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The Effect of Feed Temperature On Permeate Flux During Membrane Separation (온도가 막분리 투과성능에 미치는 영향)

  • Kim, Kwang Soo;Moon, Deok Soo;Kim, Hyeon Ju;Lee, Seung Won;Ji, Ho;Jung, Hyeon Ji;Won, Hye Jung
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.17 no.1
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    • pp.13-19
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    • 2014
  • The feed temperature has an effect on the performance during desalination of seawater by membrane separation. When the permeate flux intends to increase using the waste heat, it is necessary to analyze the effect of feed temperature precisely on the membrane performance. The experiments were carried out to investigate the performance of membranes by varying the seawater temperature from $10^{\circ}C$ to $60^{\circ}C$. The increase of permeate flux with increase of feed temperature was interpreted as the change of water viscosity and the membrane itself. While the increase of permeate flux could be predicted by the viscosity change in case of nanoflitration membrane, there exists 30% difference between the experiment data and the prediction by the viscosity change in case of reverse osmosis (RO) membrane, which seems to be due to 8% decrease of the pore size in 60caused by the contraction of membrane with the increase of temperature. Therefore, the desalination of seawater should be carried out within the range that the elevation of temperature does not cause the alteration of membrane itself even for the purpose of increasing the permeate flux.

A Study on Reported Status and Management Plan of Marine Facilities in Korea 2. On the Basis of Region and Type of Facilities (국내 해양시설의 신고 현황과 관리 방안에 관한 연구 2. 지역별 및 시설종류별 현황을 중심으로)

  • Kim, Kwang-Soo
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.16 no.3
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    • pp.275-285
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    • 2010
  • Present state of nationwide marine facilities reported to 12 regional maritime affairs and port offices of MLTM in Korea for two years 2008 and 2009 was analyzed based on region and type of facilities, and national management plan was proposed in this study. As of the end of 2009, 8 types of marine facilities were reported to Yeosu regional maritime affairs and port office, while only 3 types of facilities were reported to Pohang, Daesan and Jeju regional offices, respectively. Oil and noxious liquid substances storage facilities belonged in the type of facility which was reported to all of 12 regional offices, and ranged from 11 facilities reported to Pyeongtaek regional office to the respective 38 facilities to Yeosu and Masan regional offices. In pollutants storage facilities, 4 facilities were reported to Masan regional office, 2 facilities to Donghae and Mokpo regional offices, respectively, 1 facility to Yeosu, Gunsan and Pyeongtaek regional offices, respectively, and none of facilities to the other regional offices. Ship construction, repair and scrap facilities belonged in the type of facility which was reported to all of 12 regional offices, and 45% of the facilities were concentrated in Southeastern Sea of Korea centering around Busan and Masan. In cargo handling facilities, 3 facilities were reported to Busan and Masan regional offices, respectively, 1 facility to Daesan regional office, and none of facilities to the other regional offices. In wastes storage facilities, 5 facilities were reported to Ulsan regional office, 4 facilities to Gunsan regional office, 2 facilities to Incheon regional office, 1 facility to Yeosu regional office, and none of facilities to the other regional offices. 65% of nationwide water intake and drainage facilities were concentrated in the areas of Pohang and Mokpo, and 78% of nationwide fishing spots at play were concentrated in the area of Masan. In other marine facilities, 4 facilities were reported to Donghae regional office, 3 facilities to Masan regional office, 2 facilities to Yeosu and Pyeongtaek regional offices, respectively, 1 facility to Incheon and Ulsan regional offices, respectively, and none of facilities to the other regional offices. In integrated marine science base facilities, 3 facilities were reported to Jeju regional office, 1 facility to Yeosu, Ulsan and Gunsan regional offices, respectively, and none of facilities to the other regional offices. The management based on the circumstances of regional offices, the management based on the characteristics of the type of facilities, the amendment of the relevant rules and regulations, facility owner's full knowledge and observance of the relevant rules and regulations with regard to the relevant type of facilities, and positive management actions from national point of view were proposed for national management plans of marine facilities.

Thermodynamic Analysis of Trilateral Cycle Applied to Exhaust Gas of Marine Diesel Engine (선박용 디젤엔진의 배기가스에 적용된 3 변 사이클의 열역학적 분석)

  • Choi, Byung-Chul;Kim, Young-Min
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.9
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    • pp.937-944
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    • 2012
  • The thermodynamic characteristics of a trilateral cycle with water as a working fluid have been theoretically investigated for an electric generation system to recover the waste heat of the exhaust gas from a diesel engine used for the propulsion of a large ship. As a result, when a heat source was given, the efficiencies of energy and exergy were maximized by the specific conditions of the pressure and mass flow rate for the working fluid at the turbine(expander) inlet. In this case, as the condensation temperature increased, the volume expansion ratio of the turbine could be reduced properly; however, the exergy loss of the heat source and exergy destruction of the condenser increased. Therefore, in order to recover the waste exergy from the topping cycle, the combined cycle with a bottoming cycle such as an organic Rankine cycle, which is utilized at relatively low temperatures, was found to be useful.

Change of Heavy Metals in the Surface Sediments of the Lake Shihwa and Its Tributaries (시화호 및 주변 하천 표층 퇴적물의 중금속 분포 변화)

  • Kim, Kyung-Tae;Kim, Eun-Soo;Cho, Sung-Rok;Park, Jun-Kun;Park, Chung-Kil
    • Ocean and Polar Research
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    • v.25 no.4
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    • pp.447-457
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    • 2003
  • In order to understand the distribution of changes of geochemical characteristics in surface sediments according to various environmental changes around the artificial Lake Shihwa, surface sediments were sampled at $13{\sim}15$ sites form 1997 to 1999 and analyzed by C/S analyzer, ICP/MS and AAS. The average $S/C_{org}$ ratio was 0.35 in the surface sediments, which is similar to 0.36, the characteristic ratio of marine sediments. Heavy metal contents and enrichment factors in the surface sediments tended to be decreasing from the head to the mouth of the Lake Shihwa. With the deposition of fine-grained sediments in the central part of lake, anoxic water column induced the sulfides compounds with Cu, Cd and Zn. Metals such as Al, Fe, Cr, Co, Ni, Cu, Zn and Cd except for Mn and Pb showed relatively high correlation coefficients among them. The contents of Cr, Co, Ni, Cu, Zn and Cd in the surface sediments of the lake were two to five times higher than those in the lake before dike construction and also in outer part of the dike. These are mainly due to the Input of untreated industrial and municipal waste-waters into the lake, and the accumulation of heavy metals by limitation of physical mixing. Although metal contents of the surface sediments at the sites near the water-gate due to outer seawater inflow tended to be lower than those during the desalination, heavy metals were deposited in areas around the new industrial complex in the evidence of spatial distribution of heavy metals in the sediments. This is mainly due to the input of untreated waste-waters from tributaries.

Dynamic thermal Design of a 1-ton Class Bio-Hydrogen Production System Simulator Using Industrial Waste Heat and by-Products (산업배열 및 부산물을 활용한 1톤급 바이오수소 생산 시뮬레이터 동적 열설계)

  • Kim, Hyejun;Kim, Seokyeon;Ahn, Joon
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.29 no.5
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    • pp.259-268
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    • 2017
  • This paper proposes a hydrogen-based social economy derived from fuel cells capable of replacing fossil fuels and resolving global warming, It thus provides an entry for developing economically feasible social configurations to make use of bio-hydrogen production systems. Bio-hydrogen production works from the principle that microorganisms decompose water in the process of converting CO to $CO_2$, thereby producing hydrogen. This study parts from an analysis of an existing 157-ton class NA1 bio-hydrogen reactor that identifies the state of feedstock and reactor conditions. Based on this analysis, we designed a 1-ton class bio-hydrogen reactor process simulator. We carried out thermal analyses of biological heat reactions, sensible heat, and heat radiation in order to calculate the thermal load of each system element. The reactor temperature changes were determined by modeling the feed mixing tank capacity, heat exchange, and heat storage tank. An analysis was carried out to confirm the condition of the feed mixing tank, heat exchanger, heat storage tank capacity as well as the operating conditions of the system so as to maintain the target reactor temperature.

Prediction of Crude Protein, Extractable Fat, Calcium and Phosphorus Contents of Broiler Chicken Carcasses Using Near-infrared Reflectance Spectroscopy

  • Kadim, I.T.;Mahgoub, O.;Al-Marzooqi, W.;Annamalai, K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.18 no.7
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    • pp.1036-1040
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    • 2005
  • Near-infrared reflectance spectroscopic (NIRS) calibrations were developed for accurate and fast prediction of whole broiler chicken carcass composition. The Feed and Forage Foss systems Model 5000 Reflectance Transport Model 5000 with near-infrared reflectance spectroscopy (NIRS)-WinISI II windows software was used for this purpose. One equation was developed for the prediction of each carcass component. One hundred and fifty freeze dried broiler whole carcass samples were ground in a Cyclotech 1,093 sample mill and analyzed for dry matter, protein, fat, calcium and phosphate. Samples were divided into two sets: a calibration set from which equations were derived and a prediction set used to validate these equations. The chemical analysis values (mean${\pm}$SD) were calculated based on dry matter basis as follows: dry matter: 33.41${\pm}$2.78 (range: 26.41-43.47), protein: 54.04${\pm}$6.63 (range: 36.20-76.09), fat 35.44${\pm}$8.34 (range: 7.50-55.03), calcium 2.55${\pm}$0.65 (range: 0.99-4.41), phosphorus 1.38${\pm}$0.26 (range: 0.60-2.28). One hundred and three samples were used to calibrate the equations and prediction values. The software used was modified to obtain partial least square regression statistics, as it is the most suitable for natural products analysis. The coefficients of determination ($R^2$) and the standard errors of prediction were 0.82 and 1.83 for the dry matter, 0.96 and 1.98 for protein, 0.99 and 1.07 for fat, 0.90 and 0.30 for calcium and 0.91 and 0.11 for phosphorus, respectively. The present study indicated that NIRS can be calibrated to predict the whole broiler carcass chemical composition, including minerals in a rapid, accurate, and cost effective manner. It neither requires skilled operators nor generates hazardous waste. These findings may have practical importance to improve instrumental procedures for quick evaluation of broiler carcass composition.

The Present State of Domestic Acceptance of Various International Conventions for the Prevention of Marine Pollution (해양오염방지를 위한 각종 국제협약의 국내 수용 현황)

  • Kim, Kwang-Soo
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.12 no.4 s.27
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    • pp.293-300
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    • 2006
  • Domestic laws such as Korea Marine Pollution Prevention Law (KMPPL) which has been mae and amended according to the conclusions and amendments of various international conventions for the prevention a marine pollution such as MARPOL 73/78 were reviewed and compared with the major contents of the relevant international conventions. Alternative measures for legislating new laws or amending existing laws such as KMPPL for the acceptance of major contents of existing international conventions were proposed. Annex VI of MARPOL 73/78 into which the regulations for the prevention of air pollution from ship have been adopted has been recently accepted in KMPPL which should be applied to ships which are the moving sources of air pollution at sea rather tlnn in Korea Air Environment Conservation Law which should be applied to automobiles and industrial installations in land. The major contents of LC 72/95 have been accepted in KMPPL However, a few of substances requiring special care in Annex II of 72LC, a few of items in characteristics and composition for the matter in relation to criteria governing the issue of permits for the dumping of matter at sea in Annex III of 72LC, and a few of items in wastes or other matter that may be considered for dumping in Annex I of 96 Protocol have not been accepted in KMPPL yet. The major contents of OPRC 90 have been accepted in KMPPL. However, oil pollution emergency plans for sea ports and oil handling facilities, and national contingency plan for preparedness and response have not been accepted in KMPPL yet. The waste oil related articles if Basel Convention, which shall regulate and prohibit transboundary movement of hazardous waste, should be accepted in KMPPL in order to prevent the transfer if scrap-purpose tanker ships containing oil/water mixtures and chemicals remained on beard from advanced countries to developing and/or underdeveloped countries. International Convention for the Control if Harmful Anti-Fouling Systems on the Ships should be accepted in KMPPL rather tlnn in Korea Noxious Chemicals Management Law. International Convention for Ship's Ballast Water/Sediment Management should be accepted in KMPPL or by a new law in order to prevent domestic marine ecosystem and costal environment from the invasion of harmful exotic species through the discharge of ship's ballast water.

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Understanding and Attitude to Sustainable Development of College Students for a Nuclear Power Plant Construction in Education for Sustainable Development through Panel Discussion (패널토론을 적용한 지속가능발전교육에서 대학생의 원자력발전소 건립에 대한 지속가능발전 인식과 태도)

  • MOON, Sungchae
    • Journal of Fisheries and Marine Sciences Education
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    • v.27 no.5
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    • pp.1236-1251
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    • 2015
  • This study examined understanding and attitude of sustainable development(SD) of 38 college students in a nuclear power plant construction after education for sustainable development(ESD) through panel discussion. The results were as follows: First, after lesson 66% of students were expected that SD is possible if scientific technology is developed and a frugal life for the protection of environment is carried out. However, the remaining students regarded SD as an ideal concept, because they thought it is not possible to pursue environmental sustainability and socio-economic development simultaneously. Second, students' opinions in the evaluation of constructing a nuclear power plant in three aspects(environment, society and economy) before and after panel discussion were changed as follows; 1) After panel discussion, the objectors increased to 21% in economic evaluation, while the supporters increased to 11% in environmental evaluation. 2) Students majoring in engineering or natural sciences changed their opinions to agree in environmental evaluation because they considered a nuclear power plant safe and eco-energy. However students majoring in social science/business or liberal arts/arts changed their opinions to disagree in economic evaluation because they considered a nuclear power plant as high-cost energy when assessing danger-accidents cost, public consensus cost, operation and maintenance cost, and waste disposal cost. 3) This change of decision-making in students majoring in social science/business or liberal arts/arts after panel discussion was statistically significant(p<0.05). Implications of panel discussion as a teaching and learning method in ESD are also discussed.

Influence of Performance and Internal Flow of a Radial Inflow Turbine with Variation of Vane Nozzle Exit Angles (베인노즐 출구각도에 따른 100kW급 구심터빈의 성능 및 내부유동의 영향)

  • Mo, Jang-Oh;Kim, You-Taek;Oh, Cheol;Lee, Young-Ho
    • Journal of Advanced Marine Engineering and Technology
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    • v.35 no.6
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    • pp.757-764
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    • 2011
  • In this study, we analysed the influence of the performance and inflow flow of a radial inflow turbine with the variation of vane nozzle exit angles for a 100kW class turbine applicable in the waste heat recovery system. For this, three-dimensional CFD analysis was performed using commercial code called ANSYS Fluent 12.1. As the vane nozzle exit angle was more increased the reattachment region near blades of the vane nozzle got smaller, and also the Mach number at vane nozzle exit was observed to be 1 due to the effect of the cross section reduction. Through this study, we expect that the analysed results will be used as the design material for the composition of the turbine optimal design parameters corresponding to the target output power.

Economic Feasibility Study for Commercial Production of Bio-hydrogen (해양바이오수소개발 사업의 상업생산을 위한 예비경제성평가)

  • Park, Se-Hun;Yoo, Young-Don;Kang, Sung Gyun
    • Ocean and Polar Research
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    • v.38 no.3
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    • pp.225-234
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    • 2016
  • This project sought to conduct an economic feasibility study regarding the commercial production of bio-hydrogen by the marine hyperthermophilic archaeon, Thermococcus onnurineus NA1 using carbon monoxide-containing industrial off-gas. We carried out the economic evaluation of the bio-hydrogen production process using the raw material of steel mill by-product gas. The process parameter was as follows: $H_2$ production rate was 5.6 L/L/h; the conversion of carbon monoxide was 60.7%. This project established an evaluation criterion for about 10,000 tonne/year. Inflation factors were considered as 3%. The operating costs were recalculated based on prices in 2014. The total investment required for development was covered 30% by capital and 70% by a loan. The operation cost for the 0.5-year test and integration, and the cost for the first three months in the 50% production period were considered as the working capital in the cost estimation. The costs required for the rental of office space, facilities, and other related costs from the construction through to full-scale production periods were considered as continuing expenses. Materials, energy, waste disposal and other charges were considered as the operating cost of the development system. Depreciation, tax, maintenance and repair, insurance, labor, interest rate charges, general and administrative costs, lubrication and miscellaneous expenses were also calculated. The hydrogen price was set at US$ 4.15/kg for the economic evaluation. As a result, the process was considered to be economical with the payback period of 6.3 years, NPV of 18 billion Won and IRR of 26.7%.