• Title/Summary/Keyword: metal compound

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A Study on the Metal Powder Inductor of a Boost Converter for PFC (PFC용 Boost 컨버터의 금속분말 인덕터에 관한 연구)

  • Kim Yun-Sung;Ahn Tae-Young;Jang Pyung-Woo;Jeong In-Bum;Choi Gwang-Bo
    • Proceedings of the KIPE Conference
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    • 2001.07a
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    • pp.368-371
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    • 2001
  • In this paper, the experiment and simulation results of the Boost converter for PFC(power factor correction) using metal powder inductor are presented. The metal powder inductor used in the experiment was composed of Ni-Fe-Mo, Ni-Fe, Fe-Si-Al compound respectively The performance of the 500w class PFC rectifier with the average current mode control and the 300W class PFC rectifier with the variable frequency control, are evaluated.

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Formation of Ti and Ti ceramics composite layer on aluminium alloy (Ti 및 Ti계 세라믹스에 의한 Al합금의 표면복합합금화)

  • ;;;松田福久;中田一博
    • Journal of Welding and Joining
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    • v.13 no.1
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    • pp.103-114
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    • 1995
  • Plasma Transferred arc(PTA) hard facing process has been developed to obtain an overlay weld metal having excellent wear resistance. The effect of Ti, TiSi$_{2}$ and TiC powders addition on the surface of Aluminum alloy 5083 has been investigated with PTA process. This paper describes the result of test the performance of the overlay weld metal. The result can be summarized as follows 1. Intermetallic compound is formed on surface of base metal in Ti or TiSi$_{2}$ powder but the reaction with surface of base metal is little seen in TiC powder. 2. In formation of composite layer on aluminum alloy surface by plasma transferred arc welding process, high melting ceramics like TiC powder is excellent. 3. The multipass welding process is available for formation of high density of powder. But the more number of pass, the less effect of powder, it is considered, and limits of number of pass. 4. By increasing area fraction of TiC powder on Al alloy surface, in especially TiC powder the hardness increase more than 40% area fraction and 88% shows about Hv 700.

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The Characteristics of Cr-Free Coating Hot Dip Galvanized Sheet Steel

  • Kim, Jong-Gi;Moon, Man-Been;Yun, Jeong-Mo
    • Corrosion Science and Technology
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    • v.10 no.1
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    • pp.24-29
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    • 2011
  • The greatest purpose of chromate treatment is to improve anti-corrosion by stabilizing a metal surface. Because metal surface forms a compound by absorbing oxygen or water in the air by being generally unstable, it is necessary to improve anti-corrosion of the metal by forming the metal surface with a stable film. When considering the economical efficiency and requirements together because the film of the metal surface treated with chromate has good anti-corrosion and the stability also in the air by being compact and strong, Chromate treatment has been used most up to the electronics industry from the auto industry. However, these days, because hexavalent chromium is both a toxic agent to be able to cause cancers and deadly poisonous environmental pollutant, the strong legal controls on its use is being imposed all over the world. Because of this reason, a new anti-corrosion method is being required. Also, by users' various demands, the passivations that have recently been developed require various characteristics such as conductivity, chemical resistance, alkali cleaning resistance as well as anti-corrosion. We could confirm the results such as excellent anti-corrosion compared to chromate, conductivity, chemical resistance and detergent resistance as the result of analysis of various characteristics of the galvannealed sheet steels coated with Cr-Free solution developed in this research.

Surface Morphology and Electrical Property of PEMFC (Proton Exchange Membrane Fuel Cell) Bipolar Plates (고분자전해질 연료전지용 바이폴라 플레이트의 표면형상과 전기적 특성)

  • Song, Yon-Ho;Yun, Young-Hoon
    • Journal of the Korean Ceramic Society
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    • v.45 no.3
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    • pp.161-166
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    • 2008
  • The multi-films of a metallic film and a transparent conducting oxide (TCO, indium-tin oxide, ITO) film were formed on the stainless steel 316 and 304 plates by a sputtering method and an E-beam method and then the external metallic region of the stainless steel bipolar plates was converted into the metal nitride films through an annealing process. The multi-film formed on the stainless steel bipolar plates showed the XRD patterns of the typical indium-tin oxide, the metallic phase and the metal substrate and the external nitride film. The XRD pattern of the thin film on the bipolar plates modified showed two metal nitride phases of CrN and $Cr_2N$ compound. Surface microstructural morphology of the multi-film deposited bipolar plates was observed by AFM and FE-SEM. The metal nitride film formed on the stainless steel bipolar plates represented a microstructural morphology of fine columnar grains with 10 nm diameter and 60nm length in FE-SEM images. The electrical resistivity of the stainless steel bipolar plates modified was evaluated.

Brazing Property of SUS304 Stainless Steel and BNi-2 Filler Metal with Vacuum Brazing : Fundamental Study on Brazeability with Ni-Based Filler Metal(I) (진공브레이징에 의한 SUS304 스테인리스강과 BNi-2계 삽입금속의 접합특성 : Ni기 삽입금속에 의한 브레이징 접합성의 기초적 검토(I))

  • Lee, Yong-Won;Kim, Jong-Hoon
    • Korean Journal of Materials Research
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    • v.17 no.3
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    • pp.142-146
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    • 2007
  • Vacuum brazing method has been coming to an important process as one of the new fabricating techniques of metals and alloys. In this study, a vacuum brazing of SUS304 stainless steel with BNi-2 filler metal was carried out in $1{\times}10^{4}$ Torr of vacuum atmosphere. The formation of brittle intermetallic compounds in brazed joints between SUS304 stainless steel and BNi-2 filler metal is a major concern, since they considerably degrade the mechanical properties of joints. To obtain enough stable joining strength, it is necessary to understand the unique properties of brazing process with Ni-based filler metals containing boron. So, in this research we investigated the performance of SUS304/BNi-2 brazed system and the brazed joint properties were evaluated at room temperature by using tensile test. Metallurgical and fractographic analysis were used to characterize the microstructure, the mechanisms of brazing, and joint failure modes.

Factors influencing a Photocatalytic System in Circulating Batch Mode: Photocatalyst Dosage, DO, Retention Time and Metal Impurities (순환회분식 광촉매시스템의 영향인자 연구: 광촉매 주입량, 용존산소, 체류시간,전자포획 첨가금속)

  • Kim, Il-Kyu
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.1
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    • pp.49-58
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    • 2013
  • A selected halogenated organic contaminant, monochlorophenol was successfully degraded by photocatalytic reaction in a circulating batch system. The photocatalytic degradation in most cases follows first-order kinetics. The photocatalytic reaction rate increased in the $TiO_2$ dosage range of 0.1 g/L to 0.4 g/L, then decreased with further increase of the dosage. Also the degradation rate increased over the range of the retention time from 0.49 min. to 0.94 min., then decreased with further increase of the retention time in the circulating batch reactor. The photocatalytic activity was enhanced by addition of metal impurities, platinum(Pt) and palladium(Pd) onto the photocatalysts. The photocatalytic degradation rate increased with the increase of Pt and Pd in the content range of 0 to 2wt %, then decreased with further increase of the metal contents. Therefore the metal loading to $TiO_2$ influence the degradation rate of a halogenated organic compound by acting as electron traps, consequently reducing the electron/positive hole pair recombination rate.

Synthesis and Structure of $\eta^4$-1-Functionally Substituted-2,3,4,5-Tetraphenyl-1-Silacyclopentadienyl Complexes of Irontricarbonyl. Crystal Structure of ($\eta^4$-exo-Cyclopentadienyldicarbonyliron-endo-1-Methyl-2,3,4,5-Tetraphenyl-1-Silacyclopentadienyl)Tricarbonyliron

  • Jinkook Kang;Jaejung Ko;Youngkun Kong;Chang Hwan Kim;Myong Euy Lee;Patrick J. Carroll
    • Bulletin of the Korean Chemical Society
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    • v.13 no.5
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    • pp.542-546
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    • 1992
  • New silicon-monosubstituted (${\eta}^4$-2,3,4,5-tetraphenyl-1-silacyclopentadiene)transi tion metal complexes are described. The new (silole-transition metal complex)Fe$(CO)_3$ was obtained from the reaction of silole-tansition metal complex and Fe$(CO)_5$. We have determined the crystal structure of (${\eta}^4$-exo-cyclopentadienyldicarbonyliron-endo-1-meth yl-2,3,4,5-tetraphenyl-1-silacyclopentadienyl)tric arbonyliron by using graphitemonochromated Mo-$K_{\alpha}radiation. The compound was crystallized in the monoclinic space group $P2_1$/c with a = 8.925(1), b = 18.689(3), c = 19.930(3) ${\AA}$, and ${\beta}$ = 102.02$(1)^{\circ}$. The iron moiety CpFe$(CO)_2$ on silicon is in an axal position. The (silole-transition metal complex) Fe$(CO)_3$ was also prepared through the reaction of (${\eta}^4$-1-chloro-2,3,4,5-tetraphenylsilacyclopentadiene) Fe$(CO)_3$ and metal complex nucleophile. The structure configuration was studied by conventional spectroscopy.

Crystal Structure of $KTiP_2O_7$ (의 결정구조)

  • 이건수;윤호섭
    • Korean Journal of Crystallography
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    • v.7 no.1
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    • pp.57-63
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    • 1996
  • The compound titanium (III) pyrophosphate, KTiP2O7 has been prepared and the crystal structure of the compound has been determined by the X-ray diffraction techniques. It crytallizes in the space group P21/a of the monoclinic system with four formula units in a cell of dimensions a=8.210(3), b=10.292(2), c=7.434(1)Å and β=106.71(2)°. The structure consists of the framework possessing corner-sharing octahedral TiO6 and pyrophosphate groups. As a result, a tunnel structure has been constructed and the K+ cations reside inside the tunnel. KTiP2O7 is isostructural with other trivalent metal pyrophosphates such as KAlP2O7 and RbTiP2O7 but the size difference of the alkali metals causes the variation in the structure. The classical charge balance of the compound can be described as [K+][Ti3+][P24O74-].

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Effect of Processing Additives on Vulcanization and Properties of EPDM Rubber (EPDM 고무의 첨가제에 따른 가류 및 물성에 미치는 영향 연구)

  • Lee, Soo;Bae, Joung Su
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.1
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    • pp.173-185
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    • 2018
  • Effects of three different types of dispersions and flow improving additives composed with fatty acid esters, fatty acid metal salts and amide compound on the vulcanization and the mechanical properties properties of rubber compounds of EPDM and carbon black as fillers. were investigated using Mooney viscometer, moving die rheometer, hardness tester, and universal test machine. The aging characteristics of vulcanized EPDM compounds were also investigated. The Mooney viscosity measured at $125^{\circ}C$ showed a tendency to decrease in the order of amide type> metal salt type > ester type additive. Scorch time showed little or no difference with the addition of ester or metal salt type additives, but the amide type additive shortened a scorch time more than one minute. Rheological measurement data obtained at $160^{\circ}C$ showed that the vulcanization time was faster for metal salt type and amide type additive systems. Delta torque values of EPDM compound increased with metal salt type and amide type additives, but slightly decreased with ester type additive. The tensile strength of the EPDM compound was greatly improved when an ester type additive was added, but the amide type or metal salt type additive had no significant effect. The elongation was significantly improved for metal salt type additive, while the rest were not significantly affected. The tear strength of the EPDM compounds increased with the addition of all kinds of additives, and it increased remarkably in the case of metal salt type additive. Hardness of the EPDM compounds was nearly same value regardless of additive types. The thermal aging of the EPDM blend at $100^{\circ}C$ for 24 h showed little change in the case of metal salt type or amide type additive, but the elongation tends to decrease by 10-20% for all EPDM compounds containing additives.

Extraordinary Magnetomechanical Coupling as a Result of a Combined Magnetic Structural Transition in a New Class of Rare Earth Compound

  • Jiles, D.C.;Lee, S.J.;Han, M.;Lo, C.C.H.;Snyder, J.E.;Gschneidner, K.A.;Pecharsky, V.K.;Pecharsky, A.O.;Lograsso, T.;Schlagel, D.
    • Journal of Magnetics
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    • v.8 no.1
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    • pp.1-6
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    • 2003
  • The new class of $Gd_5(Si_xGe_{1-x})_4$ compounds undergoes a simultaneous magnetic/structural phase transition giving a high level of strain that can be induced either by change in temperature or by application of a magnetic field. Profound changes of structural, magnetic, and electronic changes occur in the $Gd_5(Si_xGe_{1-x})_4$ system lead to extreme behavior of the material such as the giant magnetocaloric effect, colossal magnetostriction, and giant magnetoresistance. These unique material characters can be utilized for various applications including magnetic solid refrigerants, sensors, and actuators.