• Title/Summary/Keyword: metal reduction

Search Result 1,688, Processing Time 0.029 seconds

Effects of Drawing Parameters on Mechanical Properties of BAS121 Alloy Tubes for Heat-exchangers by High Frequency Induction Welding (고주파유도용접된 열교환기용 BAS121합금튜브의 기계적 특성에 미치는 인발조건의 영향)

  • Han Sang-Woo;Kim Byung-Il;Lee Hyun-Woo;Chon Woo-Young;Gook Jin-Seon
    • Korean Journal of Materials Research
    • /
    • v.14 no.12
    • /
    • pp.851-856
    • /
    • 2004
  • The aim of this study is to investigate the optimum drawing parameter for BAS121 welded tubes. The BAS121 aluminium alloy tubes with 25 mm in external diameter and 1.3 mm in thickness for heat-exchangers were manufactured by high frequency induction welding with the V shaped convergence angle $6.5^{\circ}$ and power input 55 kW. With increasing the reduction of area ($13,\;21\%$) by drawing, tensile strength was increased and elongation was decreased. With increasing the reduction of area by drawing, hardness in weld metal increased rapidly, while that of base metal increased slowly. In the specimen with the outer diameter smaller than 22 mm, hardness of weld metal was higher than that of base metal. The optimum drawing parameter of area reduction in BAS121 alloys was estimated about $13\%$ because of the work hardening of welds.

Metal artifact production and reduction in CBCT with different numbers of basis images

  • Queiroz, Polyane Mazucatto;Santaella, Gustavo Machado;Groppo, Francisco Carlos;Freitas, Deborah Queiroz
    • Imaging Science in Dentistry
    • /
    • v.48 no.1
    • /
    • pp.41-44
    • /
    • 2018
  • Purpose: To evaluate the effect of different numbers of basis images and the use of metal artifact reduction (MAR) on the production and reduction of artifacts in cone-beam computed tomography images. Materials and Methods: An acrylic resin phantom with a metal alloy sample was scanned, with 450 or 720 basis images and with or without MAR. Standard deviation values for the test areas (around the metal object) were obtained as a way of measuring artifact production. Two-way analysis of variance was used with a 5% significance level. Results: There was no significant difference in artifact production among the images obtained with different numbers of basis images without MAR (P=.985). MAR significantly reduced artifact production in the test areas only in the protocol using 720 basis images (P=.017). The protocol using 450 basis images with MAR showed no significant difference in artifact production when compared to the protocol using 720 basis images with MAR (P=.579). Conclusion: Protocols with a smaller number of basis images and with MAR activated are preferable for minimizing artifact production in tomographic images without exposing the patient to a greater radiation dose.

Application of Hard Porous Pad in Metal CMP Process (금속 CMP 공정시 경질 다공성 패드의 적용)

  • 김상용;김남훈;김인표;장의구
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.16 no.5
    • /
    • pp.385-389
    • /
    • 2003
  • There are four main components of the CMP process: polishing pad, slurry, elastic supporter, and pad conditioner. The polishing pad is an essential component to the reproducibility of polishing uniformity in CMP process. However, the polishing pad in recently using metal CMP raised the several points of high cost caused by the increase of cycle time and the many usage of slurry. It is necessary to develop the novel polishing pad which would lead the cost reduction by the higher pad life-cycle, minimized cycle time and lower slurry usage. The characteristics of polishing pad were studied on the effects of different sets of the Polishing pad, which can be applied to metal chemical mechanical polishing process for global planarization of multilevel interconnection structure. The main purpose of this experiment is cost reduction by the increase of pad life-time, the decrease of cycle time and the lower usage of slurry through the specific hard porous structured pad design. It is confirmed that the novel polishing pad made the slurry usage decrease to 60% as well as the pad life-time increase twice with the 25% improvement of removal rate. The polishing time could be decreased and it also helped the cycle time to diminish. It can be expected that this results will help both the process throughput and the device yield to be improved.

Catalytic Removal of Nitric Oxide in Oxygen-Rich Exhaust with Methane over Metal Ion-Exchanged Zeolites (금속이온교환 제올라이트 촉매상에서 메탄을 이용한 산소과잉 배출가스중의 NO 제거)

  • 김상환;박정규
    • Transactions of the Korean Society of Automotive Engineers
    • /
    • v.10 no.1
    • /
    • pp.32-44
    • /
    • 2002
  • Selective catalytic reduction of nitric oxide by methane in the presence of excess oxygen was investigated over copper and cobalt ion-exchanged ZSM-5 zeolites. Copper ion-exchanged ZSM-5(Cu-ZSM-5) has the limitations for commercial applications to lean-bum gasoline and diesel engines due to low thermal stability and resistance to water vapor and sulfur dioxide. But cobalt ion-exchanged ESM-5(Co-ZSM-5) is more active at high temperatures and also stable to water vapor and sulfur dioxide for catalytic reduction of nitric oxide by methane. The catalytic activity of Cu-ZSM-5 for NO reduction increases with increasing temperatures, reaches the maximum conversion of 23.0% at 350\"C. and then decreases with higher temperatures. In the meantime catalytic activities of Co-ZSM-5 show the maximum conversion of 25.8% at $500^{\circ}C$ Therefore Co-ZSM-5 catalysts have higher thermal stability at high temperatures. Catalytic activities of both zeolites were remarkably enhanced with the existence of oxygen in the exhaust. It is noted that the catalytic activity of Cu-ZSM-5 decreases with the increasing concentration of methane while the catalytic activity of Co-ZSM-5 decreases with increasing contents of methane in the exhaust. This may imply the existence of different paths of NO reduction by methane in the presence of excess oxygen fur Cu-ZSM-5 and Co-ZSM-5 catalysts. For binary metal ionexchanged ZSM-5, the primary ion-exchanged metal may be masked by secondary ion-exchanged component, which plays the important role for catalytic activities of binary metal ion-exchanged ZSM-5, Therefore CuCo-ZSM-5 catalysts show the similar volcano-shaped curves to Cu-ZSM-5 catalysts between the activity and temperature. It Is interesting that the activities of CoCu-ZSM-5 catalysts indicate almost no dependence on the concentration of methane in the exhaust.aust.

Electrochemical Studies on Ion Recognition of Alkali Metal Cations by 18-crown-6 in Methanol

  • Chi-Woo Lee;Chang-Hyeong Lee;Doo-Soon Shin;Si-Joong Kim
    • Bulletin of the Korean Chemical Society
    • /
    • v.12 no.5
    • /
    • pp.487-490
    • /
    • 1991
  • Electrochemical studies of alkali metal cations $(Na^+, K^+, Rb^+, Cs^+)$ were performed in methanolic solutions of 18-crown-6 and tetrabutylammonium salts at dropping mercury electrodes (DME) and thin mercury film electrodes (TMFE). All the cations investigated were reduced reversibly at DME in the absence and presence of 18-crown-6, and in the latter the limiting currents were decreased and the reduction potentials shifted to the negative direction. The reduction potentials of the metal ions (0.2 mM) in the presence of the crown (10 mM) were - 2.14 $(Na^+)$, - 2.26 $(K^+)$, - 2.20 $(Rb^+) and - 2.14 $(Cs^+)$ V vs. SCE, respectively. The measured potentials were rationalized with ion recognition of the cations by the crown. Electroreduction at TMFE were highly irreversible. A new representation method of ion recognition is presented. In aqueous solutions, electroreduction of the alkali metal ions were characterized by adsorption.

Nano Electrocatalysis for Fuel Cells

  • Sung, Yung-Eun
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2013.02a
    • /
    • pp.133-133
    • /
    • 2013
  • For both oxygen reduction (ORR) and hydrogen oxidation reactions (HOR) of proton electrolyte membrane fuel cells (PEMFCs), alloying Pt with another transition metal usually results in a higher activity relative to pure Pt, mainly due to electronic modification of Pt and bifunctional behaviour of alloy surface for ORR and HOR, respectively. However, activity and stability are closely related to the preparation of alloy nanoparticles. Preparation conditions of alloy nanoparticles have strong influence on surface composition, oxidation state, nanoparticle size, shape, and contamination, which result from a large difference in redox priority of metal precursors, intrinsic properties of metals, increasedreactivity of nanocrystallites, and interactions with constituents for the synthesis such as solvent, stabilizer, and reducing agent, etc. Carbon-supported Pt-Ni alloy nanoparticles were prepared by the borohydride reduction method in anhydrous solvent. Pt-Ru alloy nanoparticles supported on carbon black were also prepared by the similar synthetic method to that of Pt-Ni. Since electrocatalytic reactions are strongly dependent on the surface structure of metal catalysts, the atom-leveled design of the surface structure plays a significant role in a high catalytic activity and the utilization of electrocatalysts. Therefore, surface-modified electrocatalysts have attracted much attention due to their unique structure and new electronic and electrocatalytic properties. The carbon-supported Au and Pd nanoparticles were adapted as the substrate and the successive reduction process was used for depositing Pt and PtM (M=Ru, Pd, and Rh) bimetallic elements on the surface of Au and Pd nanoparticles. Distinct features of the overlayers for electrocatalytic activities including methanol oxidation, formic acid oxidation, and oxygen reduction were investigated.

  • PDF

A Study on the Leachate Characteristics of Heavy Metals from MSW Bottom Ash Solidified with Stabilizing Reagents (안정화제를 첨가한 생활폐기물 소각시설 바닥재의 중금속 용출특성에 관한 연구)

  • Lim, Jong-Wan;Dong, Jong-In
    • Applied Chemistry for Engineering
    • /
    • v.26 no.6
    • /
    • pp.692-697
    • /
    • 2015
  • In this study, the reduction efficiencies of leachate heavy metal levels were investigated by adding $Al_2O_3$ and CaO to the bottom ash to observe their effects on the heavy metals leachate reduction efficiency. The ratio of $Al_2O_3$ and CaO contents were varied by 10~40% (W/W) alongside different curing time of 7 and 28 days. The reduction efficiencies of leachate heavy metal levels were estimated to be 69.3% for Cu and 52.1% for Pb during the curing time of 7 days. For the curing time of 28 days, the efficiencies changed to 85.2 and 100% for Cu and Pb, respectively. It was thus confirmed that the high reduction efficiency could be obtained as the curing time increased.

Sensitivities of Salmonella typhimurium and Staphylococcus aureus to Ozonation in the Presence of Soluble Starch and Metal Ion Complex

  • Kim, Kee-Il;Kang, Suk-Nam;Lee, Ok-Hwan;Park, Jeong-Hyun
    • Food Science and Biotechnology
    • /
    • v.17 no.4
    • /
    • pp.842-845
    • /
    • 2008
  • This study was carried out to investigate the bactericidal efficacy of concentration (0.1, 0.2, and 0.4 ppm) and exposure time (10 and 30 min) of ozone on bacterial reduction rate of Salmonella typhimurium KCTC 2541 and Staphylococcus aureus ATCC 13515 in the distilled water (DW), and DW supplemented with 0.2% soluble starch (SS), and metal ion (MC) using argentums (Ag) and copper (Cu). The significant bactericidal differences of S. aureus were showed in the treatments of DW and SS, respectively, at the concentration of ozone above 0.1 ppm for 10 min, comparing the respective initial bacterial counts. The bacterial reduction of S. aureus was more sensitive than that of S. typhimurum at the same concentration of ozone. The bacterial reduction rate of SS treatment was slightly lower than that of DW treatment at the same concentration of ozone (p<0.05), however, the bacterial reduction rate of strains improved in the MC treatment compared to the DW treatment at the same concentration of ozone.

Preparation of LaGaO3 Based Oxide Thin Film on Porous Ni-Fe Metal Substrate and its SOFC Application

  • Ju, Young-Wan;Matsumoto, Hiroshige;Ishihara, Tatsumi;Inagaki, Toru;Eto, Hiroyuki
    • Journal of the Korean Ceramic Society
    • /
    • v.45 no.12
    • /
    • pp.796-801
    • /
    • 2008
  • $LaGaO_3$ thin film was prepared on Ni-Fe metal porous substrate by Pulsed Laser Deposition method. By the thermal reduction, the dense $NiO-{Fe_3}{O_4}$ substrate is changed to a porous Ni-Fe metal substrate. The volumetric shrinkage and porosity of the substrate are controlled by the reduction temperature. It was found that a thermal expansion property of the Ni-Fe porous metal substrate is almost the same with that of $LaGaO_3$ based oxide. $LaGaO_3$ based electrolyte films are prepared by the pulsed laser deposition (PLD) method. The film composition is sensitively affected by the deposition temperature. The obtained film is amorphous state after deposition. After post annealing at 1073K in air, the single phase of $LaGaO_3$ perovskite was obtained. Since the thermal expansion coefficient of the film is almost the same with that of LSGM film, the obtained metal support LSGM film cell shows the high tolerance against a thermal shock and after 6 min startup from room temperature, the cell shows the almost theoretical open circuit potential.