• Journal of Soil and Groundwater Environment
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• v.19 no.6
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• pp.49-58
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• 2014

This study was implemented as a part of the experiment to develop two kinds of soil-based Benzo[a]pyrene (BaP) proficiency testing materials (PTMs) for soil analysis. A test was carried out for the check of solubility of the reference material (high purity reagent) using several solvents. Another test was also conducted for the evaluation of homogeneity and stability of two kinds of candidate soil reference materials. The test analysis of BaP in terms of the candidate materials was conducted according to the Standard Soil Analytical Methods by Ministry of Environment. Dissolution of the reference material was shown to vary depending on solvent type and was higher in the order of Dichloromethane > Acetone > Acetone/MeOH (9 : 1) > N-hexane. In addition, the slope on calibration curve for BaP standard solutions was largest on BaP standard solutions prepared with dichloromethane of the tested solvents. Such tendency appeared egually in the commercial BaP standard solution. Therefore, it is thought to be reasonable to use dichloromethane as the solvent in case of the standard stock solution that is used for the measurement of BaP concentration in soil. ISO 13528 and IUPAC protocol were used for verification of homogeneity on the two kinds of soil candidate materials, Both candidate materials were sufficiently homogeneous. Stability assessment of the two candidate materials was made according to ISO Guide 35 and the result showed that both batches did not have any long-term and short term stability issues that might occur during shipping. However, monitoring results of BaP concentration in soil showed that BaP concentration of the two batches measured at 15 days after the sample preparation was reduced by about 24~37% compared with that of the samples measured on 0 day of the sample preparation. Identification was done with several treatments such as irradiation and sterilization etc. The major cause was shown to be irradiation to the samples.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2000.07a
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• pp.274-277
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• 2000

SHS is recognized as an attractive process for producing high-temperature, hard materials that difficult and/or expensive to produce by conventional fabrication methods. The goal of this work is to investigate new express technology of doped Fe alloys materials. The high density, homogeneity of the components, and the low processing temperatures achieved and minimum synthesis time are all of paramount importance in fabricating Fe alloys as functional materials.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.20 no.1
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• pp.29-35
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• 2015

Dissolved nutrients in seawater are recognized as an essential biogeochemical factor for detecting global environmental changes. The importance of nutrient reference material for seawater has been increased greatly for the comparison of nutrient data, measured in different time and space in global ocean by various researchers with different levels in nutrient analysis skill. In this study, we described the homogeneity and stability of nutrient reference material for seawater using natural seawater, collected at a station of Shihwa Lake, at a coastal station near Uljin (surface water), and at a station over the Ulleung Basin (surface water and 1500 m depth water) and sterilized. Based on the homogeneity data, the nutrient reference materials has similar homogeneity compared to other nutrient reference materials. During 3-13 month period, there was no unidirectional trend of increase or decrease in nutrient concentration of newly developed nutrient reference material for seawater. However, a sustained measurement is required to check stability for longer period.

• Journal of the Korean Society for Precision Engineering
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• v.21 no.1
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• pp.181-188
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• 2004

Structural analysis for materials containing regularly spaced in-homogeneities is usually executed by using averaged material properties. For the homogenization process, a unit cell is defined and loaded somehow, and its response is investigated to evaluate the properties. The imposed loading conditions should accord to the behavior of unit cell immersed in the macroscopic structure in order to guarantee the accuracy of the effective properties. Each unit cell shows periodic variation of strain if the material is loaded uniformly, and in this study, direct implementation of this characteristic behavior is attempted on FE models of unit cell. Conventional finite element analysis tool can be used without any modification, and the boundary of unit cell is constrained in a way that the periodicity is satisfied. The proposed method is applicable to skew arrayed in-homogeneity problems. The flexibility matrix relating tonsorial stress and strain components in skewed rectilinear coordinate system is transformed so that the required engineering constants can be evaluated. Effective properties are computed for the materials with square and skew arrayed circular holes, and its accuracy is examined.

• Journal of the Korean Ceramic Society
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• v.49 no.6
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• pp.648-653
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• 2012

Hybridization of dense ceramic membranes for hydrogen separation with an electronically conductive metallic phase is normally utilized to enhance the hydrogen permeation flux and thereby to increase the production efficiency of hydrogen. In this study, we developed a nickel and proton conducting oxide ($BaCe_{0.9}Y_{0.1}O_{3-{\delta}}$: BCY) based cermet (ceramic-metal composites) membrane. Focused on the general criteria in that the hydrogen permeation properties of a cermet membrane depend on its microstructural features, such as the grain size and the homogeneity of the mix, we tried to optimize the microstructure of Ni-BCY cermets by controlling the fabrication condition. The Ni-BCY composite powder was synthesized via a solid-state reaction using $2NiCO_3{\cdot}3Ni(OH)_2{\cdot}4H_2O$, $BaCeO_3$, $CeO_2$ and $Y_2O_3$ as a starting material. To optimize the mixing scale and homogeneity of the composite powder, we employed a high-energy milling process. With this high-energy milled composite powder, we could fabricate a fine-grained dense membrane with an excellent level of mixing homogeneity. This controlled Ni-BCY cermet membrane showed higher hydrogen permeability compared to uncontrolled Ni-BCY cermets created with a conventionally ball-milled composite powder.

• Structural Engineering and Mechanics
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• v.54 no.1
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• pp.135-148
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• 2015

The present investigation is concerned with a study effect of magnetic field and non-homogenous on the elastic stresses in rotating orthotropic infinite circular cylinder. A certain boundary conditions closed form stress fields solutions are obtained for rotating orthotropic cylinder under initial magnetic field with constant thickness for three cases: (1) Solid cylinder, (2) Cylinder with a circular hole at the center, (3) Cylinder mounted on a circular rigid shaft. Analytical expressions for the components of the displacement and stress fields in different cases are obtained. The effect of rotation and magnetic field and non-homogeneity on the displacement and stress fields are studied. Numerical results are illustrated graphically for each case. The effects of rotating and magnetic field and non-homogeneity are discussed.

• Electrical & Electronic Materials
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• v.11 no.11
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• pp.46-52
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• 1998

Barium titanate owes its great importance to the fact that its dielectric constant is about 100 times higher than that of conventional dielectric materials provided its compositional and structural purity is extremely high. The value of crystalline BaTiO3 bodies as used, for instance, in computer elements, magnetic amplifiers, memory device, ets., depend on boththe compositional and the structural purity of the BaTiO3 crystals. This purity will, in turn, depend on the purity of the raw materials used in manufacturing the BaTiO3 compound and on the particularmethods of manufacture which determine the size, homogeneity, and the structural purity of the crystals. This paper reviews the important theoretical considerations, processing techniques and applications related to sol-gel derived thin films.

• Journal of the Korean Society for Aviation and Aeronautics
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• v.16 no.4
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• pp.26-34
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• 2008

This article provides a comprehensive treatment of cracks in non-homogeneous structural materials such as functionally graded materials (FGMs). It is assumed that the material properties depend only on the coordinate perpendicular to the crack surfaces and vary continuously along the crack faces. By using laminated composite plate model to simulate the material non-homogeneity, we present an algorithm for solving the system based on Laplace transform and Fourier transform techniques. Unlike earlier studies that considered certain assumed property distributions and a single crack problem, the current investigation studies multiple crack problem in the FGMs with arbitrarily varying material properties. As a numerical illustration, transient thermal flow intensity factors for a metal-ceramic joint specimen with a functionally graded interlayer subjected to sudden heating on its boundary are presented. The results obtained demonstrate that the present model is an efficient tool in the fracture analysis of non-homogeneous material with properties varying in the thickness direction.

• Journal of the Korean Society for Aviation and Aeronautics
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• v.19 no.1
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• pp.15-23
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• 2011

The purpose of this paper is to investigate the time behavior of a multiple crack problems. It is assumed that the medium contains cracks perpendicular to the crack surfaces, that the thermo-mechanical properties are continuous functions of the thickness coordinate. we use the laminated composite plate model to simulate the material non-homogeneity. By utilizing the Laplace transform and Fourier transform techniques, the multiple crack problems in the non-homogeneous medium is formulated. Singular integral equations are derived and solved to investigate the multiple crack problems. As a numerical illustration, transient thermal stress intensity factors(TSIFs) for a functionally graded material plate subjected to sudden heating on its boundary are provided. The variation in the TSIFs due to the change in material gradient and the crack position is studied.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.51 no.3
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• pp.348-354
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• 2015

Experiments for catch and cluster analysis on the catch by gillnet for the Pacific herring were conducted using traditional nylon net (PA) and developing biodegradable net (PBS) with different monofilaments of #2 (=0.23 mm) and #3 (=0.28 mm) in diameter between 2011 and 2012, and of #2, #2.5 and #3 in 2013 in the eastern coastal waters of Samcheok, Korea. The total catch during the experiments was 3,337kg in weight and 16,757 individuals in number. Though the catch ratio of the Pacific herring in 2011 and 2012 was 97.4% and 98.7%, respectively, that of the Pacific herring in 2013 was 73.6% as the biggest and followed by goldeye rockfish (8.6%), black edged sculpin (8.4%), atka mackerel (7.2%) and Alaska cod (1.0%). The ANOVA analysis on the total catch in relation to net material showed that there was not statistically significant difference at the 5% level between nylon net (PA) and biodegradable net (PBS) (p=0.91). With the cluster analysis on the catch in relation to net material (PA, PBS) and twine thick (#2, #3), it showed the influence of net material on the catch was greater than that of twine diameter in this experiment. From the test of homogeneity on the catch by the gillnet with PA and PBS in which several species were caught in 2013, there was not statistically significant homogeneity in relation to net material (p<0.005). That meant the traditional gillnet of nylon (PA) was more efficient than the biodegradable (PBS) gillnet to catch several kinds of fish, however the PBS gillnet was better than the PA gillnet to catch the target Pacific herring.