• Title/Summary/Keyword: magnesia-phosphate

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Early-Age Compressive Strength of Magnesia-Phosphate Composite with Phosphate Type (인산염 종류에 따른 마그네시아-인산염 복합체의 초기 압축강도 특성)

  • Lee, Kyung-Ho;Yang, Keun-Hyeok
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.05a
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    • pp.185-186
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    • 2016
  • Four mortar mixes tested to evaluate the early-age compressive strength of magnesia-phosphate composite with phosphate type. Monopotassium phosphate, dipotassium phosphate, ammonium dihydrogen phosphate and diammonium phosphate used as phosphate. Test results show that the compressive strength of mortar used monopotassium phosphate as phosphate was highest, while compressive strength of mortars used dipotassium phosphate and diammonium phosphate as phosphate were not developed.

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Solidification of Heavy Metal Ions using Magnesia-Phosphate (인산염 마그네시아에 의한 중금속 이온 고정화)

  • Song, Myong-Shin;Kang, Hyun-Ju;Choi, Hun;Kim, Ju-Sung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2010.05a
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    • pp.317-318
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    • 2010
  • At the latest industry develops, heavy metals or sludge contaminated surrounding farm land and rivers. In this study, wished to solve problem by saying contaminated sludge and tailing and heavy metals to do solidification using Magnesia phosphate cement. Confirmed through above experiment that magnesia is effect in solidification and stabilization of chromium and lead.

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Solidification of Heavy Metal Ions Using Magnesia-phosphate Cement (인산염 마그네시아 시멘트에 의한 중금속 이온 고정화)

  • Choi, Hun;Kang, Hyun-Ju;Song, Myung-Shin;Jung, Eui-Dam;Kim, Ju-Seng
    • Journal of the Korean Ceramic Society
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    • v.48 no.1
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    • pp.20-25
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    • 2011
  • Since 1980's, many mines have been closed and abandoned due to the exhaustion of deposits and declining prices of international mineral resources. Because of the lack of post management for these abandoned mines, Farm land and rivers were contaminated with heavy metal ions and sludge. We studied on the solidification/stabilization of heavy metal ions, chromium ions and lead ions, using magnesia-phosphate cement. Magnesia binders were used calcined-magnesia and dead-burned magnesia. Test specimens were prepared by mixing magnesia binder with chromium ions and lead ions and activators. We analyzed the hydrates by reaction between magnesiaphosphate cement and each heavy metal ions by XRD and SEM-EDAX, and analyzed the content of heavy metal ions in the eruption water from the specimens for the solidification and stabilization of heavy metal ions by ICP. The results was shown that calcined magnesia binder is effective in stabilization for chromium ions and dead-burned magnesia binder is effective in stabilization for lead ions.

Study on Phosphate Investment for High Temperature Precision Castings(II);The Effect of MgO on the characteristics of the Investment (고온정밀주조용 인산염계 매몰재에 관한연구(II);매몰재의 특성에 미치는 Mgo의 영향)

  • SunWoo, Jung-Ho;Lee, Jong-Nam
    • Journal of Korea Foundry Society
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    • v.5 no.2
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    • pp.97-108
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    • 1985
  • In order to investigate the effect of magnesia clinker on the characteristics of the investments, temperature change during setting, setting time, compressive strength and thermal expansion of the investments were measured, and x-ray analyses were also performed. The investments were prepared in accordance with variation of the content and the particle size of magnesia clinker respectively. From this experiment, the results were summarized as follows; 1. Temperature of the investments during setting rapidly increased with increase of MgO contents and decrease of the particle size of magnesia clinker. 2. Setting time decreased with increase of MgO contents and decrease of the particle size of magnesia clinker. 3. Compressive strength increased with increase of MgO contents and decrease of the particle size of magnesia clinker. 4. Thermal expansion decreased with increase of MgO contents and decrease of the particle size of magnesia clinker. From the above results, the investment which contains 8% of MgO (270-325mesh) could be recommended for phosphate investment castings.

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The application of Phosphate Magnesia Cement for Solidification of Soil (토양 고형화를 위한 인산염 마그네시아 시멘트 적용 연구)

  • Choi, Hun;Choi, Jun-Ok;Song, Myong-Shin;Moon, Chang-Yeol
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.533-536
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    • 2008
  • This study is the application of phosphate magnesia cement for solidification of soils. The object of the study is the application of the pavment of the farm roads. The new pavement method must be environmental, ecologic and durable. So, for solidification of farm road's soil, we use magnesia cement as quick setting, high strength materials. At magnesia phosphate cement, mixing ratio of mono ammonium phosphate and magnesia is 4:6 and w/b is 50 wt%, it show 14 MPa of compressive strength, and high hydration heat. Solidified soils that mixing ratios of magnesia cement and soil are 4:6 and 5:5 have very high durability for freezing and thawing.

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The Quality Properties According to the Ratio of Magnesia and Potassium Phosphate of Magnesia Composites for Living Concrete Panel (리빙 콘크리트 패널용 마그네시아 복합체의 마그네시아 및 인산칼륨 비율에 따른 기초 품질 특성)

  • Choi, Yun-Wang;Nam, Eun-Joon;Kim, Cheol-Gyu;Yang, Neung-Won
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.4
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    • pp.617-624
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    • 2021
  • In this study, the quality properties according to the ratio of magnesia and potassium phosphate of the magnesia composite were evaluated to control the quality of the parent material in terms of materials when designing living concrete panels. The quality properties are 7 levels (30, 35, 40, 45, 50, 55 and 60%) for W/B, 4 levels for P:M (1:0.5, 1:1.0, 1:2.0 and 1:3.0 vol. %) was prepared and evaluated. As a result of evaluating the flow of the magnesia complex, as W/B increased, the flow showed a tendency to increase, and the flow showed a tendency to decrease as the P:M increased. As a result of the evaluation of the compressive strength of the magnesia composite, the strength showed a tendency to decrease as P:M increased. In addition, it was confirmed that an optimal P:M ratio exists.

A Study on the Solidification of Heavy Metal Ion by Phosphate Magnesia Cement (인산염 마그네시아 시멘트에 의한 중금속 이온 고정화에 관한 연구)

  • Choi, Hun;Choi, Jung-Ok;Kang, Hyun-Ju;Song, Myong-Shin
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.321-322
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    • 2009
  • when the polluted soil with heavy metal ions was solidified using magnesia-phosphate cement, heavy metal ions were rarely eluted. Furthermore, the results cf SEM-EDS analysis showed that heavy metal ions in polluted soil turns into insoluble solid solution by magnesia-phosphate cement, it come to have the effect to stabilize heavy metals.

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Effect of Phosphate Types on the Strength and pH of Magnesia-Phosphate Composites (마그네시아 인산염 복합체의 강도 및 pH에 대한 인산염 종류의 영향)

  • Lee, Kyung-Ho;Yang, Keun-Hyeok
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.2
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    • pp.135-140
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    • 2017
  • As an elementary investigation to develop vegetation concrete with a relatively low pH value, magnesia-phosphate composites (MPC) were examined according to the phosphate types including Monoammonium, Monosodium, Monopotassium, Monocalcium, Diammonium, Disodium, Dipotassium, and Diacalcium phosphates. All of the MPC binders, the ratio of magnesia to phosphate was fixed to be 7:3. MPC mortars activated with Disodium, Dipotassium, and Diacalcium phosphates showed no compressive strength gain, even at age of 28 days. Meanwhile, MPC mortars with Monoammonium and Monosodium phosphates developed 28-day compressive strength of more than 34MPa, and showed a relatively low pH value below 9.8. Hence, Monoammonium and Monosodium phosphates have potentials as an activator for producing MPC-based vegetation concrete.

characteristics of Magnesia Dam Block for Tundish Vessel in Steel Making Process (턴디쉬용 마그네시아질 댐블록의 제조와 그특성)

  • 정두화;김상모;이석근
    • Journal of the Korean Ceramic Society
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    • v.36 no.8
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    • pp.876-885
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    • 1999
  • In order to develop high performance basic dam block for tundish vessel in steel-making binders and additives on hydration and thermal characteristics of magnesiz castable refractories were studied. Crack initiation and propagation in cement bonded magnesia castables due to slaking of magnesia clinker at drying process were suppressed by using spinel clinker instead of magnesia powder. In case of Na2O$.$2CaO$.$P2O5(NC2P) bonded castable crack initiation due to slaking of magnesia clinker did not occur but bending strength at high temperature was low. Mechanical properties of NC2P bonded castable refractories at high temperature were improved by using magnesia clinker that contains low SiO2 contents.

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An Experimental Study on the Properties of Ultra Rapid Hardening Mortar Using Magnesia-Phosphate Cement (마그네시아 인산염 시멘트를 사용한 보수용 초속경 모르타르의 특성에 관한 실험적 연구)

  • Ahn, Moo-Young;Jung, Sang-Jin
    • Journal of the Korea Institute of Building Construction
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    • v.7 no.4
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    • pp.109-116
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    • 2007
  • Building structures are generally large in size and have a long life, and the construction of such structures requires the investment of a huge amount of money and social infrastructure. Furthermore, building structures are closely related to people's life. Recently, however, the rapid development of society has been worsening air pollution, which is in turn accelerating the degradation of building structures. Thus, the safety of building structure is emerging as a critical issue. To cope with this problem, the government enacted "The Special Act on Safety Control for Infrastructure" but we need engineers' higher concern over the maintenance and reinforcement of existing structures. Recently researches are being made actively on repair mortar using ultra rapid hardening cement for recovering the performance of structures. The present study conducted an experiment on the basic physical properties of ultra rapid hardening mortar for repairing and reinforcing building structures using magnesia cement and mono-ammonium phosphate. In the experiment, we changed the water-cement ratio and carried out replacement at different ratio of MAP/MgO(%). We used retarder to have working life, and made comparative analysis through evaluating working life and fluidity and measuring strength by age.