• Title/Summary/Keyword: magnesium ion

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Mineral extraction from by-products of brown rice using electrodialysis and production of mineral salt containing lower sodium (전기투석을 이용한 현미부산물로부터의 미네랄성분 추출 및 나트륨감량형 미네랄 소금 제조)

  • No, Nam-Doo;Park, Eun-Jung;Kim, Mi-Lim
    • Food Science and Preservation
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    • v.22 no.6
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    • pp.859-866
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    • 2015
  • The purpose of this study was to develop a supplemental healthy food that can help prevent high blood pressure-related diseases caused due to the excessive consumption of sodium in salt. This was achieved by using ion-displacement techniques to produce mineral salt with lower sodium content by using fermented brown rice by-products rich in minerals. Mineral salt containing 2019.2 mg/100 g of potassium, 678.5 mg/100 g of magnesium, 48.7 mg/100 g of calcium, and 19.5 mg/100 g of sodium was obtained by fermenting brown rice by-products to create a culture medium for the mineral salt. Mineral salt containing 1769.7 mg/100 g of potassium, 573.6 mg/100 g of magnesium, 35.3 mg/100 g of calcium, and 19.5 mg/100 g of sodium was obtained by filtering and refining the by-product extract of fermented brown rice. The results showed that when the stream velocity of the instrument used for electrolysis was 200 mL/min and the current and the concentration of the reactive liquid in the purified water chamber were higher, the effect of electrolysis was greater. Ion hot water extraction of the fermented brown rice by-products improved by up to 95% and was collected as purified water within 90 min of the reaction time. Chloride ions with pH 7.4 were produced by mixing sodium hydroxide in a purified saline water chamber with electro-analyzed water. The salt produced in this study contained low sodium, 5.7~30%, as compared to 40% sodium content of the normal salt.

Investigation of Nutrient Contents in Jujube and Its Orchard Soils under Pesticide-Free Cultivation in Boeun Region

  • Lee, Gyeong-Ja;Kang, Bo-Goo;Kim, Ki-Sik;Kim, Ik-Hwan;Han, Jong-U;Kim, Hyun-Zoo
    • Korean Journal of Soil Science and Fertilizer
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    • v.46 no.6
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    • pp.452-457
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    • 2013
  • To obtain the useful data related to optimum nutrient management technique for pesticides-free jujube cultivation, nutrient contents of jujube leaves and fruits and the selected chemical properties of jujube orchard soils were investigated at 9 different orchards with pesticides-free cultivation in Boeun, Chungbuk, Korea. Soil and jujube leaf samples were collected from the different orchards in July and October, and jujube fruit samples were taken in October, 2012. Soil available $P_2O_5$ contents in the optimum level for jujube cultivation were 11% and 33% of total samples in July and October, respectively, but 56% of total samples was higher than the optimum level in both July and October. Exchangeable K and Ca ion contents were 44% and 67% of total samples, respectively, in both July and October, whereas exchangeable Mg ion content was 100% and 56% of total samples in July and October, respectively. Nutrient contents in jujube leaves were higher than those in fresh fruits. In addition, total nitrate, potassium and magnesium contents in the jujube leaves were higher in the samples collected in July than in October.

Phosphate Removal in Wastewater by Tobermolite (Tobermolite를 이용한 폐수내 인산염제거)

  • Lim, Bongsu;Kim, Deahyun;Yi, Teawoo
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.6
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    • pp.751-759
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    • 2013
  • This study is carried out to get the basic design parameters for phospate removal facilites from wastewater by Tobermolite. The phosphate removal by the apatite formation on the surface was affected by several important factors, temperature, ions present in wastewater stream, contact time, recirculation rate, and etc. In case of the temperature, with the increase of temperature, the apatite formation was accelerated. When temperature increased from $15^{\circ}C$ to $35^{\circ}C$, removal efficiency of phosphate increased from 83 % to 93 %. An increase of calcium and fluoride ion content increase the apatite formation, however, bicarbonate and magnesium ion inhibited the crystallization of apatite. As expected, when the recirculation rate was increased from 1 Q to 3 Q, at EBCT (Empty Bed Contact Time) 60min enhanced removal efficiency was observed. The more the recirculation rate increased, the more the removal efficiency increased. According to the results of column experiment using an actual wastewater with low and high phosphate concentration (5 mg/L and 50 mg/L-P), the removal efficiency was 77 % at EBCT of 45 min, and 80 % at 60 min. It was suggested that optimum EBCT was 45 min.

Cathodoluminescence of $Mg_2$$SnO_4$:Mn,:Mn Green Phosphor under Low-Voltage Electron Excitation ($Mg_2$$SnO_4$:Mn 녹색 형광체의 저전압 음극선 발광 특성)

  • Kim, Gyeong-Nam;Jeong, Ha-Gyun;Park, Hui-Dong;Kim, Do-Jin
    • Korean Journal of Materials Research
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    • v.11 no.9
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    • pp.759-762
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    • 2001
  • Mg$_2$SnO$_4$having an inverse spinel structure was selected as a new host material of $Mn^{2+}$ activator. The luminescence of the $Mg_2$SnO$_4$:Mn phosphor prepared by the solid-state reaction were investigated under ultraviolet and low-voltage electron excitation. The Mn-doped magnesium tin oxide exhibited strong green emission with the spectrum centered at 500nm wavelength. It was explained that the green emission in $Mg_2$SnO$_4$:Mn phosphor is due to energy transfer from $^4T_1to ^6A_1\;of\; Mn^{2+}$ ion at tetrahedral site in the spinel structure. The optimum concentration of $Mn^{2+}$/ion exhibiting maximum emission intensity by the low-voltage electron excitation was 0.6mol%. ?

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Effect of Magnesium Ion on the Contractility of the Isolated Rat Uterine Smooth Muscle (마그네슘 이온이 적출한 흰쥐 자궁근의 수축성에 미치는 효과)

  • Chang, Sang-Ho;Hwang, Sang-Ik;Sung, Ho-Kyung
    • The Korean Journal of Physiology
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    • v.20 no.2
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    • pp.199-208
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    • 1986
  • The effects of $Mg^{++}$ upon the spontaneous contraction activated by 1 IU/l oxytocin were studied in the isolated rat uterine muscle. Longitudinal muscle strips u·ere prepared from the rat uteri at the estrous stage. All experiments were performed in tris-buffered Tyrode solution which was aerated with 100% $O_2$ and kept at $35^{\circ}C$. The results obtained were as follows: 1) In the uterine strips contracting spontaneously, as $Mg^{++}$ concentration increased in the Tyrode solution the amplitude of peak tension decreased in all the experimental solutions containing the various concentrations of $Ca^{++}\;(0.5{\sim}4 mM)$. And the amplitude of peak tension increased in inverse proportion to the $[Mg^{++}]/[Ca^{++}]\; ratio$. It is suggested that the tension-lowering effect of $Mg^{++}$ would be developed through decreasing intracellular ionized free calcium ion concentration by uncertain mechanism. 2) The frequency of the uterine contraction activated by oxytocin increased as the $[Mg^{++}]/[Ca^{++}]\;ratio$ ratio increased up to 1/2, but the frequency decreased above this ratio. It is speculated that $Mg^{++}$ would influence the excitability control action of $Ca^{++}$.

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Effects of Long-Term Fertilization for Cassava Production on Soil Nutrient Availability as Measured by Ion Exchange Membrane Probe and by Corn and Canola Nutrient Uptake

  • Hung T. Nguyen;Anh T. Nguyen;Lee, B.W.;J. Schoenau
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.47 no.2
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    • pp.108-115
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    • 2002
  • The effects of long-term fertilization on soil properties and nutrient availability are not well documented for cassava cultivation in Vietnam. In 1990, a field research plots were established with 12 treatments to test the effect of different rates of nitrogen (N), phosphorus (P) and potassium (K) on soil properties in Acrisols at Thai Nguyen University in Northern Vietnam. In 1999, composite soil samples (0 to 20cm depth) were collected from eight selected plots for measurements of nutrient supply rates by ion exchange membrane probes and for growing corn and canola in a growth chamber with and without added lime. Generally, long-term nitrogen (N) fertilization increased available N supply rates but decreased available potassium (K) and magnesium (Mg). Long-term phosphorus(P) applications increased canola N, calcium (Ca) and Mg uptake. Canola P uptake increased with increased P rates only when lime was added. Long-term K applications increased canola N, K, Ca, Mg uptake but only significantly increased corn N uptake. Liming significantly increased uptake of N, P, K, Ca, Mg and S for both corn and canola. However, N $H_{4-}$N, K and Mg soil supply rates were reduced when lime was added, due to competition between Ca from the added lime and other nutrients.

Removal Torque of Mg-ion Implanted Clinical Implants with Plasma Source Ion Implantation Method (마그네슘 이온주입 임플란트의 뒤틀림 제거력에 관한 연구)

  • Kim, Bo-Hyoun;Kim, Dae-Gon;Park, Chan-Jin;Cho, Lee-Ra
    • Journal of Dental Rehabilitation and Applied Science
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    • v.25 no.1
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    • pp.41-52
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    • 2009
  • The surface treatment of titanium implant could bring out the biochemical bonding between bone and implant. The purpose of this study was to evaluate the biomechanical bone response of Mg-ion implanted implants with plasma source ion implantation method. Twelve New Zealand white rabbits were included in this study. Each rabbit received one control fixture (blasted with resorbable blasting media, RBM) and three types of Mg ion implanted fixtures in tibiae. The implants were left in place for 6 weeks before the rabbits were sacrificed. Removal torque value and resonance frequency analysis (ISQ) were compared. The repeated measured analysis of variance was used with $P{\leq}0.05$ as level of statistical significance. ISQ was not different among all groups. However, the ISQ was increased after 6 weeks healing. The group had lowest ISQ value showed the greatest increment. Mg-1 implants with 9.4% retained ion dose showed significantly higher removal torque value than that of the other implants. From this results, it is concluded that the Mg-1 implants has stronger bone response than control RBM surface implant.

Characterization of CaCO3 Formation Using an Ion Selective Electrode : Effects of the Mg/Ca Ratio and Temperature (이온 선택성 전극을 이용한 탄산칼슘 형성 특성 연구 : 마그네슘-칼슘 비율과 반응 온도의 영향)

  • Misong Han;Byoung-Young Choi;Seung-Woo, Lee;Jinyoung Park;Soochun Chae;Jun-Hwan Bang;Kyungsun Song
    • Applied Chemistry for Engineering
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    • v.34 no.2
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    • pp.111-120
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    • 2023
  • The nucleation mechanism was studied using a calcium ion selective electrode (Ca ISE) to observe the formation of CaCO3, a representative mineral in the CO2 cycle, and to analyze the effect of the Mg/Ca-ratio and temperature on the formation of pre-nucleation cluster (PNC) and CaCO3. As a result of the experiment, a small amount of crystal was formed. Energy dispersive X-ray spectroscopy (EDS) was used for surface element analysis, and a field emission scanning-electron microscope (FE-SEM) was used for the morphology analysis of synthesized carbonates. These results showed that various shapes of crystalline CaCO3 (calcite, aragonite, etc.) were observed for each Mg/Ca ratio and temperature. In addition, the calibration plot obtained from Ca ISE showed information on the formation process of CaCO3. Our results showed that as magnesium ions interfered with the binding of calcium and carbonate ions and delayed the aggregation between PNCs, the nucleation and formation of CaCO3 were delayed. On the other hand, the temperature showed an opposite trend as compared to the effect of magnesium under our experimental conditions, indicating that temperature accelerated the formation of CaCO3. Furthermore, the morphology of CaCO3 clearly changed according to the Mg/Ca ratio and temperature, and it was confirmed that the two factors are very important for CaCO3 formation in that they could affect the overall process.

Synthesis of Hybrid Cation Exchange Fibers by E-Beam Preirradiation and Their Adsorption Properties for Metal Ions (E-Beam 전조사법을 이용한 복합양이온 교환섬유의 합성 및 금속이온 흡착특성)

  • Baek Ki-Wan;Nho Young-Chang;Hwang Taek-Sung
    • Polymer(Korea)
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    • v.30 no.4
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    • pp.305-310
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    • 2006
  • The hybrid cation exchange fibers using graft copolymer of styrene onto PE/PP with PET trunk polymers were synthesized by electron beam preirradiation. The degree of grafting showed 123% value at 80% concentration of styrene. And also, amount of sulfonyl group in the ion exchanger was showed 3.3 mmol/g at 70% concentration of styrene and their values were constant after 70%. The tensile strength for fibers was lower than trunk fibers, and their value of ion exchange fibers were also below than copolymer. It was $0.206kgf/mm^2$ value. The breakthrough time for Ca and Mg ions of hybrid cation exchange fibers were increased with the increase in the pH and temperature. The breakthrough of Mg was slower the mixture than single Mg solution. Adsorption rate constant for Ca, Mg ions and maximum ion exchange capacity were 0.012, 0.011 L/mg.h and 47.06, 42.83 mg/g, and also, activation energies were 2169 and 1534 J/mol, respectively.

The Effect of chemical and physical properties of Korean tales on the decomposition of Malathion in dust formulations

  • Kang, Duk-Chae;Lee, Sung-Hwan;Cho, Chai-Moo
    • Applied Biological Chemistry
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    • v.2
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    • pp.45-52
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    • 1961
  • The decomposition of malathion in dust for mulations prepared from four Korean tales as carriers during storage period has been studied. Amberlite CG-120, a cation exchange resin . which has higher cation exchange capacity than tales, was also used as a carrier in hope of finding out the effect of nagative charge upon the decomposition of malathion. Besides the original talc powders obtained directly from the mines, the hydrogen ion saturated forms were also used as carriers for comparisonal study. The saturated ions for the resin were hydrogen, sodium and magnesium. As the physical properties of the tales, colloid content, water adsorption capacity, PH, specific surface, phosphate fixing capacity and exchangeable canons were determined, and these properties were correlated with the amount of the decomposition. Following results were obtained from the experiment. 1. The malathion in the talc in dust was found to decompose around 10-15% ofthe total withina month. About 50% of the decom position that took place after a month was found to occur within a week. 2. The resin which has higher cation exchange capacity than the tales was highly effective in the decomposition of malathion compared with the tales. 3. In every case the saturation of the exchange complexes with hydrogen ion greatly accelerated the decomposition of malathion. 4. The most highly correlated physical properties with the decomposition were colloid content and specific surface of the tales. 5. The water adsorption and phosphate fixing capacities of the tales were found not to correlate with the amount of malathion decomposed. From the experimental results it was concluded that the active negative spots on the colloidal tales or the resin attract the electropositive phosphorus atom in a malathion molecule thereby inducing the decomposition easier. The presence of hydrogen ion nearby might cause a catalytic effect in the decomposition of malathion.

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