• Bulletin of the Korean Chemical Society
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• v.33 no.8
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• pp.2748-2752
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• 2012

Cr(III) and Co(III) complexes with acetylacetonate were anchored onto a mesoporous MCM-41 through Schiff condensation. The materials were characterized by XRD, FT-IR, BET, CHN and ICP techniques. Elemental analysis of samples revealed that one C=N bond was formed through Schiff condensation on MCM-41 surface. The catalysts were tested for the alcohol oxidations using t-butyl hydroperoxide (TBHP) and $H_2O_2$ as oxidant. The catalytic experiments were carried out at both room temperature and reflux condition. Various solvents such as dichloromethane, acetonitrile and water were examined in the oxidation of alcohols. Among the different solvents, catalytic activity is found more in acetonitrile. Further, the catalysts were recycled three times in the oxidation of alcohols and no major change in the conversion and selectivity is observed, which shows that the immobilized metal-acetylacetonate complexes are stable under the present reaction conditions.

• Journal of The Korean Astronomical Society
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• v.37 no.5
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• pp.553-556
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• 2004

We present a new model for the generation of magnetic fields on large scales occurring at the end of cosmological reionisation. The inhomogeneous radiation provided by luminous sources and the fluctuations in the matter density field are the major ingredients of the model. More specifically, differential radiation pressure acting on ions and electrons gives rise to electric currents which induce magnetic fields on large scales. We show that on protogalactic scales, this process is highly efficient, leading to magnetic field amplitudes of the order of $10^{-1l}$ Gauss. While remaining of negligible dynamical impact, those amplitudes are million times higher than those obtained in usual astrophysical magnetogenesis models. Finally, we derive the relation between the power spectrum of the generated field and the one of the matter density fluctuations. We show in particular that magnetic fields are preferably created on large (galactic or cluster) scales. Small scale magnetic fields are strongly disfavoured, which further makes the process we propose an ideal candidate to explain the origin of magnetic fields in large scale structures.

• Journal of The Korean Astronomical Society
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• v.37 no.5
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• pp.433-438
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• 2004

Clusters of galaxies generally form by the gravitational merger of smaller clusters and groups. Major cluster mergers are the most energetic events in the Universe since the Big Bang. The basic properties of cluster mergers and their effects are discussed. Mergers drive shocks into the intracluster gas, and these shocks heat the intracluster gas. As a result of the impulsive heating and compression associated with mergers, there is a large transient increase in the X-ray luminosities and temperatures of merging clusters. These merger boost can affect X-ray surveys of clusters and their cosmological interpretation. Similar boosts occur in the strong lensing cross-sections and Sunyaev-Zeldovich effect in merging clusters. Merger shock and turbulence associated with mergers should also (re)accelerate nonthermal relativistic particles. As a result of particle acceleration in shocks and turbulent acceleration following mergers, clusters of galaxies should contain very large populations of relativistic electrons and ions. Observations and models for the radio, extreme ultraviolet, hard X-ray, and gamma-ray emission from nonthermal particles accelerated in these shocks will also be described. Gamma-ray observations with GLAST seem particularly promising.

• KSBB Journal
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• v.15 no.3
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• pp.318-322
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• 2000

An oxygen-sensitive fumarate reductase has been purified from the cytosol fraction of the Enterococcus faecalis RKY1 grown anaerobically on a defined medium containing glycerol and fumarate. A major portion of the purification was performed with employing Triton X-100 and reducing agents by Phenyl-sepharose CL-4B DEAE-sepharose and Dephadex G-150 The final activity was 0.42 unit/mg. The deduced molecular mass of active band was 66 kDa. The optimal pH and temperature for the activity were 7.0 and 38$^{\circ}C$ respectively. The enzyme activity was not affected by 1mM metal ions such as bacl2 $.$2H2O HgCl2 MnCl2$.$4H2O ZnCl2 CuCl2$.$2H2O Mgcl2$.$6H2O FeSo4$.$7H2O and by EDTA. Partially purified enzyme ws yellow in color ; spectroscopic study indicated the presence of flavins as a cofactor.

• Bulletin of the Korean Space Science Society
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• 2011.04a
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• pp.28.1-28.1
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• 2011

Radiation-induced displacement damage which has caused the increase of the dark current in the focal plane adopted in the Ozone Monitoring Instrument (OMI) was studied in regards of the primary protons and the secondaries generated by the protons in the orbit. By using the Monte Carlo N-Particle Transport Code System (MCNPX) version 2.4.0 along with the Stopping and Range of Ions in Matter version 2010 (SRIM2010), effects of the primary protons as well as secondary particles including neutron, electron, and photon were investigated. After their doses and fluxes that reached onto the charge-coupled device (CCD) were examined, displacement damage induced by major sources was presented.

• 한국신재생에너지학회:학술대회논문집
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• 2006.11a
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• pp.168-171
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• 2006

The Korean Solar Thermal Industry hopes to realize 1 Million Solar Thermal Roofs. According to the 2nd Renewable Basic Plan : 2003-2012 the Government showed a very aggressive Solar Thermal Deployment Plan including Solar Thermal Apartment Housings Program. Owing to the Vision Statement such as Million Solar Thermal Roofs Program Korean Solar thermal Industry also can bring another shinny days Especially the more solar thermal applications such as to the Apartment Housings and Green Villages could bring a sustainable Solar Society Korea The RPA Program by the 9 Major Non-Private Energy Corporal ions and the RPS Program for the Solar Thermal Energy shall be another useful policy for the realization of Million Solar Korea era.

• Journal of Korean Society for Atmospheric Environment
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• v.5 no.2
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• pp.1-11
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• 1989

Sandy dust phenomena was observed from April 19 to 23, 1988 in Seoul. During this period it rained and the precipitation was collected to investigate the rain chemistry. This study was carried out to analyzed the chemical composition of precipitation by the measurements of conditivity, cations $(H^+, NH_4^+, K^+, Na^+, Ca^{2+}, MG^{2+})$, and anions $(SO_4^{2-}, NO_3^-, Cl^-, F^-, Br^-)$ which are believed to be the major ions playing an important role in the acidity of rain water. During the period of sandy dust phenomena the range of pH value and conductivity concentration of rainwater were 6.0-6.7, 172-254 $\mu \mho/cm$. The anions and cations concentrations increased and the orders of these concentrations were $SO_4^{2-} > Cl^- > NO_3^- > Na^+ > Ca^{2+} > NH_4^+ > Mg^{2+}$. THe principal chemical compounds of rainwater were estimated at $(NH_4)_2 SO_4, CaSO_4, NaCl, and MgCl_2$.

• Reproductive and Developmental Biology
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• v.28 no.3
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• pp.147-153
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• 2004

The oocyte and its surrounding granulosa cells co-exist in a closed compartment called a follicle, although they receive many signals from other parts of the body. It is well established that the intercellular communications between the oocyte and granulosa cells are required for normal oocyte development and ovulation during folliculogenesis. Gap junctions are intercellular channels allowing the direct transmission of ions and small molecules between coupled cells. Several lines of studies have shown that multiple connexins (Cx, subunits of gap junction) are expressed in mammalian ovarian follicles. Among them, two major connexins Cx37 and Cx43 are expressed in different manner. While the gap junction channels formed by Cx37 are localized between the oocyte and encompassing granulosa cells, the intercellular channels by Cx43 are located between granulosa cells. In this review, I will summarize the general properties of gap junction channels and discuss their possible formation (or compatibility) of intercellular channels formed by the oocyte and granulosa cells.

• 한국연소학회:학술대회논문집
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• 2002.06a
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• pp.179-184
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• 2002

Interaction between flames and non-thermal plasmas of DBD type has been experimentally investigated. Vigorous streamers were observed under flame conditions because of the increase of reduced field (electrical) at high temperature as well as the seeding of free electrons and ions generated inside the flame. Flame lengths were significantly shortened as the applied voltage increased on account of intense mixing by ionic winds and soot-induced flows. Flame luminosities severely decreased under plasma conditions, which means the reduction of soot, since the residence time was reduced because of the flame shortening. Temperature and major species concentrations measured by FTIR were not changed despite the plasma generation. which shows overall chemistries were not affected by non-thermal plasmas.

• Journal of Microbiology and Biotechnology
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• v.13 no.5
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• pp.641-646
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• 2003

An accurate and efficient method for measuring the mass of hairy roots using conductometry is established. A conductivity equation expressed in terms of the concentration of the ion species in the medium is suggested. By using this equation, the effect of the individual ions on the total conductivity can be quantitatively analyzed. An equation for the in situ estimation of the cell growth coefficient for determining the mass of hairy roots is established based on measurements of the nitrogen concentration and conductivity during cultivation. The proposed equation does not require preliminary experiments to determine the cell growth coefficient. Instead, the physiological characteristics of the plant species are reflected by introducing the cellular nitrogen content. Since the cell growth coefficient is determined by measuring the major ionic nutrient concentrations, it is more effective to express the dynamics of an actual culture system. This improved method for determining the mass of hairy roots was successfully utilized in a fed-batch culture system.