• 자원환경지질
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• 제29권4호
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• pp.411-419
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• 1996

The Janggun magnetite deposits occur as the lens-shaped magnesian skarn, magnetite and base-metal sulfide orebodies developed in the Cambrian Janggun Limestone Formation. The K-Ar age of alteration sericite indicates that the mineralization took place during late Cretaceous age (107 to 70 Ma). The ore deposition is divided into two stages as a early skarn and late hydrothermal stage. Mineralogy of skara stage (107 Ma) consists of iron oxide, base-metal sulfides, Mg-Fe carbonates and some Mg- and Ca-skarn minerals, and those of the hydrothermal stage (70 Ma) is deposited base-metal sulfides, some Sb- and Sn-sulfosalts, and native bismuth. Based on mineral assemblages, chemical compositions and thermodynamic considerations, the formation temperature, $-logfs_2$, $-logfo_2$ and pH of ore fluids progressively decreased and/or increased with time from skarn stage (433 to $345^{\circ}C$, 8.8 to 9.9 atm, 29.4 to 31.6 atm, and 6.1 to 7.2) to hydrothermal stage (245 to $315^{\circ}C$, 11.2 to 12.3 atm, 33.6 to 35.4 atm, and 7.3 to 7.8). The ${\delta}^{34}S$ values of sulfides have a wide range between 3.2 to 11.6‰. The calculated ${\delta}^{34}S_{H_2S}$ values of ore fluids are relatively homo-geneous as 2.9 to 5.4‰ (skam stage) and 8.7 to 13.5‰ (hydrothermal stage), which are a deep-seated igneous source of sulfur indicates progressive increasing due to the mixing of oxidized sedimentary sulfur with increasing paragenetic time. The ${\delta}^{13}C$ values of carbonates in ores range from -4.6 to -2.5‰. Oxygen and hydrogen isotope data revealed that the ${\delta}^{38}O_{H_2O}$ and ${\delta}D$ values of ore fluids decreased gradually with time from 14.7 to 1.8‰ and -85 to -73‰ (skarn stage), and from 11.1 to -0.2‰ and -87 to -80‰ (hydrothermal stage), respectively. This indicates that magmatic water was dominant during the early skarn mineralization but was progressively replaced by meteoric water during the later hydrothermal replacement.

• 한국자기학회지
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• 제21권5호
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• pp.157-162
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• 2011

황산제일철/황산제이철의 몰비와 침전제 종류(NaOH, $NH_4OH$)를 변화시켜 공침법으로 $Fe_3O_4$를 합성하였다. 합성한 분말의 특성을 평가한 결과 모든 실험조건(황산제일철/황산제이철의 몰비와 침전제의 종류)에서 단일상의 나노 크기 $Fe_3O_4$가 생성 되었다. NaOH를 침전제로 사용한 경우에 $NH_4OH$를 침전제로 사용한 경우보다 입자크기가 작고, 좁은 입도분포를 나타내었다. 동일한 침전제를 사용할 경우에는 혼합 황산철(황산제일철/황산제이철)의 몰비가 증가할수록 입자크기와 결정자 크기가 증가하였으며 입도 분포는 넓어졌다. 모든 실험조건에서 합성된 $Fe_3O_4$ 분말은 초상자성을 나타내었으며 침전제로 $NH_4OH$를 사용하고 혼합 황산철의 몰비를 2.5로 하였을 때 가장 높은 포화자화 값 72 emu/g을 갖는 $Fe_3O_4$를 합성할 수 있었다.

• 대한환경공학회지
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• 제31권7호
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• pp.473-482
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• 2009

본 연구에서는 여러 몰비의 망간과 철을 함유한 용액을 사용하여 담체인 모래 표면에 이들 산화물들이 동시에 코팅된 산화철 및 산화망간 코팅사(IMCS)를 제조하였으며, X-선 회절분석을 통하여 제조한 IMCS 표면의 광물종 규명과 이들에 의한 As(III) 산화 및 As(V) 흡착능을 평가하였다. 망간과 철을 동시에 코팅한 IMCS들에서의 철 및 망간의 총량은 단일금속용액으로 코팅시킨 담체(ICS 혹은 MCS)에 비하여 감소하였지만 코팅된 철산화물은 goethite와 magnetite의 혼합물 그리고 망간 산화물은 ${\gamma}-MnO_2$로서 매우 유사하였다. IMCS에 의한 As(V) 흡착량은 코팅된 망간보다는 철 함량에 의해 크게 영향을 받았다. 그리고 IMCS에 의한 As(V) 흡착량은 1가 및 2가 이온들로 이루어진 이온세기 화학종으로 이온세기를 고정하였을 때에는 큰 영향을 받지 않았으나 $PO_4\;^{3-}$와 같은 3가 화학종을 사용한 경우에는 크게 억제되었다. 망간만 코팅시켜 얻은 MCS의 경우, NaCl 및 $NaNO_3$와 같은 1가 이온세기 화학종이 존재하는 경우는 $PO_4\;^{3-}$와 같은 3가 이온세기 화학종이 존재하는 경우에서 보다 2배 이상의 산화효율을 나타내었다. 이에 반해 망간과 철이 함께 코팅된 7:3, 5:5, 3:7 몰비의 경우에는 $PO_4\;^{3-}$를 이온세기 화학종으로 사용한 경우가 다른 이온세기 화학종이 존재하는 경우에서 보다 오히려 As(III) 산화력이 높게 나타났는데 이것은 $PO_4\;^{3-}$가 As(V)와 IMCS 표면에 대한 경쟁흡착을 함에 따른 결과로 나타났다.

• Journal of Magnetics
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• 제21권3호
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• pp.460-467
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• 2016

Magnetic hyperthermia mediated by superparamagnetic particles is mainly based in sinusoidal waveforms as excitation signals. Temperature changes are conventionally explained by rotation of the particles in the surrounding medium. This is a hypothesis quite questionable since habitual experimental setups only produce changes in the magnetic module, not in the field lines trajectories. Theoretical results were tested by changing the waveform of the exciting signal in order to compare non-sinusoidal signals against sinusoidal signals. Experiments were done at different frequencies: 200 KHz, 400 KHz, 600 KHz, 800 KHz and 1 MHz. Superparamagnetic Iron Oxide samples (SPION), made of magnetite ($Fe_3O_4$) and suspended in water (100 mg/ml), were used. Magnetic field strength varies from $0.1{\pm}0.015KA/m$ to $0.6{\pm}0.015KA/m$. In this study was observed that the power loss depends on the applied frequency: for 1 to 2.5 RMS current the responses for each signal are part of the higher section of the exponential function, and for 3.5 to 8 RMS current the response is clearly the decrement exponential function's tale (under $1{\times}10^3LER/gr$).

• 한국광물학회지
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• 제16권1호
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• pp.107-123
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• 2003

본 연구는 0가 철 (ZVI)의 설치위치와 전극의 배열에 따른 다양한 조합의 전기적 투수성 반응벽을 대상으로 트리클로로에틸렌의 탈염소화 반응에 의한 정화시 ZVI의 부식에 기인하는 광물상침전물에 대해 알아보고, 이에 대한 조절 요소를 알아보고자 한다. 광물학적 연구 결과, 지하수 유입부의 ZVI 시료는 상대적으로 많은 레피도크로사이트, 훼리하이드라이트 혹은 철 수산화물과 (phospho)siderite가 산출되는 반면, 용출부의 ZVI 시료는 아카가나이트, 자철석/마그헤마이트, 그리고 중간 산물인 green rust (CR) I 과 CR II가 산출되었다. 이러한 광물 조합의 변화는 용존 산소 및 pH의 상승에 주로 기인한 것으로 나타났다. 또한 전기적 투수성 반응벽 내에 산출되는 광물상 침전물들의 조절 요소들은 (1) pH, (2) 용존산소, (3) 철의 부식시 중간 산물, (4) 음이온 종류 등으로 밝혀졌다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2008년도 추계 학술발표회 제20권2호
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• pp.785-788
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• 2008

선박의 안전성을 유지하기 위하여 사용하는 밸러스트는 그 용적에 의해 적재 능력이 감소되는 문제점을 가지고 있다. 이를 해결하기 위해 선박의 밸러스트에 고중량 콘크리트를 적용하여 연구를 진행하였다. 고중량 콘크리트 제조에는 자철광, 갈철광 등 밀도가 큰 골재를 사용하는 것이 일반적이나 이러한 골재는 수급이 어렵고 고가인 단점을 가지고 있다. 이에 본 연구에서는 고중량이며 수급이 용이한 폐분철을 이용하여 고중량 밸러스트 콘크리트의 품질특성 및 주의사항을 검토하여 현장적용 타당성을 검증하고자 하였다. 고중량 밸러스트 콘크리트는 현장 특성상 압축강도의 요구치는 없으나, 밸러스트 탱크의 밀실한 채움을 위해 고유동 및 2700kg/m$^3$이상의 단위용적질량이 요구된다. 예비 실험을 통해 설계된 현장배합의 온도균열지수는 균열을 제한할 수 있는 수준으로 나타났으며, 복합부식실험 결과 염화물에 대한 저항성 측면에서 우수한 성능을 보였다. 이러한 결과로 폐분철을 이용한 고중량 콘크리트를 밸러스트의 제조 및 시공이 가능한 것으로 나타났으며, 적재 능력이 증가함으로 선박운송에 큰 도움이 될 것으로 판단된다.

• 자원환경지질
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• 제2권1호
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• pp.13-33
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• 1969

The Mulkum mine, located in Mulkum-myon, Yangsan-Kun, Kyeongsang Province, is one of the biggest iron mine in Korea. The geology of this mine and its vicinity consists of Chusan andesitic rocks and Datae-dong andesite porphyry of the Kyeongsang System which were intruded by biotite granite widely distributed near the vicinity of Mulkum-ni. The ore deposits, embedded in Dotae-dong andesite porphyry, are fissure-filling vein type in origin. Up to present ore bodies of Main vein, No. 2 vein, Eastern No. 1, 2 vein and Western No. 1 vein are exploited. Generally the veins strike N 10-25 E and dip to 60-90 SE. The proved length of vein is more than 500 meters and its depth 150 meters in Main vein with 3-4 meters of thickness in average. Ore minerals are mainly magnetite and locally associated with small amounts of hematite, sphecularite and chalcopyrite. Gangue minerals are quartz, epidote, chlorite, pyroxene, and garnet, etc. The modes of occurrence of vein are as follow; 1. Branching and parallel vein patterns are observed around main shaft in -1 level. 2. Multiple cymoid loops and subrectangular vein patterns are observed around main shaft in -2 level. 2. Single vein patterns are observed in -3 and -5 level. The ore-shoots plunge northeasterly about 20-30 degrees. In conclusion, the tectonically fractured zone belongs to the poorly mineralized zone and shoots are formed as single vein type. The general trends of one-shoots must be applied the prospecting of the deep-seated ore body in the deposits.

• Advances in nano research
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• 제4권1호
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• pp.1-14
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• 2016

Superparamagnetic iron oxide nanoparticles (Nps), composed of magnetite, $Fe_3O_4$, or maghemite, ${\gamma}-Fe_2O_3$, core and biocompatible polymer shell, such as dextran or chitozan, have recently found wide applications in magnetic resonance imaging, contrast enhancement and hyperthermia therapy. For different diagnostic and therapeutic applications, current attempt is focusing on the synthesis and biomedical applications of various ferrite Nps, such as $CoFe_2O_4$ and $MnFe_2O_4$, differing from iron oxide Nps in charge, surface chemistry and magnetic properties. This study is focused on the synthesis of manganese ferrite, $MnFe_2O_4$, Nps by most commonly used chemical way pursuing better control of their size, purity and magnetic properties. Co-precipitation syntheses were performed using aqueous alkaline solutions of Mn(II) and Fe(III) salts and NaOH within a wide pH range using various hydrothermal treatment regimes. Different additives, such as citric acid, cysteine, glicine, polyetylene glycol, triethanolamine, chitosan, etc., were tested on purpose to obtain good yield of pure phase and monodispersed Nps with average size of ${\leq}20nm$. Transmission electron microscopy (TEM), X-ray diffraction, energy dispersive X-ray spectroscopy (EDX), $M\ddot{o}ssbauer$ spectroscopy down to cryogenic temperatures, magnetic measurements and inductively coupled plasma mass spectrometry were employed in this study.

• 자원환경지질
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• 제56권6호
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• pp.745-764
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• 2023

In the Republic of Congo, Banded iron formations (BIFs) occur in two areas: the Chaillu Massif and the Ivindo Basement Complex, which are segments of the Archean Congo craton outcropping in the northwestern and southwestern parts of the country. They show interesting potential with significant mineral resources reaching 2 Bt and grades up to 60% Fe. BIFs consist mostly of oxide-rich facies (hematite/magnetite), but carbonate-rich facies are also highlighted. They are found across the country within the similar geological sequences composed of amphibolites, gneisses and greenschists. The Post-Archean Australian Shale (PAAS)-normalized patterns of BIFs show enrichment in elements such as SiO₂, Fe₂O₃, CaO, P₂O₅, Cr, Cu, Zn, Nb, Hf, U and depletion in TiO₂, Al₂O₃, MgO, Na₂O, K₂O, Sc, Th, Ba, Zr, Rb, Ni, V. REE diagrams show slight light REEs (rare earth elements; LREEs) compared to heavy REEs (HREEs), and positive La and Eu anomalies. The lithological associations, as well as the very high (Eu/Eu^*)_SN ratios> 1.8 shown by the BIFs, suggest that they are related to Algoma-type BIFs. The positive correlations between Zr and TiO₂, Al₂O₃, Hf suggest that the contamination comes mainly from felsic rocks, while the absence of correlations between MgO and Cr, Ni argues for negligeable contributions from mafic sources. Pr/Pr^* vs. Ce/Ce^* diagram indicates that the Congolese BIFs were formed in basins with redox heterogeneity, which varies from suboxic to anoxic and from oxic to anoxic conditions. They were formed through hydrothermal vents in the seawater, with relatively low proportions of detrital inputs derived from igneous sources through continental weathering. Some Congolese BIFs show high contents in Cr, Ni and Cu, which suggest that iron (Fe) and silicon (Si) have been leached through hydrothermal processes associated with submarine volcanism. We discussed their tectonic setting and depositional environment and proposed that they were deposited in extensional back-arc basins, which also recorded hydrothermal vent fluids.

• 자원환경지질
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• 제26권3호
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• pp.267-278
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• 1993

Serpentinite rocks which are composed mainly of olivine, serpentine and clinopyroxene, cropped out in the anorogenic Kyongsang sedimentary basin of South Korea. The serpentinites contain high content of MgO (36.87~41.99%) and 47~67 ppm Co, 1185~2042 ppm Ni and 979~3582 ppm Cr, which are quite similar to those of ultrabasic rocks such as peridotite and dunite. Isotopic compositions of serpentinites range from -95.5 to -105.7‰ in ${\delta}D$ and +1.7 to 7.1‰ in ${\delta}^{18}O$ corresponding to the continental antigorite type. A wide variation of oxygen isotopic values and $H_2O^+$ content of serpentinites reflect the different water/rock ratios during serpentinization processes. Formation temperature of serpentine minerals are estimated to be unusually high temperature of $488{\sim}646^{\circ}C$ by serpentine-magnetite isotopic fractionation, which belong to continental antigorite type. Calculated ${\delta}^{18}O$ value of serpentinized fluid during serpentinization is suggested that the hydrothermal fluid responsible for serpentinization be originated from the magmatic fluid with a minor influx of paleo-meteoric water in this area.