• 제목/요약/키워드: magnetic oxide

검색결과 513건 처리시간 0.028초

Expanded Graphite 산화물과 자성 나노입자의 복합화와 자기적 특성 (Synthesis and Magnetic Properties of Expanded Graphite Oxide/Magnetic Nanoparticle Composite)

  • 노일표;임현준;강명철;이찬혁;심인보
    • 한국자기학회지
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    • 제22권1호
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    • pp.11-14
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    • 2012
  • Expanded graphite 산화물과 자성 나노입자의 복합화는 화학적 방법을 이용하였으며, Ni과 Co 나노입자를 사용하여 간단한 방법으로 자기적 특성을 가지는 graphite 산화물을 합성하였다. $H_2SO_4$$(NH_4)SO_4$을 첨가한 혼합 용액을 제조하여, natural graphite와 반응시키고, 1차 열처리하여 expanded graphite를 제조하였다. $1050^{\circ}C$에서 30초간 급속 2차 열처리와 화학적 산화 과정을 거쳐 expanded graphite oxide로 변화시킨 뒤에 $Ni(acac)_2$, $Co(acac)_3$과 화학적 반응을 통하여 Expanded graphite 산화물자성 나노입자 복합체를 제조하였다. 결정 구조 분석을 위하여 x-선 회절 측정을 수행하였으며, Raman 분광 측정으로 graphite 산화물의 층상 구조를 분석하였다. 미세구조 분석을 위하여 투과전자현미경 측정을 수행하였으며, 진동시료형 자화율측정기를 이용하여 복합체의 자기적 특성을 연구하였다. 이러한 연구 결과는 graphite 화합물과 자성 물질의 복합화를 위한 기저 기술로 활용될 수 있을 것이다.

Thermo-sensitive Electrospun Fibrous Magnetic Composite Sheets

  • Choi, Jungsu;Kim, Jinu;Yang, Heejae;Ko, Frank K.;Kim, Ki Hyeon
    • Journal of Magnetics
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    • 제20권3호
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    • pp.215-220
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    • 2015
  • The PVDF fibrous composite filled with iron oxide nanoparticles were prepared by using the electrospinning technique. The electrospun composite have the thickness in the range of $60-80{\mu}m$ with the average fibrous diameters of 500-900 nm. The magnetizations of PVDF fibrous composite filled with iron oxide nanoparticles showed 4.5 emu/g, 3.1 emu/g and 1.6 emu/g at 1.5 T of external magnetic field for 20 wt.%, 10 wt.% and 5 wt.% iron oxide nanoparticles, respectively. The heat elevation of the magnetic composite were measured under various AC magnetic fields, frequency and the ambient temperatures. The temperature reached up to $46.3^{\circ}C$ from $36^{\circ}C$ at 128 Oe and 355 kHz for 20 wt.% iron oxide nanoparticles filled in PVDF fibrous composite sheet. The specific absorption rate of theses sheets increased from 0.041 W/g to 0.236 W/g with the increment of AC magnetic field from 90 Oe to 167 Oe at 190 kHz, respectively.

Removal of arsenic from aqueous phase using magnetized activated carbon and magnetic separation

  • Kwon, H.W.;Shin, T.C.;Kim, J.J.;Ha, D.W.;Kim, Min Gyu;Kim, Young-Hun
    • 한국초전도ㆍ저온공학회논문지
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    • 제20권2호
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    • pp.1-5
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    • 2018
  • Arsenic (As) is one of the elements having most harmful impact on the human health. Arsenic is a known carcinogen and arsenic contamination of drinking water is affecting on humans in many regions of the world. Adsorption has been proved most preferable technique for the removal of arsenic. Many researchers have studied various types of solid materials as arsenic adsorbent, and iron oxide and its modified forms are considered as the most effective adsorbent in terms of adsorption capacity, recovery, and economics. However, most of all iron oxides have small surface area in comparing with common adsorbents in environmental application such as activated carbon but the activated carbon has weak sorption affinity for arsenic. We have used an activated carbon as base adsorbent and iron oxide coating on the activated carbon as high affinity sorption sites and giving magnetic attraction ability. In this study, adsorption properties of arsenic and magnetic separation efficiency of the magnetized activated carbon (MAC) were evaluated with variable iron oxide content. As the iron oxide content of the MAC increased, adsorption capacity has also gradually increased up to a point where clogging by iron oxide in the pore of activated carbon compensate the increased sorption capacity. The increase of iron oxide content of the MAC also affected magnetic properties, which resulted in greater magnetic separation efficiency. Current results show that magnetically modified common adsorbent can be an efficiency improved adsorbent and a feasible environmental process if it is combined with the magnetic separation.

선 대 평판형 플라즈마 반응기를 이용한 자계 시뮬레이션과 질소산화물제거 특성 (Simulation of Magnetic Field and Removal Characteristic of Nitrogen Oxide Using Wire-Plate Type Plasma Reactor)

  • 이현수;박재윤
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제52권9호
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    • pp.407-411
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    • 2003
  • The purpose of this paper is to study the removal of nitrogen oxide(NOx) using a wire-plate type plasma reactor with magnet attached for indoor air purification. In order to produce a more effective reactor, we conducted magnetic field simulations. The results of the magnetic field simulations show that NOx can be removed more effectively. The results from the magnetic field simulation show that when 7 magnets were applied to the reactor, the magnetic flux density was at its highest amount than when using 0, 3, or 5 magnets. From the data obtained by the simulation results a plasma reactor was made and thus, several experiments were conducted. The best removal efficiency was obtained with 14 W AC power to the reactor with 5 magnets.

Crystallographic and Magnetic Properties of Iron Oxide Nanoparticles for Applications in Biomedicine

  • Lee, Sang-Won;Woo, Kyoung-Ja;Kim, Chul-Sung
    • Journal of Magnetics
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    • 제9권3호
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    • pp.83-85
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    • 2004
  • Magnetic nanoparticles have been investigated for use as biomedical purposes for several years. For biomedical applications the use of particles that present superparamagnetic behavior at room temperature is preferred [1-4]. To control the magnetic materials by magnetic field is essential locate particle to the suitable destination on feeding by injection. In order to use them properly, the particles should be nano size. However there are many difficulties in applications, because there is lack of identifications in nano magnetic properties. In our studies, structural and magnetic properties of iron oxide nanoparticles were investigated by XRD, VSM, TEM, and Mossbauer spectroscopy. At 13 K, hyperfine fields of ${\gamma}-Fe_2O_3$ were 516 kOe and 490 kOe, that of $Fe_3O_4$ were 517 kOe and 482 kOe. The saturation magnetizations were 21.42 emu/g and 39.42 emu/g. The particle size of powders is 5~19 nm.

알루미나 세라믹스 ELID연삭면의 자기연마 가공 특성 (Application of Magnetic Assisted Polishing for ELID Ground Surface of Aluminum Oxide Ceramics)

  • 이용철;정명원;김태규;곽태수
    • 한국정밀공학회지
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    • 제30권12호
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    • pp.1259-1264
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    • 2013
  • This study has focused on the application of magnetic assisted polishing for ELID ground surface of aluminum oxide ceramics. Aluminum oxide ceramics has been widely used as advanced materials for electric, optic, mechanic, chemical usage and so on. In this study, ELID grinding and magnetic assisted polishing technology was adopted for high-effective manufacturing and high quality surface of ceramic parts. The characteristic of MAP machining have been evaluated by the value of surface roughness and surface profile before and after magnetic assisted polishing. As the results of experiments, the surface roughness after magnetic assisted polishing has shown a significant improvement and the surface roughness was more improved when the feed rate of tool became slow.

Aerosol Synthesis and Growth Mechanism of Magnetic Iron Nanoparticles

  • Tolochko, O.V.;Vasilieva, E.S.;Kim, D.;Lee, D.W.;Kim, B.K.
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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    • pp.446-447
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    • 2006
  • Magnetic oxide-coated iron nanoparticles with the mean size ranging from 6 to 75 nm were synthesized by aerosol method using iron carbonyl as a precursor under the flowing inert gas atmosphere. Oxide shells were formed by passivation of asprepared iron particles. The influence of experimental parameters on the nanoparticles' microstructure, phase composition and growth behavior as well as magnetic properties were investigated and discussed in this study.

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Removal of iron oxide scale from feed-water in thermal power plant using superconducting magnetic separation

  • Nishijima, S.
    • 한국초전도ㆍ저온공학회논문지
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    • 제21권2호
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    • pp.22-25
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    • 2019
  • The superconducting magnetic separation system has been developing to separate the iron oxide scale from the feed water of the thermal power plant. The accumulation in the boiler lowers the heat exchange rate or in the worst case damages it. For this reason, in order to prevent scale generation, controlling pH and redox potential is employed. However, these methods are not sufficient and then the chemical cleaning is performed regularly. A superconducting magnetic separation system is investigated for removing iron oxide scale in a feed water system. Water supply conditions of the thermal power plant are as follows, flow rate 400 t / h, flow speed 0.2 m / s, pressure 2 MPa, temperature $160-200^{\circ}C$, amount of scale generation 50 - 120 t / 2 years. The main iron oxide scale is magnetite (ferromagnetic substance) and its particle size is several tens ${\mu}m$. As the first step we are considering to introduce the system to the chemical cleaning process of the thermal power plant instead of the thermal power plant itself. The current status of development will be reported.