• Journal of the Korean institute of surface engineering
• /
• v.52 no.2
• /
• pp.96-102
• /
• 2019

Magnesium and its alloys are prone to be corroded, thus surface treatments improving corrosion resistance are always required for practical applications. As a surface treatment of magnesium alloys, plasma electrolytic oxidation (PEO), creating porous stable oxide layer by a high voltage discharge in electrolyte, enhances the corrosion resistance. However, due to superhydrophilicity of the porous oxide layer, which easily allow the penetration of corrosive media toward magnesium alloys substrate, post-treatments inhibiting the transfer of corrosive media in porous oxide layer are required. In this work, we employed a hydrophobizing method to enhance the corrosion resistance of PEO treated Mg alloy. Three types of hydrophobizing techniques were used for PEO layer. Thin Teflon coating with solvent evaporation, self-assembled monolayer (SAM) coating of octadecyltrichlorosilane (OTS) based on solution method and SAM coating of perfluorodecyltrichlorosilane (FDTS) based on vacuum method significantly enhances corrosion resistance of PEO treated Mg alloy with reducing the contact of water on the surface. In particular, the vacuum based FDTS coating on PEO layer shows the most effective hydrophobicity with the highest corrosion resistance.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2016.05a
• /
• pp.34-35
• /
• 2016

Most of the construction adhesive may contain harmful component to the human body with an organic adhesive. In addition, when the adhesive caused hydroquinone, alkyl benzophenone, etc, also it raises the skin diseases to workers. Therefore, the inorganic adhesive development is necessary. This study was a study to know adhesive strength properties that adhesive using a magnesium oxide according to the addition ratio of the retarder. It has experiments to two types of magnesium oxide and type and ratio of retarder differently.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2015.05a
• /
• pp.156-157
• /
• 2015

Recently, the trend for structure is being changed from wall construction to rhamen construction. rhgamen construction reduces floor noise and selfweight in structures. The amount of lightweight panels used in rhamen construction is also increasing. Also, Worldwide refinery industry is a large amount of sulfur is produced by develrop ment. Sulfur is resistant to freezing and thawing. Terefore, this study focuses on the density and absorption of magnesium oxide matrix that contains wood powder and pearlite to replace lightweight panel for rhamen construction. Adding pearlite 15% has the lowest density but, it has the highest absorption.

• Elastomers and Composites
• /
• v.50 no.3
• /
• pp.205-209
• /
• 2015

Magnesium oxide (MgO) reinforced polyamide-66 (PA66) composites were prepared through melt-compounding method in order to determine the possibility of using MgO particle as conductive filler in the polymer-based composite. The effects of MgO filler content on the thermal conductivity and mechanical properties for the PA66/MgO composites were investigated. The results showed that the addition of MgO filler to the PA66 matrix led to a large increase in thermal conductivity of the PA66/MgO composites. Tensile strengths of the PA66/MgO composites were slightly decreased as MgO filler loading increased. However, flexural strength and flexural modulus were improved with increasing filler loading. Notched Izod impact strengths were dramatically lowered by the addition of MgO filler.

• Proceedings of the KIEE Conference
• /
• 2006.07c
• /
• pp.1560-1561
• /
• 2006

A high rate deposition sputtering process of magnesium oxide thin film in oxide mode has been developed using a 20 kW unipolar pulsed power supply. The power supply was operated at a maximum constant voltage of 500 V and a constant current of 40 A. The pulse repetition rate and the duty were changed in the ranges of $10{\sim}50\;kHz$ and $10{\sim}60%$, respectively. The deposition rate increased with rising incident power to the target. Maximum incident power to the magnesium target was obtained by the control of frequency, duty and current. The deposition rate of a moving state was 9 nm m/min at the average power of 1.5 kW.

• Applied Science and Convergence Technology
• /
• v.26 no.2
• /
• pp.21-25
• /
• 2017

The shape of the reflection spectrum is complex and appears to overlap with several signals, because the surface state is uneven due to the natural oxide film, so that the spectrum becomes a complicated signal shape divided into regions 1 and 2 due to diffuse reflection. On the other hand, it is seen that the reflection spectrum after PEO surface treatment is overlapped with several signals. In addition, the reflectance of the energy band varies from 1.32 to 1.46 eV. Usually, the MgO-type oxide film was observed at an energy band of ~4.2 eV. The thickness of the oxide film was increased as the DC voltage was increased by the thin film thickness meter (QuaNix; 7500M) after Plasma Electrolytic Oxidation (; PEO) surface treatment. This is because the higher the DC voltage, the easier the binding of the $OH^-$ ions in the solution solution and the $Mg^+$ ions of the magnesium alloy. An important part of the bonding of ordinary ions is the energy source (plasma) which can promote bonding. However, when a certain threshold voltage or more is applied, the material is adversely affected. The oxide film of the surface may be destroyed without increasing the thickness of the oxide film, that is, whitening of the material may occur.

• Laser Solutions
• /
• v.13 no.4
• /
• pp.21-24
• /
• 2010

Plasma electrolyte oxidation (PEO) surface treatment of magnesium alloy, an optical analysis method through reflection spectra were measured. As a result, the sample is formed on the membrane form of MgO or $Mg(OH)_2$ is in the form of oxide. The wavelength energy of surface treatment of magnesium alloy sample observed 0.23eV red shift. The measured reflectance spectra observed with the three different signals. This is due to $Mg(OH)_2$ oxide layer formed on porous hole.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2000.02a
• /
• pp.122-122
• /
• 2000

Magnesium oxide is thermodynamically very stable, has a low dielectric constant and a low refractive index, and has been widely used as substrate for growing various thin film materials, particulary oxides of the perovskite structure. There has been a considerable interest in integrating the physical properties of these oxides with semiconductor materials such as GaAs and Si. In this regard, it is considered very important to be able to grow MgO buffer layers epitaxially on the semiconductors. Various oxide films can then be grown on such buffer layers eliminating the need for using MgO single crystal substrates. Vapor phase epitaxy of magnesium oxide has been accomplished on Si(001) substrates in a high vacuum chamber using the single precursor methylmagnesium tert-butoxide in the temperature range 750-80$0^{\circ}C$. For the epitaxy of the MgO films, SiC buffer layers had to be grown on Si(001). The films were characterized by reflection high energy electron diffraction (RHEED) in situ in the growth chamber, and x-ray diffraction (XRD), x-ray pole figure analysis, scanning electron microscopy (SEM), and x-ray photoelectron spectroscopy (XPS) after the growth.

• Journal of the Korean Ceramic Society
• /
• v.55 no.5
• /
• pp.446-451
• /
• 2018

In this study, different formulations of magnesium oxide and various modifiers (phosphoric acid, ferrous sulfate, pure acrylic emulsion, silicone acrylic emulsion, glass fiber, and polypropylene fiber) were used to prepare magnesium oxychloride cement composites. The compressive strength of the magnesium oxychloride cement was tested, and the softening coefficients of the composites after soaking in water were also calculated. The results showed that a magnesium oxychloride cement sample could not be coagulated when the MgO activity was 24.3%, but the coagulation effect of the magnesium oxide cement sample was excellent when the MgO activity was 69.5%. While pure acrylic emulsion, silicon-acrylic emulsion, and glass fiber showed insignificant modification effects on the magnesium oxychloride cement, ferrous sulfate heptahydrate, phosphoric acid, and polypropylene fiber could effectively improve its water resistance and compressive strength. When the phosphoric acid, ferrous sulfate heptahydrate, and polypropylene fiber contents were 0.47%, 0.73%, and 0.25%, respectively, the softening coefficient of a composite soaked in water reached 0.93 after 7 days, and the compressive strength reached 64.3 MPa.

• Journal of Environmental Science International
• /
• v.10 no.5
• /
• pp.381-386
• /
• 2001

The characteristics of precipitation separation and solvent extraction separation of magnesium from the waste bittern were studied experimentally In the result of precipitation separation, the size of magnesium hydroxide precipitated was not affected on pH, but decreased with increasing the precipitation temperature. The purity of magnesium oxide precipitated was increased with pH beyond pH 11. From the solvent extraction separation, the equilibrium extraction ratio of magnesium was increased with pH and temperature of extraction phase, the concentration of stripping phase, and with decreasing pH of stripping phase. The extractant of Aliquat 336 and Acid 810 mixture was more effective than that of DCH18C6 and $D_2EHPA$ mixture in the extraction separation of magnesium.