• Title/Summary/Keyword: metal oxides.

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Preparation and Analysis of High Functional Silicone Hydrogel Lens Containing Metal Oxide Nanoparticles by Photopolymerizaion

  • Heo, Ji-Won;Sung, A-Young
    • Korean Journal of Materials Research
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    • v.32 no.4
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    • pp.193-199
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    • 2022
  • In this study, lenses are fabricated using various nanomaterials as additives to a silicone polymer made with an optimum mixing ratio and short polymerization time. In addition, PVP is added at a ratio of 1 % to investigate the physical properties according to the degree of dispersion, and the compatibility with hydrophobic silicone and the possibility of application as a functional lens material are confirmed. The main materials are SIU as a silicone monomer, DMA, a hydrophilic copolymer, EGDMA as a crosslinking agent, and 2H2M as a photoinitiator. Holmium (III) oxide, Europium (III) oxide, aluminum oxide, and PVP are used. When Holmium (III) oxide and Europium (III) oxide are added based on the Ref sample, the characteristics of the lens tend to be similar overall, and the aluminum oxide shows a tendency slightly different from the previous two oxides. This material can be used as a silicone lens material with various nano oxides and polyvinylpyrrolidone (PVP) acting as a dispersant.

Characterization of Compacted and Pressureless Sintered Parts for Molybdenum Oxide Powder according to Hydrogen Reduction Temperature (수소 환원 온도에 따른 몰리브덴 산화물의 성형 및 상압소결특성 평가)

  • Jong Hoon Lee;Kun-Jae Lee
    • Journal of Powder Materials
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    • v.31 no.4
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    • pp.336-341
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    • 2024
  • Molybdenum, valued for its high melting point and exceptional physical and chemical properties, is studied in diverse fields such as electronics, petrochemicals, and aviation. Among molybdenum oxides, molybdenum dioxide stands out for its higher electrical conductivity than other transition metal oxides due to its structural characteristics, exhibiting metallic properties. It is applied as pellets to gas sensors, semiconductors, and secondary batteries for its properties. Thus, research on molybdenum dioxide compaction and pressureless sintering is necessary, yet research on pressureless sintering is currently insufficient. This study synthesized MoO3 powder via solution combustion synthesis and reduced it using the 3% hydrogen/argon gas mixture to investigate the effect of reduction temperature on the powder. Additionally, the reduced powder was compacted and subjected to pressureless sintering with temperature as a variable. The density and the microstructure of brown parts were analyzed and discussed.

Synthesis of Nanoporous Metal Oxide Films Using Anodic Oxidation and Their Gas Sensing Properties

  • Suh, Jun Min;Kim, Do Hong;Jang, Ho Won
    • Journal of Sensor Science and Technology
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    • v.27 no.1
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    • pp.13-20
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    • 2018
  • Gas sensors based on metal oxide semiconductors are used in numerous applications including monitoring indoor air quality and detecting harmful substances like volatile organic compounds. Nanostructures, for example, nanoparticles, nanotubes, nanodomes, and nanofibers have been widely utilized to improve gas sensing properties of metal oxide semiconductors, and this increases the effective surface area, resulting in participation of more target gas molecules in the surface reaction. In the recent times, 1-dimensional (1D) metal oxide nanostructures fabricated using anodic oxidation have attracted great attention due to their high surface-to-volume ratio with large-area uniformity, reproducibility, and capability of synthesis under ambient air and pressure, leading to cost-effectiveness. Here, we provide a brief overview of 1D metal oxide nanostructures fabricated by anodic oxidation and their gas sensing properties. In addition, recent progress on thin film-based anodic oxidation for application in gas sensors is introduced.

An Overview of Self-Grown Nanostructured Electrode Materials in Electrochemical Supercapacitors

  • Shinde, Nanasaheb M.;Yun, Je Moon;Mane, Rajaram S.;Mathur, Sanjay;Kim, Kwang Ho
    • Journal of the Korean Ceramic Society
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    • v.55 no.5
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    • pp.407-418
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    • 2018
  • Increasing demand for portable and wireless electronic devices with high power and energy densities has inspired global research to investigate, in lieu of scarce rare-earth and expensive ruthenium oxide-like materials, abundant, cheap, easily producible, and chemically stable electrode materials. Several potential electrode materials, including carbon-based materials, metal oxides, metal chalcogenides, layered metal double hydroxides, metal nitrides, metal phosphides, and metal chlorides with above requirements, have been effectively and efficiently applied in electrochemical supercapacitor energy storage devices. The synthesis of self-grown, or in-situ, nanostructured electrode materials using chemical processes is well-known, wherein the base material itself produces the required phase of the product with a unique morphology, high surface area, and moderate electrical conductivity. This comprehensive review provides in-depth information on the use of self-grown electrode materials of different morphologies in electrochemical supercapacitor applications. The present limitations and future prospects, from an industrial application perspectives, of self-grown electrode materials in enhancing energy storage capacity are briefly elaborated.

Efficiency Improvement of Metal-Mesh Electrode Type Photoelectrochemical Cells by Oxides Layer Coatings (산화물박막 증착에 의한 금속 메쉬전극 구조 광전기화학셀의 효율 개선에 관한 연구)

  • Han, Chi-Hwan;Park, Seon-Hee;Sung, Youl-Moon
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.60 no.3
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    • pp.584-587
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    • 2011
  • In this work, the $TiO_2$ and $SnO_2$ thin films as blocking layers were coated directly onto the metal-mesh electrode surface to prevent unnecessary inflow of back-transfer electrons from the electrolyte ($I^-/I_3^-$) to the metal-mesh electrode. The DSCs were fabricated with working electrode of SUS mesh coated with blocking $TiO_2$ and $SnO_2$ layers, dye-attached mesoporous $TiO_2$ film, gel electrolyte and counter electrode of Pt-deposited F:$SnO_2$. From the experimental result, it was ascertained that the efficiency of metal electrode coated with $TiO_2$ by Dip-coating was superior to that of metal electrode coated with $SnO_2$ by Dip-coating and screen printing with the results of experiments. The photo-current conversion efficiency of the cell obtained from optimum fabrication condition was 3% ($V_{oc}$=0.61V, $J_{sc}$=11.64 mA/$cm^2$, ff=0.64) under AM1.5, 100 mW/$cm^2$ illumination.

Development of Pre-treatment for Tin Recovery from Waste Resources (주석 함유 폐자원의 공정부산물 전처리 기술)

  • Jin, Y.H.;Jang, D.H.;Jung, H.C.;Lee, K.W.
    • Journal of Powder Materials
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    • v.21 no.2
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    • pp.142-146
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    • 2014
  • Fundamental experiences have been studied for development of pre-treatment process of Sn by-products such as solders. Dry and wet separation/recovery processes were considered by the differences of physical properties. The by-products, which are analyzed by solder metal and oxides. The metal and oxide were simply separated by dry ball-milling process for 12 hours, after that recovery metal powder might be reusable as lead or lead-free solders. In terms of wet separation process, samples were dissolved in $HNO_3+H_2O_2$ and the precipitation were analyzed by $SnO_2$. Overall efficiency of recovery might be increasing via developing simple pre-treatment process.

Preparation of nano composite metal-oxide electrode and its application for superrcapacitor (나노복합산화물 전극의 제조 및 수퍼커패시터로써의 응용)

  • Kim, Hong-Il;Lee, Ju-Won;Kim, Sang-Gil;Yuk, Gyung-Chang;Park, Soo-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.801-804
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    • 2002
  • Electrochemical capacitors are becoming attractive energy storage systems particularly for applications involving high power requirements such as hybrid systems consisting of batteries and electrochemical capacitors for electric vehicle propulsion. Both of amorphous cobalt oxide and manganese dioxide were prepared by sol-gel process reported in our previous work. Nanostructured supramolecular oligomer of 1,5-diaminoanthraquinone(DAAQ) coated metal oxides were successfully prepared by electrochemical oxidation from an acidic non-aqueous medium. We established process parameters of the technique for the formation of nano-structured materials. Furthermore, improved the capacitive properties of the nano structured metal oxide electrodes using controlled solution chemistry. $CoO_2$ and $MnO_2$-based composite electrode showed relatively good electrochemical behaviors in acidic electrolyte system with respect to specific capacity and scan rate dependency.

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Study of Plasma Process Induced Damages on Metal Oxides as Buffer Layer for Inverted Top Emission Organic Light Emitting Diodes

  • Kim, Joo-Hyung;Lee, You-Jong;Jang, Jin-Nyoung;Song, Byoung-Chul;Hong, Mun-Pyo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.543-544
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    • 2008
  • In the fabrication of inverted top emission organic light emitting diodes (ITOLEDs), the organic layers are damaged by high-energy plasma sputtering process for transparent top anode. In this study, the plasma process induced damages on metal oxide hole injection layers (HILs) including $WO_3$, $MoO_3$, and $V_2O_5$ as buffer layer are examined. With the result of IV characteristic of hole-only devices, we propose that $MoO_3$ and $V_2O_5$ are stable materials against plasma sputtering process.

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A New Chemical for the Separation of the CRT Panel Glass from its Funnel

  • Lee, Ki-Won;Byun, Ji-Young;Kim, Kyong-Tae;Oh, Jong-Kee
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.71-75
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    • 2001
  • The first step for recycling the CRT bulb is to remove frist seals between the panel and funnel. For this purpose, various kinds of methods have been used. One of those is to use the nitric acid, which is a proven technology and widely used in CRT-making industries. The process. however. has a problem of NOx generation. Such a drawback can be overcome by using a new chemical. This new chemical can remove the frit without NOx generation. This paper describes the dissolution ability of the chemical for lead and zinc oxides and the application to the separation of the CRT panel from its funnel.

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The effect of interfacial layer thickness on the interface dipole energy in $O_2$ plasma treated metal/organic interface

  • Kim, Soo-Young;Lee, Jong-Lam
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.115-117
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    • 2009
  • Interface dipole energies between interfacial layers with different thicknesses coated on indium tin oxides (ITOs) and 4,4'-bis[N-(1-naphtyl)-N-phenyl-amino]biphenyl are determined. After $O_2$ plasma treatment on thick-metal (>4 nm) coated ITO, the work function and interface dipole energy increased. In thin-metal (< 2 nm) coated ITO, no change in the interface dipole energy was found though the work function increased. Thus, the $O_2$ plasma treated thin (< 2 nm) interfacial layer reduced the hole injection barrier.

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