• Journal of the Korean Society of Safety
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• v.33 no.4
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• pp.8-14
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• 2018

In the industrial chemical process involving combustible materials, reliable safety data are required for design prevention, protection and mitigation measures. The accurate combustion properties are necessary to safely treatment, transportation and handling of flammable substances. The combustion parameters necessary for process safety are lower flash point, upper flash point, fire point, lower explosion limit(LEL), upper explosion limit(UEL)and autoignition temperature(AIT) etc.. However, the combustion properties suggested in the Material Safety Data Sheet (MSDS) are presented differently according to the literatures. In the chemical industries, tetralin which is widely used as a raw material of intermediate products, coating substances and rubber chemicals was selected. For safe handling of tetralin, the lower and flash point, the fire point, and the AIT were measured. The LEL and UEL of tetralin were calculated using the lower and upper flash point obtained in the experiment. The flash points of tetralin by using the Setaflash and Pensky-Martens closed-cup testers measured $70^{\circ}C$ and $76^{\circ}C$, respectively. The flash points of tetralin using the Tag and Cleveland open cup testers are measured $78^{\circ}C$ and $81^{\circ}C$, respectively. The AIT of the measured tetralin by the ASTM E659 apparatus was measured at $380^{\circ}C$. The LEL and UEL of tetralin measured by Setaflash closed-cup tester at $70^{\circ}C$ and $109^{\circ}C$ were calculated to be 1.02 vol% and 5.03 vol%, respectively. In this study, it was possible to predict the LEL and the UEL by using the lower and upper flash point of tetralin measured by Setasflash closed-cup tester. A new prediction method for the ignition delay time by the ignition temperature has been developed. It is possible to predict the ignition delay time at different ignition temperatures by the proposed model.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.32 no.4
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• pp.371-380
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• 2022

Objectives: To ensure that employers handling petroleum compounds understand whether petroleum-based UVCB (unknown or variable composition, complex reaction products, or biological materials) substances contain hazardous substances and comply with the Occupational Safety and Health Act, petroleum-based UVCB substances were analyzed and the results from samples were compared with MSDS (Material Safety Data Sheet) contents. Methods: Twenty-one petroleum samples were analyzed using GC-MS (Gas Chromatography-Mass Spectrometry), targeting ten volatile organic compounds regulated by the Occupational Safety and Health Act. Results: The target chemicals were detected in 13 out of 21 samples. All 13 samples were in the naphtha (low boiling point naphthas (gasolines)) group. There were also naphtha group samples containing 2% benzene. Some naphtha samples used as solvents contained about 1% benzene. Conclusions: This study shows that naphtha group petroleum substances contain hazardous chemicals in many cases. In particular, if benzene, n-hexane, and toluene with low occupational exposure limits are contained above the limit concentration. Such information should be delivered in the article on MSDS legal regulations.

• Fire Science and Engineering
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• v.30 no.5
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• pp.137-143
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• 2016

The use of chemicals is increasing due to industrial advancement and diversification. In addition, the number of chemical accidents are increasing at the same time. A multifaceted effort in chemical accidents is needed for efficient prevention and countermeasures. This paper presents, under the current Act, a chemical accident case, including the material safety data sheet (MSDS) through the chemical accident prevention and measures for improvement with regard to research.

• Journal of Korean Society of societal Security
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• v.3 no.2
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• pp.27-32
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• 2010

Emergency preparedness plan (EPP) is the systematic management of activities that involve a material degree of risk of loss or other damage to the surroundings (people, property and environment), and the boundary of accident recovery plan (ARP). The main purpose of the program is to provide a safety management system to each facility in order to enable to prevent accident and to control accident immediately. The EPP includes not only typical safety-related documentations such as material safety data sheet (MSDS), standard operation procedure (SOP), emergency response plan(ERP). EPP is established basis of the preliminary safety analysis involving risk identification, assessment and prevention plans. The program is also helpful for government or related agencies to control a number of accidents in small-scale companies in the whole country.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.11 no.3
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• pp.179-189
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• 2001

This study was performed to identify the current status of work environment management and to provide appropriate recommendations for small scale industry with less than 5 workers from September, 2000 to October, 2000 in Seoul city and Gyoung-gi province. The 211 companies were surveyed by checklist included the elements of management of work environment, hazardous chemicals, MSDS, personal protective equipment, and ventilation system. The proportion of metal products manufacturing and printing industries are 25.6 % and 22.3%, respectively. The daily working hours in printing industry is longer than others. The industries that produce potentially hazardous agents, such as noise, dust, metal, organic solvents, radiation and chemical material are pulp, plating, machinery, and printing, respectively. In above industries, only 2.8 % of those recognised and had MSDS. The proportion of companies providing fire extinguishers, safety showers are found to be 13.3 %, 7.1 %, respectively. Only 24.2 % of companies provided personal protective equipment to the workers. The ventilation system was operated in most of companies. But local exhaust ventilation system is provided to 22.3 % of those, also had not been annually inspected. This study showed that the current status of occupational safety and health was not appropriate for workers in small scale industries. It is suggested that annual physical examination have to be performed, MSDS usage must become widespread, and employer and emplyees in small scale industry should be educated for the treatment and storage of hazardous chemicals to improve the occupational safety and health of the working environment. also, regulatory standard has to be applied to local exhaust ventilation system in small scale industry to improve the working condition.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.33 no.3
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• pp.365-374
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• 2023

Objectives: After the MSDS submission and non-disclosure review system was introduced in January 2021, there were compliance difficulties in the field. Accordingly, for the establishment of the MSDS system, the government intends to investigate what has been improved and what urgently needs to be improved in the future, and to suggest detailed improvement plans. Methods: The background and problems of urgent difficulties in the field handling chemicals were investigated, and realistic improvement plans were derived through review of other laws related to the MSDS system and overseas cases. Results: In order to guarantee the safety of the public while at the same time promoting corporate R&D, it is necessary to alleviate the non-disclosure screening system for chemical substances for R&D, and to improve the irrationality of failing to implement the non-disclosure screening system due to information on unclassified substances being circulated. For this reason, it seems necessary to ease the requirement to submit all ingredients. In addition, it is necessary to strengthen punishment to raise awareness so that health problems do not occur due to the harmfulness and danger of hidden substances among workers who handle chemical substances and downstream users due to false descriptions in MSDS. Conclusions: All members of our society, including chemical manufacturers/importers and handling companies, academia, civil society, and the government, each subject of chemicals, should take an interest in the entire process from production to disposal of chemicals and work together to prevent harm to the public.

• Journal of the Korean Society of Safety
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• v.26 no.5
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• pp.54-58
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• 2011

Emergency preparedness plan(EPP) is the systematic management of activities that involve a material degree of risk of loss or other damage to the surroundings(people, property and environment), and the boundary of accident recovery plan(ARP). The main purpose of the program is to provide a safety management system to each facility in order to enable to prevent accident and to control accident immediately. The EPP includes not only typical safety-related documentations such as material safety data sheet(MSDS), standard operation procedure(SOP), emergency response plan(ERP). EPP is established basis of the preliminary safety analysis involving risk identification, assessment and prevention plans. The program is also helpful for government or related agencies to control a number of accidents in small-scale companies in the whole country.

• Journal of the Korean Institute of Gas
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• v.7 no.4 s.21
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• pp.30-35
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• 2003

Product liability(PL) law imposes the liability on manufacturer or wholesaler when the product defects cause harm to consumers of the products or any other parties in their lives, bodies, or properties. In Korea, the law of product liability was enforced in July 2002. In this study the Product Liability Response System of chemical products was developed by using Failure Mode and Effect Analysis(FMEA). For a case study peformed for N,N-Dimethylethylamine. First, product information was gathered through Material Safety Data Sheet(MSDS)and which considered as an instruction manual of chemical product. And an effect caused by product defects is analyzed by FMEA to get Risk Priority Number(RPN) which is calculated by multiplying of severity, occurrence, and detection of the defects. Then hazard was estimated quantitatively by RPN.

• Korean Chemical Engineering Research
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• v.56 no.4
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• pp.474-478
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• 2018

For process safety, fire and explosion characteristics of combustible materials handled at industrial fields must be available. The combustion properties for the prevention of the accidents in the work place are flash point, fire point, explosion limit, and autoignition temperature (AIT) etc.. However, the combustion properties suggested in the Material Safety Data Sheet (MSDS) are presented differently according to the literatures. The accurate combustion properties are necessary to safely treatment, transportation and handling of flammable substances. In the chemical industries, n-ethylaniline which is widely used as a raw material of intermediate products and rubber chemicals was selected. For safe handling of n-ethyl aniline, the flash point, the fire point and the AIT were measured. The lower explosion limit (LEL)of n-ethylaniline was calculated using the lower flash point obtained in the experiment. The flash points of n- ethylaniline by using the Setaflash and Pensky-Martens closed-cup testers measured $77^{\circ}C$ and $82^{\circ}C$, respectively. The flash points of n-ethylaniline using the Tag and Cleveland open cup testers are measured $85^{\circ}C$ and $92^{\circ}C$, respectively. The AIT of the measured n-ethyl aniline by the ASTM E659 apparatus was measured at $396^{\circ}C$. The LEL of n-ethylaniline measured by Setaflash closed-cup tester at $77^{\circ}C$ was calculated to be 1.02 vol%. In this study, it was possible to predict the LEL by using the lower flash point of n-ethylaniline measured by closed-cup tester. The relationship between the ignition temperature and the ignition delay time of the n-ethylaniline proposed in this study makes it possible to predict the ignition delay time at different ignition temperatures.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.25 no.4
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• pp.506-515
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• 2015

Objectives: This study was conducted to evaluate the status of hazard communication regarding dental materials among dental hygienists in the Daegu Metropolitan City and the North Gyeongsang-do Province area. Materials: A total of 310 dental hygienists were surveyed using self-administered questionnaires to investigate the status of hazard communication on dental materials and information needs. We collected instructions for use and material safety data sheets(MSDSs) for 67 dental materials frequently used at dental hospitals located in the Daegu Metropolitan City and the North Gyeongsang-do Province area. Results: The questionnaire surveys showed that only 11% of the 310 dental hygienists had knowledge of MSDS and 46.8% of respondents never read instructions for use before using materials. Just 7.4% of dental hygienists have undergone training on hazard information for dental materials. In particular, dental hygienists working at dental clinics had significantly lower response rates on knowledge of MSDS(p<0.001), reading of instructions for use(p=0.042) and training on the hazard information of dental materials(p=0.004) than those in dental hospitals or general hospitals. The essential information most desired by dental hygienists was hazard identification(82.3%) followed by first-aid measures(53.9%), handling and storage(51%), disposal considerations (49%) and toxicological information(47.1%). All dental materials were on foreign products which came from Japan(59.7%), the USA(26.9%) and Liechtenstein(13.7%). In terms of usage, 56.7% of dental materials were prosthetic, followed by conservation(31.3%), orthodontics(9%), and prevention(3%). We found that dental hygienists had accessed MSDSs for only five dental products among the 67 dental materials. The instructions for the use of the 67 dental materials provided hazard identification(64.2%), first-aid measures(83.6%), handling and storage(97%), disposal considerations(20.9%) and toxicological information(26.9%). Conclusions: Based on the results of this study, the hazard communication system for dental hygienists working at dental clinics should be improved.