• Title/Summary/Keyword: low temperature reduction

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Characteristics of Ag ions Photoadsorption Using Photocatalytic TiO2 Nanocrystalline Powder (광촉매용 TiO2 나노분말을 이용한 Ag이온의 흡착 특성)

  • 이종국;유해근;황규홍;서동석;강희석;배현숙;김흥회
    • Journal of the Korean Ceramic Society
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    • v.39 no.6
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    • pp.535-539
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    • 2002
  • In this study photoadsorption propreties of Ag ion in AgNO$_3$ solution by TiO$_2$nanopowder synthesized by homogeneous precipitation process at low temperature were investigated. It was found that the photocatalytic redliction in AgNO$_3$solution was occurred by TiO$_2$nanopowder even under th sun light irradiation, although the reduction of Ag ions was slow with th small adsorption of 9.32 ppm. Notably the Ag adsorption was promoted in th dark condition probably owing to the chestnut bur shape of TiO$_2$ nanopowder itself. In the application of UV the Ag ions were completely adsorbed within 120 min, showing more significant photocatalytic reaction. The measured adsorption reaction rate and adsorption equilibrium rate constants were 0.0004 g/min and 1494.20(120 $m^2$/g), respectively.

Analysis of the Long-term Trend of PM10 Using KZ Filter in Busan, Korea (KZ 필터를 이용한 부산지역 PM10의 장기 추세 분석)

  • Do, Woo-gon;Jung, Woo-Sik
    • Journal of Environmental Science International
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    • v.26 no.2
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    • pp.221-230
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    • 2017
  • To determine the effect of air pollution reduction policies, the long-term trend of air pollutants should be analyzed. Kolmogorov-Zurbenko (KZ) filter is a low-pass filter, produced through repeated iterations of a moving average to separate each variable into its temporal components. The moving average for a KZ(m, p) filter is calculated by a filter with window length m and p iterations. The output of the first pass subsequently becomes the input for the next pass. Adjusting the window length and the number of iterations makes it possible to control the filtering of different scales of motion. To break down the daily mean $PM_{10}$ into individual time components, we assume that the original time series comprises of a long-term trend, seasonal variation, and a short-term component. The short-term component is attributable to weather and short-term fluctuations in precursor emissions, while the seasonal component is a result of changes in the solar angle. The long-term trend results from changes in overall emissions, pollutant transport, climate, policy and/or economics. The long-term trend of the daily mean $PM_{10}$ decreased sharply from $59.6ug/m^3$ in 2002 to $44.6ug/m^3$ in 2015. This suggests that there was a long-term downward trend since 2005. The difference between the unadjusted and meteorologically adjusted long-term $PM_{10}$ is small. Therefore, we can conclude that $PM_{10}$ is unaffected by the meteorological variables (total insolation, daily mean temperature, daily mean relative humidity, daily mean wind speed, and daily mean local atmospheric pressure) in Busan.

A Study on the Structure Fabrication of LDD-nMOSFET using Rapid Thermal Annealing Method of PSG Film (PSG막의 급속열처리 방법을 이용한 LDD-nMOSFET의 구조 제작에 관한 연구)

  • 류장렬;홍봉식
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.31A no.12
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    • pp.80-90
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    • 1994
  • To develop VLSI of higher packing density with 0.5.mu.m gate length of less, semiconductor devices require shallow junction with higher doping concentration. the most common method to form the shallow junction is ion implantation, but in order to remove the implantation induced defect and activate the implanted impurities electrically, ion-implanted Si should be annealed at high temperature. In this annealing, impurities are diffused out and redistributed, creating deep PN junction. These make it more difficult to form the shallow junction. Accordingly, to miimize impurity redistribution, the thermal-budget should be kept minimum, that is. RTA needs to be used. This paper reports results of the diffusion characteristics of PSG film by varying Phosphorus weitht %/ Times and temperatures of RTA. From the SIMS.ASR.4-point probe analysis, it was found that low sheet resistance below 100 .OMEGA./ㅁand shallow junction depths below 0.2.mu.m can be obtained and the surface concentrations are measured by SIMS analysis was shown to range from 2.5*10$^{17}$ aroms/cm$^{3}$~3*10$^{20}$ aroms/cm$^{3}$. By depending on the RTA process of PSG film on Si, LDD-structured nMOSFET was fabricated. The junction depths andthe concentration of n-region were about 0.06.mu.m. 2.5*10$^{17}$ atom/cm$^{-3}$ , 4*10$^{17}$ atoms/cm$^{-3}$ and 8*10$^{17}$ atoms/cm$^{3}$, respectively. As for the electrical characteristics of nMOS with phosphorus junction for n- region formed by RTA, it was found that the characteristics of device were improved. It was shown that the results were mainly due to the reduction of electric field which decreases hot carriers.

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Effects of Dietary Lycopene Supplementation on Antioxidtion in Broiler and Layer (Lycopene의 사료 내 첨가가 육계와 산란계의 항산화에 미치는 영향)

  • Ju, Won-Don;An, Byeong-Gi;Gang, Chang-Won
    • Proceedings of the Korea Society of Poultry Science Conference
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    • 2005.11a
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    • pp.17-30
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    • 2005
  • Lycopene is the red-coloured carotenoid predominantly found in tomato fruit and one of the major carotenoids in the diets of North American and Europeans. Interest in lycopene is growing rapidly following the recent publication of its effects as a natural antioxidant and prevention of cardiovascular disease and cancers. Lycopene, a polyene hydrocarbon carotenoid haying 13 double bond, of which 11 are conjugated double bonds in a linear array exhibits a strong antioxidant property almost twice as strong as that of ${\beta}$-carotene. Lycopene has been shown in recent epidemiological and experimental studies to protect against oxidative damage of DNA which plays an important part in development of various cancer. Lycopene also contribute towards reducing the risk of cardiovascular diseases by preventing oxidation of low-density lipoprotein(LDL) cholesterol. This review summarize our knowledge and the current understanding of lycopene in human health as well as the results of experiments we conducted. We conducted experiments for investigating the effects of antioxidant in broiler and the possibilities of production of high quality eggs containing lycopene by the dietary lycopene supplementation with synthetic lycopene or tomato paste. The results shows that thiobarbituric acid reaction substances(TBARS) values in process of LDL oxidation in blood serum of broiler were significantly decreased by dietary lycopene and tomato paste. The dietary lycopene supplementation resulted in improved egg yolk color and in decreased the malondialdehyde (MDA) of egg yolk after 4 wk of storage at room temperature significantly(P<0.05). The dietary tomato paste was more effective in the MDA reduction compared to the lycopene(P<0.05). The contents of lycopene in egg yolk of the lycopene supplementation groups were significantly higher than those of the control group.

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Influence of porosity and cement grade on concrete mechanical properties

  • Huang, Jiandong;Alyousef, Rayed;Suhatril, Meldi;Baharom, Shahrizan;Alabduljabbar, Hisham;Alaskar, Abdulaziz;Assilzadeh, Hamid
    • Advances in concrete construction
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    • v.10 no.5
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    • pp.393-402
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    • 2020
  • The given research focuses on examining the effect of relatively humidity (RH) and curing temperature on the hydrates as well as the porosity of calcium sulfoaluminate (CSA) cement pastes. Numerous tests, which consist of mercury intrusion porosimetry (MIP), thermosgravi metric (TG) and X-ray diffraction (XRD) were conducted. Various characterization techniques which include, scanning electron microscopy, Fourier transform microscopy along with X-ray diffraction evaluations were conducted on the samples to examine phase formation and crystallinity, morphology and microstructure along with bond formations and functional groups, respectively. During long-term study, the performance of concrete which consisted of limestone and flash-calcined was close to those from standard Portland cement concrete. Traditional classifications and methods of corrosion were widely used for the assessment of steel in concrete which may get employed to concrete which contains LC3 to recalibrate the range of polarization resistance for passitivity condition. For example, there is up to 79.5% and 146% respective flexural and compressive strengths. Moreover, they developed more advance electrical and thermo-mechanical performance with a substantial reduction in absorption of water of close to 400%. These advantages allow this research crucial to evaluate how these methods can be applied. Additionally, the research evaluates developed and more advanced cement preservation and repair techniques. The conclusion suggests concerted efforts by various stakeholders such as policy makers to enable low-carbon rates.

Low Temperature Co-firing of Camber-free Ceramic-metal Based LED Array Package (세라믹-금속 기반 LED 어레이 패키지의 저온동시소성시 휨발생 억제 연구)

  • Heo, Yu Jin;Kim, Hyo Tae
    • Journal of the Microelectronics and Packaging Society
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    • v.23 no.4
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    • pp.35-41
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    • 2016
  • Ceramic-metal based high power LED array package was developed via thick film LTCC technology using a glass-ceramic insulation layer and a silver conductor patterns directly printed on the aluminum heat sink substrate. The thermal resistance measurement using thermal transient tester revealed that ceramic-metal base LED package exhibited a superior heat dissipation property to compare with the previously known packaging method such as FR-4 based MCPCB. A prototype LED package sub-module with 50 watts power rating was fabricated using a ceramic-metal base chip-on-a board technology with minimized camber deformation during heat treatment by using partially covered glass-ceramic insulation layer design onto the aluminum heat spread substrate. This modified circuit design resulted in a camber-free packaging substrate and an enhanced heat transfer property compared with conventional MCPCB package. In addition, the partially covered design provided a material cost reduction compared with the fully covered one.

Dyeing Properties of Acetate/Functional Polyester Composite Yarn in Different Yarn Twisting Processes (연사방법에 따른 아세테이트/기능성 폴리에스터 복합사의 염색성에 관한 연구)

  • Kim, So-Jin;Jeon, Dong-Won;Park, Young-Hwan
    • Journal of the Korean Society of Clothing and Textiles
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    • v.30 no.2 s.150
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    • pp.255-265
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    • 2006
  • The purpose of this study was to examine the dyeing properties of four kinds of composite yams that were twisted in different processes. The composite yarns consist of acetate and functional polyester in ratio of 70 : 30. The composite yams were dyed at 100$^{circ}C$ and 125$^{circ}C$ using three types of dyes, disperse dyes for acetate fiber, PET fiber and PET-acetate blended fiber, in the three primary colors. The exhaustion($\%$) and K/S value were observed for each case. Also the effects of four different twisting processes to dyeing properties and physical properties were examined. Regardless of twisting methods, the composite yarns that were dyed at 125$^{circ}C$ had higher exhaustion($\%$) than those were dyed at 100$^{circ}C$ with all three types of dyes; However, tendency of the K/S value after reduction cleaning process was measured at 100$^{circ}C$ and the value measured 125$^{circ}C$ had a great difference with disperse dyes for acetate and dyes for PET. The difference of the K/S values of composite yarns, when dyed at 100$^{circ}C$ and 125$^{circ}C$ with disperse dyes for PET-acetate blended fiber, was almost negligible. According to twisting methods K/S values were in the following order: AP1 > AP3 > AP4> AP2. This means that AP1, treated at 220$^{circ}C$, had the highest K/S value and K/S value becomes higher as the yam is higher twisted and becomes lower as lower twisted. On the other hand, the dry shrinkage and wet shrinkage showed low shrinkage rate when the twist was high and steam setting temperature was high.

Dyeing of Treditional Fabrics with Natural Dyeing (전통직물의 천연염료 염색에 관한 연구)

  • Chung, In-Mo;Lee, Yong-Woo;Woo, Soon-Ok
    • Journal of Sericultural and Entomological Science
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    • v.41 no.1
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    • pp.61-69
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    • 1999
  • The dyeing experiments were done by using tannin pigments and herbs for natural fabrics such as ramie, hemp and silk. The anti-bacterial ability and color fastness were examined for dyed fabrics. Dye materials containing tannin pigment such as oak tree leaf showed rich dyeing on ramie, hemp, and silk fabrics when the pH of dye solution is lower as well as the dyeing temperature is higher. In crimson dyeing, the colour of fabric showed red-purple when the crimson pigment was extracted at 40$^{\circ}C$, while yellow-red when extracted above 70$^{\circ}C$. The colour fastness of dye materials containing tannin pigment was excellent showing 3~4 grade or above, while most of those derived from chinese medicine showed poor colour fastness of below 3 grade. The anti-bacterial ability of dye materials derived from chinese medicine was high, since the sappan wood fabric showed low bacteria reduction rate.

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Effect of Metal-Induced Lateral Crystallization Boundary Located in the TFT Channel Region on the Leakage Current (박막트랜지스터의 채널 내에 형성된 금속 유도 측면 결정화의 경계가 누설전류에 미치는 영향)

  • Kim, Tae-Gyeong;Kim, Gi-Beom;Yun, Yeo-Geon;Kim, Chang-Hun;Lee, Byeong-Il;Ju, Seung-Gi
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.37 no.4
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    • pp.31-37
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    • 2000
  • In the case of metal-induced lateral crystallization (MILC) for low temperature poly-Si TFT, offset length between Ni-thin film and the sides of gate could be modified to control the location of MILC boundary. Electrical characteristics were compared to analyze the effect of MILC boundary that was located either in or out of the channel region of the TFT. By removing the MILC boundary from channel region, on current, subthreshold slope and leakage current properties could be improved. When MILC boundary was located in the channel region, leakage current was reduced with electrical stress biasing. The amount of reduction increased as the channel width increased, but it was independent of the channel length.

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Growth Dynamics of Zostera marina Transplants in the Nakdong Estuary Related to Environmental Changes (낙동강 하구에 이식된 잘피(Zostera marina)의 환경변화에 따른 성장특성)

  • Park, Jung-Im;Lee, Kun-Seop;Son, Min-Ho
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.44 no.5
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    • pp.533-542
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    • 2011
  • Numerous seagrass habitat restoration projects have been attempted recently due to the remarkable decline in seagrass coverage. Seagrass transplants tend to adapt to a new environment after experiencing transplanting stress during the early stages of transplantation. Once acclimated, the transplants grow into healthy seagrass beds via vegetative propagation. The establishment and growth dynamics of transplanted seagrasses in bays and coasts are widely reported, but few studies have been conducted on estuaries in Korea. We transplanted Zostera marina in November 2007 and November 2008 in the Nakdong estuary using the staple method, and monitored the survival, adaptation, and growth dynamics of the transplants as well as environmental factors every month for 1 year. Both transplants adapted well to the new environment without initial losses and showed rapid productivity during early summer. However, density of transplants increased 320% in 1 year from the previous year's transplants but that decreased to 59% during the following year. This significant reduction in density in the second year may have been caused by exposure to low salinity (10 psu) for 3 weeks during the unusually long monsoon season. While the survival and growth dynamics of seagrass transplants planted in bays and coasts are mainly controlled by underwater photon flux density and water temperature, salinity was the critical factor for those planted in Nakdong estuary.