• Title/Summary/Keyword: metal electrode

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Crystallographic Relationships of (Ba, Sr) $TiO_3$Thin Film Prepared by Metal-Organic Chemical Vapor Deposition on (111) Textured Pt Electrode

  • Yoo, Dong-Chul;Lee, Jeong-Yong
    • Journal of the Korean Ceramic Society
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    • v.37 no.11
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    • pp.1126-1129
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    • 2000
  • The crystallographic orientations of $Ba_{0.6}$S $r_{0.4}$Ti $O_3$(BST) thin film deposited by a metal-organic chemical vapor deposition on (111) textured Pt electrode were studied with a transmission electron microscopy. The fully crystallized BST thin film (50nm) has (100) and (110) preferred orientations. A high resolution transmission electron microscopy study has revealed the crystallographic orientation relationships between BST thin film and Pt electrode. These relationships explained the preferred orientation of BST film on (111) textured Pt electrode. With these results, we could represent the atomic arrangement at the BST/Pt interface.e.e.

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Electrocatalytic Reduction of Thionyl Chloride by Schiff Base Metal(II) Complexes (1)

  • Sin, Mi Suk;Kim, U Seong;Jo, Gi Hyeong;Choe, Yong Guk
    • Bulletin of the Korean Chemical Society
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    • v.16 no.3
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    • pp.205-210
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    • 1995
  • Catalytic effects of various Schiff base metal(II) complexes on the reduction of thionyl chloride at glassy carbon electrode are evaluated by determining the kinetic parameters from cyclic voltammetry technique. The charge transfer process is affected strongly by the concentration of catalysts during the reduction of thionyl chloride. The catalytic effects are shown by both a shift of the reduction potential for thionyl chloride toward more positive direction and an increase in peak current. The diffusion coefficient value, Do, of the 8.17 ${\times}$ 10-9 $cm^2/s$ was observed at the bare glassy carbon electrode, whereas larger values (0.9-1.09 ${\times}$ 10-8 $cm^2/s$) were observed at the catalyst supported glassy carbon electrode. Significant improvements in the cell performance have been noted in terms of both exchange rate constants and current densities at glassy carbon electrode.

A Study on Fume Formation Ratio on Flux Cored Arc Welding Process (플럭스 코어드 아크 용접 공정에서의 흄 형성량에 관한 연구)

  • Yoon, Chung-Sik;Paik, Nam-Won
    • Journal of Environmental Health Sciences
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    • v.25 no.3
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    • pp.108-112
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    • 1999
  • A study was conducted for the effects of input energy on fume formation ratios based on electrode(FFR$_{electrode}(g/kg_{electrode})),\;deposited\;metal(FFR_{weld}(g/kg_{weld}))\;and\;slag(FFR_{slag}(g/kg_{slag}))\;at\;CO_2$ flux cored arc welding on stainless steel. Experiments were run in well designed welding fume box. Six types of flux cored wires were used and three levels of current and voltages were given. The measured values of $FFR_{electrode},\;FFR_{weld},\;FFR_{slag}\;are\;7.90{\pm}1.47\;g/kg_{electrode},\;9.18{\pm}1.65\;g/kg_{\electrode},\;71.8{\pm}24.2\;g/kg_{slag}$ respectively. Fume formation ratios are not increased dramatically by input energy because of simultaneous increasing of melted electrodes, deposited metal and slag. The results indicate that the test of fume formation ratios in the research on production of low fume welding wire can be run at the fixed condition of input energy rather than various condition.

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Study on Surface Plasmon Electrode Using Metal Nano-Structure for Maximizing Sterilization of Dielectric Discharge (유전체 방전 살균 극대화를 위한 금속 나노 구조를 이용한 표면 플라즈몬 전극에 관한 연구)

  • Ki, Hyun-Chul;Oh, Byeong-Yun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.2
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    • pp.80-84
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    • 2018
  • In this study, we investigated plasmon effects to maximize the sterilization of dielectric discharge. We predicted the effect using the finite difference time domain (FDTD) method as a function of electrode shape, size, and period. The structure of the electrode was designed with a thickness of 100 nm of silver nanoparticles on a glass substrate, and was varied according to the shape, size, and period of the electrode hole. Based on the results, it was confirmed that the effect of plasmons was independent of the shape of the electrode hole. It was thus confirmed that the plasmon effect depended only on the size and period of the holes. Further, the plasmon effect was affected by the size rather than period of the holes. Because the absorption of light by the metal varied according to the size of the hole, the plasmon effect generated by the absorption of light also varied. The best results were obtained when the radius and period of the electrode holes were $0.1{\mu}m$ and $0.4{\mu}m$, respectively.

The Coating Materials of Electrode Materials on Machinability of W-EDM (와이어전극의 도금재료가 W-EDM 가공성에 미치는 영향)

  • 김창호;허관도
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2000.05a
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    • pp.735-738
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    • 2000
  • The characteristics of wire electrical discharge machining (WEDM) are governed by many factors such as the power supply type, operating condition and electrode material. This work deals with the effect of wire electrode materials on the machining characteristics such as, metal removal rate, surface characteristics and surface roughness during WEDM A wire's thermal physical properties are melting point, electrical conductivity and vapor pressure. One of the desired qualities of wire is a low melting point and high vapor pressure to help expel the contaminants from the gap. They are determined by the mix of alloying elements (in the case of plain brass and coated wire) or the base core material(i.e. molybdenum). Experiments have been conducted regarding the choice of suitable wire electrode materials and influence of the properties of these materials on the machinability and surface characteristics in WEDM, the experimental results are presented and discussed from their metallurgical aspect. And the coating effect of various alloying elements(Au, Ag, Cu, Zn, Cr, Mn, etc.) to the Cu or 65-35 brass core on them was reviewed also. The removal rate of some coated wires are higher than that of 65-35 brass electrode wire because the wire is difficult to break due to the wire cooling effect of Zn evaporation latent heat and the Zn oxide on the surface is effective in preventing short circuit. The removal rate increases with increasing Zn content from 35, 40 and Zn coated wire

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Effect of Adhesion Strength Between Flexible Substrates and Electrodes on the Durability of Electrodes (유연 기판과 전극 사이의 접합력이 전극의 내구성에 미치는 영향)

  • Doyeon Im;Byoung-Joon Kim;Geon Hwee Kim;Taechang An
    • Journal of Sensor Science and Technology
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    • v.33 no.2
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    • pp.86-92
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    • 2024
  • Flexible electronic devices are exposed to repeated mechanical deformation; therefore, electrode performance is an important element. Recently, a new technology has been developed to improve the adhesion strength between polymer substrates and metal thin films through the cross-linking reaction of bovine serum albumin (BSA) bioconjugation proteins; however, additional performance evaluation as an electrode is necessary. Therefore, in this study, we investigated the effect of adhesive strength between a flexible substrate and a metal thin film on the performance of a flexible electrode. Cracks and changes in the electrical resistance of the electrode surface were observed through outer bending fatigue tests and tensile tests. As a result of a bending fatigue test of 50,000 cycles and a tensile test at 10% strain, the change in the electrical resistance of the flexible electrode with a high adhesion strength was less than 40%, and only a few microcracks were formed on the surface; thus, the electrical performance did not significantly deteriorate. Through this study, the relationship between the adhesion strength and electrical performance was identified. This study will provide useful information for analyzing the performance of flexible electrodes in the commercialization of flexible electronic devices in the future.

Effect of Microstructure on Electrical Properties of Thin Film Alumina Capacitor with Metal Electrode (금속 전극 알루미나 박막 캐패시터의 전기적 특성에 미치는 미세구조의 영향)

  • Jeong, Myung-Sun;Ju, Byeong-Kwon;Oh, Young-Jei;Lee, Jeon-Kook
    • Korean Journal of Materials Research
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    • v.21 no.6
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    • pp.309-313
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    • 2011
  • The power capacitors used as vehicle inverters must have a small size, high capacitance, high voltage, fast response and wide operating temperature. Our thin film capacitor was fabricated by alumina layers as a dielectric material and a metal electrode instead of a liquid electrolyte in an aluminum electrolytic capacitor. We analyzed the micro structures and the electrical properties of the thin film capacitors fabricated by nano-channel alumina and metal electrodes. The metal electrode was filled into the alumina nano-channel by electroless nickel plating with polyethylene glycol and a palladium catalyst. The spherical metals were formed inside the alumina nano pores. The breakdown voltage and leakage current increased by the chemical reaction of the alumina layer and $PdCl_2$ solution. The thickness of the electroless plated nickel layer was 300 nm. We observed the nano pores in the interface between the alumina layer and the metal electrode. The alumina capacitors with nickel electrodes had a capacitance density of 100 $nF/cm^2$, dielectric loss of 0.01, breakdown voltage of 0.7MV/cm and leakage current of $10^4{\mu}A$.

Research on Transparent LED Display with Use of Metal Mesh (메탈메쉬를 활용한 투명 LED 디스플레이에 관한 연구)

  • Hwang, In-Kwan;Roh, Su-Sung
    • The Journal of the Korea Contents Association
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    • v.15 no.10
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    • pp.10-17
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    • 2015
  • Transparent LED display is providing city residents with different attractions via information services and landscape and increasing demand is detected in various areas. It is true that majority of the current demand in transparent electrode material was found and used in ITO but limitations in capacity and economic efficiency led to the need for continuous research and technology development via new materials. As a new material, metal mesh has 85% of the materials to substitute ITO and is widely used due to low-cost and high-conductive rate. Maintenance of transparent LED display utilizing metal mesh compared to existing ITO transparent display is much easier as it not only saves resources but is also economical. Thus the objective of this paper lies in proposing the utilization of metal mesh in transparent LED display prototype to enable economical use of transparent LED display technology and to expand the market and to also propose transparent LED display development method via metal mesh and manufacture a prototype based on the method. And a characteristic comparison test between ITO and metal mesh provides the possibility of using metal mesh as a transparent electrode material in transparent LED display development.

Analysis of Degradation Phenomena in Arc-Tube of Ceramic Metal Halide Lamp (세라믹 메탈할라이드 램프의 아크튜브 열화현상 분석)

  • Kim, Woo-Young;Lee, Se-Il;Yang, Jong-Kyung;Jang, Hyeok-Jin;Park, Dae-Hee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.12
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    • pp.996-1001
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    • 2010
  • Recently, the demand of ceramic metal halide lamp has been expanded. Therefore, the lamp with high efficiency and long lifetime are increasing and the evaluation of reliability is needed. In this paper, the degradation phenomena of ceramic metal halide lamp was studied. The lamp was tested for 3000 on/off cycles with each cycle having a duration of 20 minutes on and 20 minutes off based on the accelerated aging experiment based on "Reliability Standards RS C 0085". As result, the corrosion of arc tube and leak was appeared from reaction between inner wall of PCA and chemical elements, and distortion of electrode was resulted from difference of thermal expansion between arc tube of PCA and electrode. Also, the efficiency of lamp was decreased by the change of inner pressure, operation temperature, and driving voltage from wall blackening.

Development of Alkali Metal Thermal-to-Electric Converter Unit Cells Using Mo/TiN Electrode

  • Seog, Seung-won;Choi, Hyun-Jong;Kim, Sun-Dong;Lee, Wook-Hyun;Woo, Sang-Kuk;Han, Moon-Hee
    • Journal of the Korean Ceramic Society
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    • v.54 no.3
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    • pp.200-204
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    • 2017
  • Molybdenum (Mo), an electrode material of alkali metal thermal-to-electric converters (AMTEC), facilitates grain growth behavior and forms Mo-Na-O compounds at high operating temperatures, resulting in reduced performance and shortened lifetime of the cell. Mo/TiN composite materials have been developed to provide a solution for such issues. Mo is a metal that possesses excellent electrical properties, and TiN is a ceramic compound with high-temperature durability and catalytic activity. In this study, a dip-coating process with an organic solvent-based slurry was used as an optimal coating method to achieve homogeneity and stability of the electrodes. Cell performance was evaluated under various conditions such as the number of coatings, ranging from 1 to 3 times, and heat treatment temperatures of $800-1100^{\circ}C$. The results confirmed that the cell yielded a maximum power of 9.99 W for the sample coated 3 times and heat-treated at $900^{\circ}C$.