• Title/Summary/Keyword: magnesium water

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Studies on Magnesia Production. Production of Magnesium Hydroxide from Bittern and Sea Water (마그네시아 製造에 關한 硏究 간수, 海水로 부터 水酸化마그네슘 製造)

  • Maeng, Jung-Jae;Chang, In-Soon
    • Journal of the Korean Chemical Society
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    • v.9 no.1
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    • pp.49-54
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    • 1965
  • One of the difficult and time consuming problems in the production of magnesia from sea water is a settling rate of magnesium hydroxide. In this experiments, authors attempted to accelerate its settling rate by addition of various sedimenting agents as C.M.C., Separan and Starch, and sought for optimum calcination temperature for domestic dolomite, as alkali source, mole ratio of dolomite milk to bittern. It is observed through experiments that the small amounts of sedimenting agents, C.M.C., Separan, starch, 20 mg/l, 40 mg/l, 400mg/l, respectively increase the settling rate of magnesium hydroxide by 8 times or more. The following conditions resulted in good yield of magnesium hydroxide from sea water with relatively tolerable calcium oxide contaminated for the magnesium clinker. Calcinating temperature, $1,100{\sim}1,200^{\circ}C$, mole ratio of 10% dolomite milk to magnesium salts in sea water or bittern, 1. 2 : 1.

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The Effect of Temperature on the Stable Region of Magnesium Ion in Aqueous System (수중 마그네슘이온의 안정영역 변화에 대한 온도효과)

  • Kim, Hee-Jin;Kim, Dong-Su
    • Journal of Korean Society on Water Environment
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    • v.27 no.4
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    • pp.438-444
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    • 2011
  • Magnesium is one of the abundant natural resources in the earth crust and seawater, which is directly related to various organisms activities interconnecting with water-rock system. In aqueous system, magnesium is known to predominantly exist in the form of $Mg^{2+}$ ion which is verified in its $E_h-pH$ diagram. When it is at equilibrium in aqueous system, temperature takes an essential role to complete equilibrium states. This study represents the change of the stable region of magnesium ion according to temperature, and how the consequences would affect aquatic organisms. It was revealed that there is a noticeable tendency shrinking the stable region of magnesium ion in a diagram as temperature increases, and as a result, aquatic bio-species presumably have difficulties to absorb the nutrient. Also, it was considered that the water system would be acidified by decreasing alkalinity.

EFFECT OF ADDITIONS OF POTASSIUM AND NITROGEN INTO PRESS CAKE ON MAGNESIUM UTILIZATION OF GOATS WITH RELATION TO WATER INTAKE

  • Kim, S.A.;Ohshima, M.;Kayama, R.
    • Asian-Australasian Journal of Animal Sciences
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    • v.1 no.1
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    • pp.33-41
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    • 1988
  • In a study about minerals cycling in grassland agro-ecosystem, investigation on relations among two minerals, potassium(K) and magnesium(Mg), and nitrogen(N) was performed. Four kinds of diets different in K and N levels were fed to four goats with a Latin-square method and $2{\times}2$ factorial design. As the basal diet, press cake silage prepared from Italian ryegrass was used because of its uniformity and comparatively low mineral concentrations. Supplementation of K and N were made using potassium bicarbonate and urea. In the experiment, it was clearly shown that high K concentration in the forage crops is the main reason of the low utilization of Mg in ruminant animals. However, high nitrogen intake resulted in the increase of magnesium retention, urinary potassium excretion, water intake and volume of urine and in the decreases of potassium intake minus urinary potassium excretion. The results of high nitrogen intake seemed to be produced in the following order;increase of urine, increase of water intake, increase of urinary potassium excretion, and decrease of intake minus urinary potassium excretion. The amount of potassium intake minus urinary potassium excretion had significantly close relationships with magnesium utilization and serum magnesium concentration. As a conclusion, higher nitrogen intake by ruminants seemed to be preferable for magnesium utilization through increased water intake and urinary potassium excretion, if the sufficient drinking water could be supplied to ruminants.

Durability of CFRP strengthened RC beams under wetting and drying cycles of magnesium sulfate attack

  • Rahmani, Hamid;Alipour, Soha;Mansoorkhani, Ali Alipour
    • Advances in concrete construction
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    • v.8 no.1
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    • pp.39-45
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    • 2019
  • Durability of strengthened reinforced concrete (RC) beams with CFRP sheets under wetting and drying cycles of magnesium sulfate attack is investigated in this research. Accordingly, 18 RC beams were designed and made where 10 of them were strengthened by CFRP sheets at their tension side. Magnesium sulfate attack and wetting and drying cycles with water and magnesium sulfate solution were considered as exposure conditions. Finally, flexural performance of the beams was measured before and after 5 months of exposure. Results indicated that the bending capacity of the strengthened RC beams was reduced about 10% after 5 months of immersion in the magnesium sulfate solution. Wetting and drying cycles of magnesium sulfate solution reduced the bending capacity of the strengthened RC beams about 7%. Also, flexural capacity reduction of the strengthened RC beams in water and under wetting and drying cycles of water was negligible.

Corrosion Behavior of AZ31 Magnesium Alloy during Machining (AZ31 마그네슘 합금의 절삭가공과정에서의 부식거동)

  • Kim, Jae-Hak;Kwon, Sung-Eun;Lee, Seung-Jae
    • Journal of the Korea Institute of Military Science and Technology
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    • v.15 no.3
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    • pp.315-321
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    • 2012
  • In the study, corrosion characteristics of AZ31 magnesium alloy under various environments exposed during machining(immersion in cutting oil, 5 % cutting oil aqueous solution and distilled water & contact with dissimilar metals, SPC4 and A5052-H32) were investigated. A corrosion test was performed AZ31 magnesium alloy was immersed in each electrolyte solution after contacting with each dissimilar metals, and the results were observed by an electron microscope. In immersion tests, corrosion of AZ31 magnesium alloy showed to be in the sequence of distilled water> 5 % cutting oil aqueous solution> cutting oil> air, and in the test of contact with dissimilar metals, corrosion showed to be in the sequence of SPC4> A5052-H32> AZ31. It can be concluded that to prevent corrosion during machining, AZ31 magnesium alloy must prevent contacting water and use magnesium alloy for raw material of Jig & Fixture.

Study on Water Resistance of Environmentally Friendly Magnesium Oxychloride Cement for Waste Wood Solidification

  • Zhang, Feng-Jun;Sun, Xian-Yang;Li, Xuan;Zhang, Dan;Xie, Wen- Jie;Liu, Jin;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.55 no.5
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    • pp.446-451
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    • 2018
  • In this study, different formulations of magnesium oxide and various modifiers (phosphoric acid, ferrous sulfate, pure acrylic emulsion, silicone acrylic emulsion, glass fiber, and polypropylene fiber) were used to prepare magnesium oxychloride cement composites. The compressive strength of the magnesium oxychloride cement was tested, and the softening coefficients of the composites after soaking in water were also calculated. The results showed that a magnesium oxychloride cement sample could not be coagulated when the MgO activity was 24.3%, but the coagulation effect of the magnesium oxide cement sample was excellent when the MgO activity was 69.5%. While pure acrylic emulsion, silicon-acrylic emulsion, and glass fiber showed insignificant modification effects on the magnesium oxychloride cement, ferrous sulfate heptahydrate, phosphoric acid, and polypropylene fiber could effectively improve its water resistance and compressive strength. When the phosphoric acid, ferrous sulfate heptahydrate, and polypropylene fiber contents were 0.47%, 0.73%, and 0.25%, respectively, the softening coefficient of a composite soaked in water reached 0.93 after 7 days, and the compressive strength reached 64.3 MPa.

Density and Water Absorption Ratio Property of the Magnesium Oxide Matrix According to Wood flour Addition Ratio (목분의 첨가량에 따른 산화마그네슘 경화체의 밀도 및 흡수율 특성)

  • Jung, Byeong-Yeol;Kim, Heon-Tae;Lee, Sang-Soo;Song, Ha-Young
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2014.05a
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    • pp.236-237
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    • 2014
  • Recently, it changes to the frame construction in the wall type structure for the life span improvement of the apartment house of our country. The execution of the light panel increased while the execution of the frame construction increased. Therefore, the density and absorption ratio of the magnesium oxide matrix according to the wood flour amount of addition ratio property try to be analyze for the lightweight of the surface material of the light panel. The test result, the density has been declined as the addition ratio increase of the wood flour. In the case of the water absorption ratio, water absorption ratio has been increased as addition ratio increase of wood flour. However, wood flour addition ratio 15% determined the most appropriate when considering the density and water absorption ratio.

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Determination of Water in Magnesium Metaphosphate Glasses (MgO.$P_2O_5$ 유리의 수분 측정)

  • 강은태;박용완
    • Journal of the Korean Ceramic Society
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    • v.23 no.3
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    • pp.94-98
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    • 1986
  • Infrared has been used in determination of water in magnesium metaphosphate glasses. The method consisted of measuring the weight loss and the variation in absorption coefficient at 3, 200$cm^{-1}$. The molar absorptivity of water in magnesium metaphophate glasses was found to 76.9ι$mol^{-1} cm^{-1}$ Using the value for $\varepsilon$, A and Δ$\upsilon$H of the hydroxyl band in the spectra of magnesium metaphosphate. The molar absorptivity of the hydroxyl absorption band at 3, 3130-2, $925cm^{-1}$ in the spectra of MgO.$P_2O_5$ system glasses could be computed. And a variation of molar absorptivity against the MgO/P2O5 ratio has not been shown regulation.

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Effect of Metal Ionic Crosslinking Agents on the Water Resistance and Mechancial Properties of EVA Emulsion (EVA 에멀젼의 내수성 및 기계적 특성에 미치는 금속 이온 가교제의 효과)

  • Lee, Eun-Kyoung;Choi, Sei-Young
    • Journal of Adhesion and Interface
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    • v.9 no.2
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    • pp.24-31
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    • 2008
  • In this work, calcium hydroxide and magnesium carbonate as metal ionic crosslinking agents were used to introduce ionic crosslinking points to the ethylene vinylacetate (EVA) emulsions for the enhancement of water resistance and mechanical properties of emulsion films. The properties of EVA emulsion film were investigated in crosslinking density, thermal features, surface energy, and mechanical properties, such as tensile strength, elongation at break and tear strength. With the increasing content of metal ionic crosslinking agent, the crosslinking density of the EVA emulsion film increases, resulting into the improvement of water resistance. The surface energy and mechanical properties of the EVA emulsion film, however, showed somewhat different behaviors. The highest surface energy, tensile strength, and tear strength were observed when 0.4% for calcium hydroxide and 0.5% for magnesium carbonate was added respectively, because the EVA emulsion containing carboxylic acid forms strong carboxylate-metal bond of ionically-crosslinked system. Therefore, it can be concluded that metal ionic crosslinking agents, such as magnesium carbonate and calcium hydroxide are considered to improve water resistance and mechanical properties of the EVA emulsion.

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Effects of Water on Mechanical Properties of Magnesium Metaphosphate Glass (MgO.$P_2O_5$ 유리의 기계적 성질에 미치는 수분의 영향)

  • 강은태;박용완
    • Journal of the Korean Ceramic Society
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    • v.23 no.5
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    • pp.75-80
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    • 1986
  • The mechanical properties were measured for magnesium phosphate glasses containing small amounts of water. The decrease in hardness with increasing water content was resulted from a looser chain structure caused by water. The fracture of these glasses was changed from brittle fracture to plastic deformation as a results of the increased viscous flow with increasing water contents. The extent of any viscous flow or deformation initiating from the crack tips in these glasses could be considered as quite small.

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