• 한국안전학회지
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• 제17권3호
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• pp.81-89
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• 2002

The runaway reaction was analyzed experimently and theoretically at the batch styrene suspension polymerization process. In the experiments, the reaction temperature with time was measured at various experimental conditions. According to the experimental results, the risk of the runaway reaction was increased with increasing the ratio of the monomer(styrene, M) to the dispersion medium(water, W), the concentration of the initiator(BPO), and the monomer mass, respectively. And simulation results showed that the runaway reaction was significantly affected by the reaction rate constant of the propagation and that the phenomena of the runaway reaction occurred at about 70% conversion. Also, we found that the runaway reaction did not occur under the operating condition of below 0.5 for M/W, approximate 3 wt% BPO, and below 75$^{\circ}C$ for the cooling temperature.

• Bulletin of the Korean Chemical Society
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• 제25권6호
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• pp.813-818
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• 2004

A systematic study of microbial fuel cells comprised of thermophilic Bacillus licheniformis and Bacillus thermoglucosidasius has been carried out under various operating conditions. Substantial amount of electricity was generated when a redox mediator was used. Being affected by operation temperature, the maximum efficiency was obtained at 50$^{\circ}C$ with an open circuit voltage of ca. 0.7 V. While a small change around the optimum temperature did not make much effect on the cell performance, the rapid decrease in performance was observed above 70$^{\circ}C$. It was noticeable that fuel cell efficiency and discharge pattern strongly depended on the kind of carbon sources used in the initial culture medium. In the case of B. thermoglucosidasius, glucose alone was utilized constitutively as a substrate in the microbial fuel cell irrespective of used carbons sources. When B. licheniformis was cultivated with lactose as a carbon source, best charging characteristics were recorded. Trehalose, in particular, showed 41.2% coulombic efficiency when B. thermoglucosidasius was cultured in a starch-containing medium. Relatively good repetitive operation was possible with B. thermoglucosidasius cells up to 12 cycles using glucose as a carbon source, when they were cultured with lactose as an initial carbon source. This study demonstrates that highly efficient thermophilic microbial fuel cells can be constructed by a pertinent modulation of the operating conditions and by carefully selecting carbon sources used in the initial culture medium.

• 한국초전도ㆍ저온공학회논문지
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• 제15권4호
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• pp.59-62
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• 2013

The conductive link is used as a cooling medium between a cryocooler and magnet in a cryogen-free superconducting magnet system. The low temperature superconducting (LTS) magnet has one solenoidal configuration with a metal former which has a 52 mm room temperature bore. The superconducting coil is installed in the cryostat maintaining high vacuum and cooled by a two-stage cryocooler. In order to maintain the operating temperature of magnet at the designed level, the cold head temperature of the cryocooler must be lower so that heat can be removed from the superconducting coil. Also, temperature difference is occurred between the magnet and cryocooler and its magnitude is dependent upon the contact resistance at the interfacial surface between metals in the conductive link. In the paper, the performance of the LTS magnet is investigated with respect to the conductive link between the magnet former and the cold head of the cryocooler. The effects of the contact pressure and interfacial materials on the temperature distribution along the conductive link are also presented.

• Journal of Power Electronics
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• 제15권5호
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• pp.1380-1391
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• 2015

This paper provides a loss analysis and comparison of high power semiconductor devices in 5MW Permanent Magnet Synchronous Generator (PMSG) Medium Voltage (MV) Wind Turbine Systems (WTSs). High power semiconductor devices of the press-pack type IGCT, module type IGBT, press-pack type IGBT, and press-pack type IEGT of both 4.5kV and 6.5kV are considered in this paper. Benchmarking is performed based on the back-to-back type 3-level Neutral Point Clamped Voltage Source Converters (3L-NPC VSCs) supplied from a grid voltage of 4160V. The feasible number of semiconductor devices in parallel is designed through a loss analysis considering both the conduction and switching losses under the operating conditions of 5MW PMSG wind turbines, particularly for application in offshore wind farms. This paper investigates the loss analysis and thermal performance of 5MW 3L-NPC wind power inverters under the operating conditions of various power factors. The loss analysis and thermal analysis are confirmed through PLECS Blockset simulations with Matlab Simulink. The comparison results show that the press-pack type IGCT has the highest efficiency including the snubber loss factor.

• 전기화학회지
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• 제26권4호
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• pp.56-63
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• 2023

태양, 파도, 바람 등 친환경 재생에너지원을 이용한 전력 생산 기술이 성숙함에 따라 재생에너지 전력의 경제성과 규모 측면에서 빠르게 발전하고 있다. 특히, 전기화학적인 방법으로 수소를 생산하는 기술은 이러한 재생에너지와 효율적으로 연계될 수 있는 방법 중 하나로 주목받고 있다. 수전해 기술은 작동 온도에 따라서 저온(100 ℃ 이하), 중온(300-700 ℃), 고온(700 ℃ 이상) 수전해로 나눌 수 있으며, 에너지 소비량 및 전압 효율 평가는 열역학 법칙에 따라 계산한다. 그러나 수전해 평가에서 열역학적 전압(thermodynamic voltage)과 열중성 전압(thermo-neutral voltage)의 개념이 혼용되어 사용되고 있다. 본 총설에서는 저온 PEM (proton exchange membrane) 수전해 기술을 바탕으로 작동 전압과 효율 평가에 대한 이해를 높이고, 열역학적 전압과 열중성 전압의 차이점을 명확히 하고자 한다.

• Journal of the Korean Society for Industrial and Applied Mathematics
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• 제17권1호
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• pp.1-15
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• 2013

In this paper the three dimensional wave propagation in a homogeneous isotropic thermo elastic cylindrical panel embedded in an elastic medium (Winkler model) is investigated in the context of the L-S (Lord-Shulman) theory of generalized thermo elasticity. The analysis is carried out by introducing three displacement functions so that the equations of motion are uncoupled and simplified. A Bessel function solution with complex arguments is then directly used for the case of complex Eigen values. This type of study is important for design of structures in atomic reactors, steam turbines, wave loading on submarine, the impact loading due to superfast train and jets and other devices operating at elevated temperature. In order to illustrate theoretical development, numerical solutions are obtained and presented graphically for a zinc material with the support of MATLAB.

• Korean Membrane Journal
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• 제9권1호
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• pp.18-26
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• 2007

The transport and removal characteristics of cobalt ions were investigated in a continuous electrodeionization with cation exchange textile (CEDI-CET). It was shown that the removal properties of cobalt ions are strongly dependent on the operating parameters such as temperature, flow velocity, and the solution pH. The transport and removal of cobalt ions was mainly related to the sorption on the surface and the convection and electro-migration through the ion exchange medium. In this study, the CEDI-CET showed good process performance for the removal of metal ions compared with the conventional CEDI with resins.

• 대한화학회지
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• 제58권1호
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• pp.80-84
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• 2014

The process of petroleum involves in a large amount of oily wastewater that contains high levels of chemical oxygen demand (COD) and toxic compounds. So they must be treated before their discharge into the receptor medium. In this paper, wet peroxide oxidation (WPO) was adopted to treat the oily wastewater. Central composite design, an experimental design for response surface methodology (RSM), was used to create a set of 31 experimental runs needed for optimizing of the operating conditions. Quadratic regression models with estimated coefficients were developed to describe the COD removals. The experimental results show that WPO could effectively reduce COD by 96.8% at the optimum conditions of temperature $290^{\circ}C$, $H_2O_2$ excess (HE) 0.8, the initial concentration of oily wastewater 3855 mg/L and reaction time 9 min. RSM could be effectively adopted to optimize the operating multifactors in complex WPO process.

• 대한기계학회논문집
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• 제16권2호
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• pp.325-335
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• 1992

In this work, direct contact 4-stage fluidized bed heat exchanger is experimentally studied to develop a new type of heat exchanger which recovers the energy contained in the high temperature waste gas exhausted from the industrial furnaces. A sand is used as a heat transfer medium in this experiment. To determine the optimum operating condition, 11 different perforated plates which have a different free area ratio with different hole diameter are used in the experiment. From the room temperature experiment, the pressure drop which is caused by fluidized bed formation is observed. The high temperature experiment is carried out to seek the optimum operating condition of high heat efficiency at low heat exchanger operation cost. The results of experiment are as following. The pressure drop in the high temperature condition can be predicted from the results of the room temperature experiment. And Nusselt number becomes smaller due to the increased interference between sand particles as Reynolds number increases when the dilute phase fluidized beds are formed in nigh temperature condition. But heat transfer amount through the total sand surface area become larger due to the large resident amount of sand. Considering the heat transfer amount and the heat exchanger operation cost, perforated plates which have either a 30% or 35% of free area ratio with 15mm of hole diameter are best fitted for our goal of this work. The values of .phi. which is a dimensionless number representing the absorption heat amount per unit sand rate are in the range from 0.4 to 0.5, when Reynolds number of waste gas ranges from 25-30 with these perforated plates.

• 에너지공학
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• 제10권4호
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• pp.318-326
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• 2001

중저온 배열회수를 통해 열설비의 열효율을 향상시키기 위하여 1 MW급 유기랭킨사이클시스템을 설계, 개발하였다. 포항제철소에 있는 두 대의 100 MW급 기력발전소에서 발생하는 175$^{\circ}C$의 배가스를 산업체에서 발생하는 대표적인 중저온배열원으로 선정하고, 환경오염을 최소화할 수 있는 신냉매인 HCFC-123을 시스템의 작동유체로 선정하였다. 유기냉킨사이클시스템의 시험운전을 통하여 유기랭킨사이클시스템이 산업체의 중저온배열을 회수하는데 유용함을 확인하였다. 열수의 가열, 터빈기동 및 전기투입방법 등의 운전방법을 최적화하였다. 그러나 HCFC-123 공급펌프의 능력부족으로 작동유체의 공급이 부족하여 정격출력보다 낮은 670kW의 전력을 생산할 수 있었다. HCFC-123의 공급유량을 증가시키기 위하여 파이프의 압력손실저하 및 펌프의 성능 향상을 위한 펌프교체 등이 고려되어야 함을 알 수 있었다.