• Title/Summary/Keyword: magnetic oxide

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Synthesis and Magnetic Properties of Expanded Graphite Oxide/Magnetic Nanoparticle Composite (Expanded Graphite 산화물과 자성 나노입자의 복합화와 자기적 특성)

  • Roh, Il-Pyo;Yim, Hyun-Joon;Kang, Myung-Chul;Rhee, Chan-Hyuk;Shim, In-Bo
    • Journal of the Korean Magnetics Society
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    • v.22 no.1
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    • pp.11-14
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    • 2012
  • The composites of expanded graphite oxide and magnetic nanoparticle (Ni and Co) were synthesized by using simple chemical method. From the raw material natural graphite, the expanded graphite was fabricated using sulfuric acid and $1^{st}$ heat treatment at $600^{\circ}C$ for 1 hour. The expanded graphite was changed to expanded graphite oxide by 2nd heat treatment at $1050^{\circ}C$ for 15 sec and chemical oxidation. The expanded graphite oxide/1-methyl-2-pyrrolidone solution reacts with the magnetic nanoparticle to form a magnetic graphite oxide composite. These graphite-based materials were characterized by x-ray diffractometer, Raman spectroscopy, transmission electron microscope, and vibration sample magnetometer. We expect that these results of this paper were become basis research of graphite oxide composite.

Thermo-sensitive Electrospun Fibrous Magnetic Composite Sheets

  • Choi, Jungsu;Kim, Jinu;Yang, Heejae;Ko, Frank K.;Kim, Ki Hyeon
    • Journal of Magnetics
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    • v.20 no.3
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    • pp.215-220
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    • 2015
  • The PVDF fibrous composite filled with iron oxide nanoparticles were prepared by using the electrospinning technique. The electrospun composite have the thickness in the range of $60-80{\mu}m$ with the average fibrous diameters of 500-900 nm. The magnetizations of PVDF fibrous composite filled with iron oxide nanoparticles showed 4.5 emu/g, 3.1 emu/g and 1.6 emu/g at 1.5 T of external magnetic field for 20 wt.%, 10 wt.% and 5 wt.% iron oxide nanoparticles, respectively. The heat elevation of the magnetic composite were measured under various AC magnetic fields, frequency and the ambient temperatures. The temperature reached up to $46.3^{\circ}C$ from $36^{\circ}C$ at 128 Oe and 355 kHz for 20 wt.% iron oxide nanoparticles filled in PVDF fibrous composite sheet. The specific absorption rate of theses sheets increased from 0.041 W/g to 0.236 W/g with the increment of AC magnetic field from 90 Oe to 167 Oe at 190 kHz, respectively.

Removal of arsenic from aqueous phase using magnetized activated carbon and magnetic separation

  • Kwon, H.W.;Shin, T.C.;Kim, J.J.;Ha, D.W.;Kim, Min Gyu;Kim, Young-Hun
    • Progress in Superconductivity and Cryogenics
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    • v.20 no.2
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    • pp.1-5
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    • 2018
  • Arsenic (As) is one of the elements having most harmful impact on the human health. Arsenic is a known carcinogen and arsenic contamination of drinking water is affecting on humans in many regions of the world. Adsorption has been proved most preferable technique for the removal of arsenic. Many researchers have studied various types of solid materials as arsenic adsorbent, and iron oxide and its modified forms are considered as the most effective adsorbent in terms of adsorption capacity, recovery, and economics. However, most of all iron oxides have small surface area in comparing with common adsorbents in environmental application such as activated carbon but the activated carbon has weak sorption affinity for arsenic. We have used an activated carbon as base adsorbent and iron oxide coating on the activated carbon as high affinity sorption sites and giving magnetic attraction ability. In this study, adsorption properties of arsenic and magnetic separation efficiency of the magnetized activated carbon (MAC) were evaluated with variable iron oxide content. As the iron oxide content of the MAC increased, adsorption capacity has also gradually increased up to a point where clogging by iron oxide in the pore of activated carbon compensate the increased sorption capacity. The increase of iron oxide content of the MAC also affected magnetic properties, which resulted in greater magnetic separation efficiency. Current results show that magnetically modified common adsorbent can be an efficiency improved adsorbent and a feasible environmental process if it is combined with the magnetic separation.

Simulation of Magnetic Field and Removal Characteristic of Nitrogen Oxide Using Wire-Plate Type Plasma Reactor (선 대 평판형 플라즈마 반응기를 이용한 자계 시뮬레이션과 질소산화물제거 특성)

  • 이현수;박재윤
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.52 no.9
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    • pp.407-411
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    • 2003
  • The purpose of this paper is to study the removal of nitrogen oxide(NOx) using a wire-plate type plasma reactor with magnet attached for indoor air purification. In order to produce a more effective reactor, we conducted magnetic field simulations. The results of the magnetic field simulations show that NOx can be removed more effectively. The results from the magnetic field simulation show that when 7 magnets were applied to the reactor, the magnetic flux density was at its highest amount than when using 0, 3, or 5 magnets. From the data obtained by the simulation results a plasma reactor was made and thus, several experiments were conducted. The best removal efficiency was obtained with 14 W AC power to the reactor with 5 magnets.

Crystallographic and Magnetic Properties of Iron Oxide Nanoparticles for Applications in Biomedicine

  • Lee, Sang-Won;Woo, Kyoung-Ja;Kim, Chul-Sung
    • Journal of Magnetics
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    • v.9 no.3
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    • pp.83-85
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    • 2004
  • Magnetic nanoparticles have been investigated for use as biomedical purposes for several years. For biomedical applications the use of particles that present superparamagnetic behavior at room temperature is preferred [1-4]. To control the magnetic materials by magnetic field is essential locate particle to the suitable destination on feeding by injection. In order to use them properly, the particles should be nano size. However there are many difficulties in applications, because there is lack of identifications in nano magnetic properties. In our studies, structural and magnetic properties of iron oxide nanoparticles were investigated by XRD, VSM, TEM, and Mossbauer spectroscopy. At 13 K, hyperfine fields of ${\gamma}-Fe_2O_3$ were 516 kOe and 490 kOe, that of $Fe_3O_4$ were 517 kOe and 482 kOe. The saturation magnetizations were 21.42 emu/g and 39.42 emu/g. The particle size of powders is 5~19 nm.

Application of Magnetic Assisted Polishing for ELID Ground Surface of Aluminum Oxide Ceramics (알루미나 세라믹스 ELID연삭면의 자기연마 가공 특성)

  • Lee, Yong-Chul;Jung, Myung-Won;Kim, Tae-Kyu;Kwak, Tae-Soo
    • Journal of the Korean Society for Precision Engineering
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    • v.30 no.12
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    • pp.1259-1264
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    • 2013
  • This study has focused on the application of magnetic assisted polishing for ELID ground surface of aluminum oxide ceramics. Aluminum oxide ceramics has been widely used as advanced materials for electric, optic, mechanic, chemical usage and so on. In this study, ELID grinding and magnetic assisted polishing technology was adopted for high-effective manufacturing and high quality surface of ceramic parts. The characteristic of MAP machining have been evaluated by the value of surface roughness and surface profile before and after magnetic assisted polishing. As the results of experiments, the surface roughness after magnetic assisted polishing has shown a significant improvement and the surface roughness was more improved when the feed rate of tool became slow.

Aerosol Synthesis and Growth Mechanism of Magnetic Iron Nanoparticles

  • Tolochko, O.V.;Vasilieva, E.S.;Kim, D.;Lee, D.W.;Kim, B.K.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.446-447
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    • 2006
  • Magnetic oxide-coated iron nanoparticles with the mean size ranging from 6 to 75 nm were synthesized by aerosol method using iron carbonyl as a precursor under the flowing inert gas atmosphere. Oxide shells were formed by passivation of asprepared iron particles. The influence of experimental parameters on the nanoparticles' microstructure, phase composition and growth behavior as well as magnetic properties were investigated and discussed in this study.

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Removal of iron oxide scale from feed-water in thermal power plant using superconducting magnetic separation

  • Nishijima, S.
    • Progress in Superconductivity and Cryogenics
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    • v.21 no.2
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    • pp.22-25
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    • 2019
  • The superconducting magnetic separation system has been developing to separate the iron oxide scale from the feed water of the thermal power plant. The accumulation in the boiler lowers the heat exchange rate or in the worst case damages it. For this reason, in order to prevent scale generation, controlling pH and redox potential is employed. However, these methods are not sufficient and then the chemical cleaning is performed regularly. A superconducting magnetic separation system is investigated for removing iron oxide scale in a feed water system. Water supply conditions of the thermal power plant are as follows, flow rate 400 t / h, flow speed 0.2 m / s, pressure 2 MPa, temperature $160-200^{\circ}C$, amount of scale generation 50 - 120 t / 2 years. The main iron oxide scale is magnetite (ferromagnetic substance) and its particle size is several tens ${\mu}m$. As the first step we are considering to introduce the system to the chemical cleaning process of the thermal power plant instead of the thermal power plant itself. The current status of development will be reported.