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$Pr^{3+}-and$ $Pr^{3+}/Er^{3+}$-Doped Selenide Glasses for Potential $1.6{\mu}m$ Optical Amplifier Materials

  • Choi, Yong-Gyu;Park, Bong-Je;Kim, Kyong-Hon;Heo, Jong
    • ETRI Journal
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    • v.23 no.3
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    • pp.97-105
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    • 2001
  • $1.6\;{\mu}m$ emission originated from $Pr^{3+}:\;(^3F_3,\;^3F_4)\;{\longrightarrow}\;^3H_4$ transition in $Pr^{3+}-\;and\;Pr^{3+}/Er^{3+}$-doped selenide glasses was investigated under an optical pump of a conventional 1480 nm laser diode. The measured peak wavelength and fullwidth at half-maximum of the fluorescent emission are ~1650nm and 120nm, respectively. A moderate lifetime of the thermally coupled upper manifolds of ${\sim}212{\pm}10{\mu}s$ together with a high stimulated emission cross-section of ${\sim}(3{\pm}1){\times}10^{-20}\;cm^2$ promises to be useful for $1.6{\mu}m$ band fiber-optic amplifiers that can be pumped with an existing high-power 1480 nm laser diode. Codoping $Er^{3+}$ enhances the emission intensity by way of a nonradiative $Er^{3+}:\;^4I_{13/2}\;{\longrightarrow}\;Pr^{3+}:\;(^3F_3,\;^3F_4)$ energy transfer. The Dexter model based on the spectral overlap between donor emission and acceptor absorption describes well the energy transfer from $Er^{3+}$ to $Pr^{3+}$ in these glasses. Also discussed in this paper are major transmission loss mechanisms of a selenide glass optical fiber.

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Fluorescence Enhancement of 7-Diethylamino-4-methylcoumarin by Noncovalent Dipolar Interactions with Cucurbiturils

  • Park, Mee Ock;Moon, Myung Gu;Kang, T.J.
    • Bulletin of the Korean Chemical Society
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    • v.34 no.5
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    • pp.1378-1382
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    • 2013
  • We have investigated the complex forming behavior of cucurbit[6]urils(CB6) and cucurbit[7]urils(CB7) with 7-diethylamino-4-methylcoumarin(C460) in water. The electronic absorption maximum of C460 shows bathochromic shift with the addition of CB7 and fluorescence intensity is greatly increased, while CB6 has no noticeable effects on the spectroscopic properties of C460. It is noted that CB7 interacts more strongly with C460 than CB6 does. Fluorescence lifetime also significantly increased for the CB7 complex, which is attributed to reduced polarity surrounding C460 and/or C460 being in a restricted environment. The stoichiometry for the complex formation determined from the fluorescence titration measurement indicates that 2:1 complex in which two CB7 molecules bind to C460 is formed. Thus, two step equilibrium processes are suggested for the complex formation and the binding constants are estimated. The semi-empirical electronic structures calculations indicate that C460 is not included in the CB7 cavity but interacts noncovalently with the portal carbonyls of CB7.

Development of Alkali Metal Thermal-to-Electric Converter Unit Cells Using Mo/TiN Electrode

  • Seog, Seung-won;Choi, Hyun-Jong;Kim, Sun-Dong;Lee, Wook-Hyun;Woo, Sang-Kuk;Han, Moon-Hee
    • Journal of the Korean Ceramic Society
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    • v.54 no.3
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    • pp.200-204
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    • 2017
  • Molybdenum (Mo), an electrode material of alkali metal thermal-to-electric converters (AMTEC), facilitates grain growth behavior and forms Mo-Na-O compounds at high operating temperatures, resulting in reduced performance and shortened lifetime of the cell. Mo/TiN composite materials have been developed to provide a solution for such issues. Mo is a metal that possesses excellent electrical properties, and TiN is a ceramic compound with high-temperature durability and catalytic activity. In this study, a dip-coating process with an organic solvent-based slurry was used as an optimal coating method to achieve homogeneity and stability of the electrodes. Cell performance was evaluated under various conditions such as the number of coatings, ranging from 1 to 3 times, and heat treatment temperatures of $800-1100^{\circ}C$. The results confirmed that the cell yielded a maximum power of 9.99 W for the sample coated 3 times and heat-treated at $900^{\circ}C$.

Use of Lèvy distribution to analyze longitudinal data with asymmetric distribution and presence of left censored data

  • Achcar, Jorge A.;Coelho-Barros, Emilio A.;Cuevas, Jose Rafael Tovar;Mazucheli, Josmar
    • Communications for Statistical Applications and Methods
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    • v.25 no.1
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    • pp.43-60
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    • 2018
  • This paper considers the use of classical and Bayesian inference methods to analyze data generated by variables whose natural behavior can be modeled using asymmetric distributions in the presence of left censoring. Our approach used a $L{\grave{e}}vy$ distribution in the presence of left censored data and covariates. This distribution could be a good alternative to model data with asymmetric behavior in many applications as lifetime data for instance, especially in engineering applications and health research, when some observations are large in comparison to other ones and standard distributions commonly used to model asymmetry data like the exponential, Weibull or log-logistic are not appropriate to be fitted by the data. Inferences for the parameters of the proposed model under a classical inference approach are obtained using a maximum likelihood estimators (MLEs) approach and usual asymptotical normality for MLEs based on the Fisher information measure. Under a Bayesian approach, the posterior summaries of interest are obtained using standard Markov chain Monte Carlo simulation methods and available software like SAS. A numerical illustration is presented considering data of thyroglobulin levels present in a group of individuals with differentiated cancer of thyroid.

Digital Change Detection by Post-classification Comparison of Multitemporal Remotely-Sensed Data

  • Cho, Seong-Hoon
    • Korean Journal of Remote Sensing
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    • v.16 no.4
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    • pp.367-373
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    • 2000
  • Natural and artificial land features are very dynamic, changing somewhat repidly in our lifetime. It is important that such changes are inventoried accurately so that the physical and human processes at work can be more fully understood. Change detection is a technique used to determine the change between two or more time periods of a particular object of study. Change detection is an important process in monitoring and managing natural resources and urban development because it provides quantitative analysis of the spatial distribution in the population of interest. The purpose of this research is to detect environmental changes surrounding an area of Mountain Moscow, Idaho using Landsat Thematic Maper (TM) images of (July 8, 1990 and July 20, 1991). For accurate classification, the Image enhancement process was performed for improving the image quality of each image. A SPOT image (Aug. 14, 1992) was used for image merging in this research. Supervised classification was performed using the maximum likelihood method. Accuracy assessments were done for each classification. Two images were compared on a pixel-by-pixel basis using the post-classification comparison method that is used for detecting the changes of the study area in this research. The 'from-to' change class information can be detected by post classification comparison using this method and we could find which class change to another.

Service life prediction of a reinforced concrete bridge exposed to chloride induced deterioration

  • Papadakis, Vagelis G.
    • Advances in concrete construction
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    • v.1 no.3
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    • pp.201-213
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    • 2013
  • While recognizing the problem of reinforcement corrosion and premature structural deterioration of reinforced concrete (RC) structures as a combined effect of mechanical and environmental actions (carbonation, ingress of chlorides), emphasis is given on the effect of the latter, as most severe and unpredictable action. In this study, a simulation tool, based on proven predictive models utilizing principles of chemical and material engineering, for the estimation of concrete service life is applied on an existing reinforced concrete bridge (${\O}$resund Link) located in a chloride environment. After a brief introduction to the structure of the models used, emphasis is given on the physicochemical processes in concrete leading to chloride induced corrosion of the embedded reinforcement. By taking under consideration the concrete, structural and environmental properties of the bridge investigated, an accurate prediction of its service life is taking place. It was observed that the proposed, and already used, relationship of service lifetime- cover is almost identical with a mean line between the lines derived from the minimum and maximum critical values considered for corrosion initiation. Thus, an excellent agreement with the project specifications is observed despite the different ways used to approach the problem. Furthermore, different scenarios of concrete cover failure, in the case when a coating is utilized, and extreme deicing salts attack are also investigated.

Multiple Sink Nodes to Improve Performance in WSN

  • Dick, Mugerwa;Alwabel, Mohammed;Kwon, Youngmi
    • Journal of Korea Multimedia Society
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    • v.22 no.6
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    • pp.676-683
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    • 2019
  • Wireless Sensor Networks (WSNs) consist of multiple tiny and power constrained sensors which use radio frequencies to carry out sensing in a designated sensor area. To effectively design and implement reliable WSN, it is critical to consider models, protocols, and algorithms that can optimize energy consumption of all the sensor nodes with optimal amount of packet delivery. It has been observed that deploying a single sink node comes with numerous challenges especially in a situation with high node density and congestion. Sensor nodes close to a single sink node receive more transmission traffic load compared to other sensors, thus causing quick depletion of energy which finally leads to an energy hole and sink hole problems. In this paper, we proposed the use of multiple energy efficient sink nodes with brute force technique under optimized parameters to improve on the number of packets delivered within a given time. Simulation results not only depict that, deploying N sink nodes in a sensor area has a maximum limit to offer a justifiable improvement in terms of packet delivery ratio but also offers a reduction in End to End delay and reliability in case of failure of a single sink node, and an improvement in the network lifetime rather than deploying a single static sink node.

Diamond-like Carbon Tribological Endurance using an Energetic Approach

  • Alkelae, Fathia;Jun, Tea-Sung
    • Tribology and Lubricants
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    • v.37 no.5
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    • pp.179-188
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    • 2021
  • Reputed for their low friction coefficient and wear protection effect, diamond-like carbon (DLC) materials are considered amongst the most important lubricant coatings for tribological applications. In this framework, this investigation aims to elucidate the effect of a few operating parameters, such as applied stress and sliding amplitude on the friction lifetime of DLC coatings. Fretting wear tests are conducted using a 12.7 mm radius counterpart of 52100 steel balls slid against a substrate of the same material coated with a 2 ㎛ thickness DLC. Approximately, 5 to 57 N force is applied, generating a maximum Hertzian contact pressure of 430 to 662 MPa, corresponding to the applied force. The coefficient of friction (CoF) generates three regimes, first a running-in period regime, followed by a steady-state evolution regime, and finally a progressive increase of the CoF reaching the steel CoF value, as an indicator of reaching the substrate. To track the wear scenario, interrupted tests are performed with analysis combining scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), 3D profilometer and micro-Raman spectroscopy. The results show two endurance values: one characterizing the coating failure (Nc1), and the other (Nc2) indicating the friction failure which is situated where the CoF reaches a threshold value of μth = 0.3 in the third regime. The Archard energy density factor is used to determine the two endurance values (Nc1, Nc2). Based on this approach, a master curve is established delimitating both the coating and the friction endurances.

Development of Marine Turning Gear Based on Helical Planetary Reducer (헬리컬 유성감속기 기반 선박용 터닝기어 개발)

  • Kim, Kun-Woo;Lee, Jae-Wook;Jang, Jin-Seok;Choi, Chang-Young;Hong, Jong-Hae;Lee, Kang-Jae
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.19 no.10
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    • pp.36-43
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    • 2020
  • A marine turning gear is the main auxiliary machine that enables the disassembly of and maintenance on the main engines. In this study, a marine turning gear based on a helical planetary reducer was developed through analysis of a marine turning gear based on a spur planetary reducer. Nonlinear numerical analysis was performed to determine the ideal contact ratio between the sun gear and the idle gear. Based on this, the surface durability, tooth bending strength, and contact ratio were calculated. In addition, the helix direction was selected to utilize the existing bearings. Gears were manufactured based on the helical gear design values, and the turning gear was evaluated using the FTA standards of MAN Co. Ltd. As a result, a lifetime of 3,000 to 5,000 hours was verified, the maximum torque measured was 105kNm, and the efficiency was measured to be 87.4%.

Alternating Current (AC) Powered LED Lighting Technology with Constant Brightness (빛의 밝기가 일정한 교류 구동 LED 조명기술)

  • Lee, Dong Won;Ahn, Ho-Myoung;Kim, Byungcheul
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.35 no.5
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    • pp.466-470
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    • 2022
  • In order to widely disseminate LED lighting, LED lighting technology that directly uses AC commercial power has been recently introduced. AC powered LED lighting technology has a problem in that the light brightness of the LED changes because the voltage applied to the LED and the current flowing through the LED continuously change. In this study, when the LED current is greater than the design current, the current control signal generated by the controller is supplied to the current source to supply only the design current to the LED by increasing the voltage drop at the current source. If it is smaller than the design current, the controller is adjusted so that the current is supplied only to the LED without a voltage drop in the current source. It can be seen that the higher the maximum rectified voltage, the faster the lighting time of the LED light emitting block is, so that the power factor of the LED lighting is improved. The LED lighting technology proposed in this study enables LED lighting with constant light brightness, reduced power consumption, and long lifetime.