pp.31-36
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• 2002

The effects of pH, time, dielectric constant of solvent and crosslink on adsorption of metal ions by resin(cryptand resin) adsorbent were investigated. The metal ions were showed fast adsorption on the resins in over pH 3. The equilibrium time for adsorption of metallic ions was about two hours and the adsorption selectivity determined in methanol was in increasing order $UO^{2+}$ > $Mn^{2+}$ > $Gd^{3+}$ ion. The adsorption was in the order of 1%, 2% and 5% crosslink resin and adsorption of resin decreased in proportion to the order of dielectric constant of solvents.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.08a
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• pp.270-270
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• 2010

4족 반도체 원소 양자점들은 원소가 가지고 있는 반도체적 성질과, 양자점에서 나타나는 quantum confinements 적인 특성 때문에 전자재료나 광학적 분야, 특히 태양전지 분야에서 그 쓰임이 대두되고 있다. 이러한 4족 반도체 원소의 양자점들을 만들기 위한 여러 방법들이 시도되고 있는데, 그 중에서 특히 절연체 박막에 4족 반도체 원소의 양자점들을 만드는 방법에는 이온주입, PVD, 그리고 CVD 를 통한 multi-layer 증착후 열처리 과정을 반드시 포함하는 Stranski- krastanov 방법이 주로 사용되고 있다. 본 실험에서는 고체원소 이온주입이라는 방법을 통해 절연체 박막의 증착과 이온주입이 한 진공용기 내에서 연속공정으로 이루어 지면서, 별도의 열처리 과정 없이 결정화된 게르마늄 양자점을 만들어 보았다. 이는 (X-ray diffraction) XRD와 Raman spectroscopy로 결정화된 게르마늄을 확인할 수 있었으며, (X-ray photoelectron spectroscopy)XPS 데이터로도 순수한 게르마늄이 표면에서 깊이 방향으로 약 $1,000\;{\AA}$ 만큼 게르마늄 양자점들이 만들어 짐을 알 수 있었다. 마지막으로 (High resolution transmittance electron microscopy) HRTEM으로 그 양자점의 크기와 분포도 그리고 결정성을 알아 보았다.

• Analytical Science and Technology
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• v.8 no.4
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• pp.631-636
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• 1995

Electrochemical properties of self-dopable poly(aniline N-butylsulfonate)s in various acidic medium were investigated by spectroelectrochemical techniques. Cyclic voltammetric study showed more than two reversible process of one electron transfer, the potential and peak intensity of which were dependent on the acid concentration and dopant ion. Spectroscopic study at different oxidation level indicated that the electrochromic switching of the poly(aniline N-alkylsulfonate)s film involves structural changes from benzenoid ring to quinoid ring. Spectrocyclic voltammetry together with impedance spectra of the PANBUS film in 0.1 M $LiClO_4$ solution of acetonitrile containing 0.46 M of perchloric acid showed two types of highly conductive states at the intermediate oxidation levels, which can be related to the metallic polaron states doped by two different process.

• Transactions of the Korean hydrogen and new energy society
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• v.19 no.4
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• pp.340-347
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• 2008

Dissolution process of serpentine in distilled water was systematically investigated for study on pre-treatment of serpentine which was a candidate material for carbon dioxide sequestration. The metallic ions(Ca, Si, Mg etc.) were dissolved in distilled water at ambient condition and their concentrations were changed with dissolution time. The precise evaluation of dissolution process for serpentine dissolved solvent was performed by ion conductivity and pH measurement. Serpentine dissolution in distilled water was evaluated as a stable pre-treatment process without changes of crystallographic structure and chemical structure changes.

• Proceedings of the KIEE Conference
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• 1987.11a
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• pp.486-488
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• 1987

Studine the characteristic or C.T.I affectine on the tracking failure when interface active materials are diffused into the phenolic resin. we conclude as follow: 1) As the density of $NH_4Cl$ increase the quality or sludge increase the value of C.T.I decreases. 2) The materal of ion absorption can make the period of sludge metallic matal generation delay more than times and the value of C.T.I increase. 3) By addition of interface active material that makes forming period delay, the starting voltage of corona blackdown id delayed and the value of C.T.I is increased.

• Proceedings of the Optical Society of Korea Conference
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• 1995.06a
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• pp.18-23
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• 1995

광도파로와 반도체 광증폭기를 직접하여 1.3$\mu$m 과장대에서 동작하는 2x2 InGaAsP/InP LD-gate형 광스위치를 제작하였다. 광스위치의 특성으로 광섬유 입출력간의 총삽입 손실이 6~10dB 이었고, 소광비가 40dB 이상으로서 세계적인 수준의 양호한 결과를 얻었다. 제작된 광스위치는 광도파로와 반도체 광증폭기 간의 높은 광 결합 효율을 얻기 위하여 RIE(Reactive Ion Etching) 에 의한 건식 식긱과 4회에 걸친 OMVPE(Organo Metallic Vapor Phase Epitaxy) 결정 성장을 이용하였으녀, 수동 도파로와 LD 사이의 광 결합 효율이 '90% 이상이 됨을 확인하였다. d;라힌 결과는 광집적화의 연구에 상당한 기에를 할 것으로 기대된다.

• Journal of the Korean Chemical Society
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• v.7 no.2
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• pp.186-188
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• 1963

An attempt to improve the method of volumetric determination of tungsten developed by Luke has been made successfully. Using amalgam coated lead instead of pure metallic lead in the reduction procedure. W(VI)-W(III) reduction has been found to be quantitative in rather concentrated hydrochloric acid. Since there was no excessive dissolution of lead via reduction of hydrogen ion, lead surface was totally accessible for the reduction of tungsten and no trouble was caused by dereposition of $PbCl_2$ crystals at the nozzle of Jones reductor. Furthermore, it has been confirmed that almost 100 mg. of $WO_3$ can be handled easily if the chloride concentration of the HCl is increased by adding solid $NH_4Cl$.

• Nuclear Engineering and Technology
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• v.37 no.3
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• pp.293-298
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• 2005

We have performed the density functional theory calculations of $UO_2$ using the spin-polarized generalized gradient approximation (SP-GGA) and the SP-GGA+U approach. The SP-GGA+U approach correctly predicts the insulating electronic structure with antiferromagnetic ordering, but the SP-GGA calculations predict metallic behavior. The cohesive properties obtained from the SP-GGA+U calculations are in good agreement with the available experimental results and previous calculations. The spin-polarized local density of states shows that the antiferromagnetic ordering of $UO_2$ is governed by 5f orbitals of uranium ion. Our calculations demonstrate that the strong correlation of U 5f electrons should be taken into account for a reliable description of $UO_2$ physics.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2009.11a
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• pp.77-80
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• 2009

Because buildings which apply color that is various to concrete recently are introduced, value as design element of building is rising gradually in townscape. Even if expense is increased according as importance of concrete that have variety of design because do such social background and connection is emphasized, development of color concrete is pressing. Therefore, in this research, examined concrete physical & chemical characteristics by use of acid agent as part of research to embody diverse surface color of cement material. Here, embodiment of various color by unique color that stained hydrate has as that Color Concrete forms stained oxide that react with hydrate within concrete spreading stained agent that contain acid and metallic-ion in matrix that have cement ingredient on the surface is available.