• Title/Summary/Keyword: membrane transformation

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Change of Phase Transformation Temperature at Fabricated Membrane using Sol-gel Method

  • Cheong, Hun;Choi, Duck-Kyun;Cheong, Deock-Soo
    • Journal of the Korean Ceramic Society
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    • v.38 no.10
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    • pp.876-880
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    • 2001
  • The supported and unsupported boehmite ($\gamma$-AlOOH) membranes were prepared using a boehmite sol. The supported membrane was consisted of a porcelain support, two intermediate $\alpha-{Al_2}{O_3}$ layers, and a top boehmite membrane. XRD patterns showed that the supported top membrane had a higher $\theta-$ to $\alpha-{Al_2}{O_3}$ transformation temperature compared to the unsupported membrane. This result was also confirmed from microstructural study of the membrane. The shift in the phase transformation temperature should be explained by difference of a stress generated in the supported top membrane due to interaction between the support layers and the top membrane.

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Free Vibration Analysis of Solid and Annular Circular Membranes with Continuously Varying Density Using The Differential Transformation Method

  • Shin, Young-Jae;Yun, Jong-Hak;Jaun, Su-Ju;You, Young-chan
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2003.11a
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    • pp.988-993
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    • 2003
  • This paper presents the application of the technique of differential transformation of free vibration of membrane. Numerical calculations are carried out and compared with previously published results. The results obtained by the present method agree very well with those reported in the previous works. The present analysis shows the usefulness and validity of differential transformation in solving a solid and annular circular membranes problem of the responses of the free vibration.

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Change of Phase Transformation and Microstructure of Alumina Membrane: I. Effect by Porosity of Support (알루미나 여과막의 상전이와 미세구조 변화: I. 지지체의 기공율에 의한 영향)

  • Cheong, Hun;Hwang, Kwang-Taek;Choi, Duck-Kyun;Cheong, Deock-Soo
    • Korean Journal of Materials Research
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    • v.12 no.3
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    • pp.205-210
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    • 2002
  • The HPS(High Porosity Support, 39.3%) and the LPS( Low Porosity Support, 18.7%) were fabricated to investigate the phase transformation and the chance of microstructure with porosity of alumina support. Alumina sol was made using aluminum tri-sec $butoxide(ATSB,\; Al(O-Bu)_3)$, the membrane on porous support with different porosity and the membrane without support were fabricated. The $\theta$-to ${\alpha}-A1_2O_3$ phase transformation in the membranes was investigated using thin film X-ray diffraction (XRD), and the change of microstructure was observed using scanning electron microscopy(SEM). XRD patterns showed that the membrane on LPS and HPS had 10$0^{\circ}C$, 5$0^{\circ}C$ higher $\theta$-to ${\alpha}-A1_2O_3$ transformation temperature compared to the unsupported membrane. A similar effect was also observed in microstructure of the membranes, theoritical temperature difference were 97$^{\circ}C$ and 44$^{\circ}C$ by Crapeyron equation.

Phase Transformation and Microstructural Change of Alumina Membrane (알루미나 여과막의 상전이와 미세구조 변화)

  • Cheong, Hun;Choi, Duck-Kyun;Cheong, Deck-Soo
    • Korean Journal of Materials Research
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    • v.10 no.9
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    • pp.619-623
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    • 2000
  • Alumina membrane was prepared by sol-gel coating method using boehmite powder(${\Upsilon}-AlOOH$). The supported and the unsupported alumina membrane were fabricated to investigate the phase transformation and change of microstructure. It is important to control the homogeneous pore size and distribution in application of filtering process. The ${\theta}-to\;{\alpha}-AL_2O_3$ phase transformation (XRD) and the change of microstructure was investigated using scanning electron microscopy(SEM). XRD patterns showed that the supported membrane had $100^{\circ}C$ higher ${\theta}-to\;{\alpha}-AL_2O_3$ transformation temperature compared to the unsupported membrane. The similar effect was also observed for microstructural change of the membrane.

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Power series solution of circular membrane under uniformly distributed loads: investigation into Hencky transformation

  • Sun, Jun-Yi;Rong, Yang;He, Xiao-Ting;Gao, Xiao-Wei;Zheng, Zhou-Lian
    • Structural Engineering and Mechanics
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    • v.45 no.5
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    • pp.631-641
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    • 2013
  • In this paper, the problem of axisymmetric deformation of the circular membrane fixed at its perimeter under the action of uniformly-distributed loads was resolved by exactly using power series method, and the solution of the problem was presented. An investigation into the so-called Hencky transformation was carried out, based on the solution presented here. The results obtained here indicate that the well-known Hencky solution is, without doubt, correct, but in the published papers the statement about its derivation is incorrect, and the so-called Hencky transformation is invalid and hence may not be extended to use as a general mathematical method.

A Study on Phase Transformation and Microstructure Control of $Al_2O_3$ ($Al_2O_3$의 상전이 및 그에 따른 미세구조 제어에 관한 연구)

  • 신상현;오창섭;최성철
    • Journal of the Korean Ceramic Society
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    • v.34 no.6
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    • pp.553-560
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    • 1997
  • A fine $\alpha$-Al2O3 powder was prepared by sol-gel process for membrane application. And it was carried out by adding 1.5wt% $\alpha$-Al2O3 powders(mean size : 87 nm) as seeds to the prepared sols and by controlling the heating schedule (the heating rate and the soaking time) to prevent the microstructural change, which occured during $\theta$-to $\alpha$Al2O3 phase transformation. The seeded $\alpha$-Al2O3 particles acted as the heterogeneous nucleation sites for the $\alpha$-Al2O3 nucleation during the transformation of $\theta$- to $\alpha$-Al2O3 and resulted in increasing the driving force of phase transformation to activate the formation of $\alpha$-Al2O3 phase at 82$0^{\circ}C$. By $\alpha$-Al2O3 seeding and controlling of heating condition the phase transformation of $\theta$- to $\alpha$-Al2O3 was accomplished at low temperature and the grain growth process was depressed. Therefore, the unsupported membrane could be fabricated in $\alpha$-Al2O3 . The average diameter of pores in the fabricated membrane was 7 nm and the porosity was 47%.

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Current Technologies and Related Issues for Mushroom Transformation

  • Kim, Sinil;Ha, Byeong-Suk;Ro, Hyeon-Su
    • Mycobiology
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    • v.43 no.1
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    • pp.1-8
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    • 2015
  • Mushroom transformation requires a series of experimental steps, including generation of host strains with a desirable selective marker, design of vector DNA, removal of host cell wall, introduction of foreign DNA across the cell membrane, and integration into host genomic DNA or maintenance of an autonomous vector DNA inside the host cell. This review introduces limitations and obstacles related to transformation technologies along with possible solutions. Current methods for cell wall removal and cell membrane permeabilization are summarized together with details of two popular technologies, Agrobacterium tumefaciens-mediated transformation and restriction enzyme-mediated integration.

Reuse potential of spent RO membrane for NF and UF process

  • Ng, Zhi Chien;Chong, Chun Yew;Sunarya, Muhammad Hamdan;Lau, Woei Jye;Liang, Yong Yeow;Fong, See Yin;Ismail, Ahmad Fauzi
    • Membrane and Water Treatment
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    • v.11 no.5
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    • pp.323-331
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    • 2020
  • With the increasing demand on reverse osmosis (RO) membranes for water purification worldwide, the number of disposed membrane elements is expected to increase accordingly. Thus, recycling and reuse of end-of-life RO membranes should be a global environmental action. In this work, we aim to reuse the spent RO membrane for nanofiltration (NF) and ultrafiltration (UF) process by subjecting the spent membrane to solvent and oxidizing solution treatment, respectively. Our results showed that solvent-treated RO membrane could perform as good as commercial NF membrane by achieving similar separation efficiencies, but with reduced water permeability due to membrane surface fouling. By degrading the polyamide layer of RO membrane, the transformed membrane could achieve high water permeability (85.6 L/㎡.h.bar) and excellent rejection against macromolecules (at least 87.4%), suggesting its reuse potential as UF membrane. More importantly, our findings showed that in-situ transformation on the spent RO membrane using solvent and oxidizing solution could be safely conducted as the properties of the entire spiral wound element did not show significant changes upon prolonged exposure of these two solutions. Our findings are important to open up new possibilities for the discarded RO membranes for reuse in NF and UF process, prolonging the lifespan of spent membranes and promoting the sustainability of the membrane process.

Deletion Analysis of the Major NF-${\kappa}B$ Activation Domain in Latent Membrane Protein 1 of Epstein-Barr Virus

  • Cho, Shin;Lee, Won-Keun
    • Journal of Microbiology
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    • v.37 no.4
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    • pp.256-262
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    • 1999
  • Latent membrane protein 1 (LMP1) of the Epstein-Barr virus (EBV) is an integral membrane protein with six transmembrane domains, which is essential for EBV-induced B cell transformation. LMP1 functions as a constitutively active tumor necrosis factor receptor (TNFR) like membrane receptor, whose signaling requires recruitment of TNFR-associated factors (TRAFs) and leads to NF-${\kappa}B$ activation. NF-${\kappa}B$ activation by LMP1 is critical for B cell transformation and has been linked to many phenotypic changes associated with EBV-induced B cell transformation. Deletion analysis has identified two NF-${\kappa}B$ activation regions in the carboxy terminal cytoplasmic domains of LMP1, termed CTAR1 (residues 194-232) and CTAR2 (351-386). The membrane proximal C-terminal domain was precisely mapped to a PXQXT motif (residues 204-208) involved in TRAF binding as well as NF-${\kappa}B$ activation. In this study, we dissected the CTAR2 region, which is the major NF-${\kappa}B$ signaling effector of LMP1, to determine a minimal functional sequence. A series of LMP1 mutant constructs systematically deleted for the CTAR2 region were prepared, and NF-${\kappa}B$ activation activity of these mutants were assessed by transiently expressing them in 293 cells and Jurkat T cells. The NF-${\kappa}B$ activation domain of CTAR2 appears to reside in a stretch of 6 amino acids (residues 379-384) at the end of the carboxy terminus.

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Synthesis of zeolite A membranes on alumina support by hydrothermal reaction (수열반응에 의한 알루미나 지지체에 제올라이트 A 박막의 합성)

  • Ko, Tae-Seog
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.17 no.3
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    • pp.95-101
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    • 2007
  • The synthesis of NaA zeolite membrane on a porous alumina support from clear solution by using hydrothermal reaction was investigated. Effects of reaction temperature, reaction time and seeding for transformation of zeolite A membrane and powder which are produced in the reactor were monitored through X-ray diffraction (XRD) analysis and scanning electron microscopy (SEM). The transformation process of producing Zeolite A membrane starts from the formation of the compact and continuous membrane on the surface of porous support from clear solution. The large Zeolite A poly-crystal was then farmed through the dissolution process. Finally, the process was advanced from sodalite to amorphous. In case of powder, sodalite is formed in the early stage of reaction because of surrounding space difference between membrane and powder crystal. Discrete surrounding space of powder crystal makes easy to transform to sodalite. From Zeolite A to amorphous through transformed product was rapidly advanced at high temperature while the membrane with somewhat low coverage was obtained at low temperature. A compact and continuous zeolite A membrane was synthesized at $120^{\circ}C$ in 12-hour period.