• 제목/요약/키워드: low oxygen pressure

검색결과 433건 처리시간 0.032초

PLD에 의해 제조된 PZT 박막의 미세구조가 강유전 특성에 미치는 영향 (Effects of microstructures on ferroelectric properties of PZT thin films prepared by PLD)

  • 백동수;김민철;신현용;박용웅;윤석진
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 추계학술대회 논문집
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    • pp.224-227
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    • 1999
  • Ferroelectric Pb(Zr$\sub$0.52/Ti$\sub$0.48/)O$_3$ thin films were fabricated by pulsed laser deposition, mainly varying process conditions such as substrate temperature, oxygen pressure, and laser energy, PZT films annealed at more than 600$^{\circ}C$ were crystallized into pure perovskite phases regardless of deposition temperatures. Lower deposition temperature of 400$^{\circ}C$ accompanied with post-annealing at 650$^{\circ}C$ resulted in denser microstructures with extremely small grains compated to those of thin films annealed at higher deposition temperatures. Hysteresis curves of thin film with small grains exhibitied good squareness and low leakage characteristics.

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Preparation of gas-atomized Fe-based alloy powders and HVOF sprayed coatings

  • Chau, Joseph Lik Hang;Pan, Alfred I-Tsung;Yang, Chih-Chao
    • Advances in materials Research
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    • 제6권4호
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    • pp.343-348
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    • 2017
  • High-pressure gas atomization was employed to prepare the Fe-based $Fe_{50}Cr_{24}Mo_{21}Si_2B_3$ alloy powder. The effect of flow rate of atomizing gas on the median powder diameter was studied. The results show that the powder size decreased with increasing the flow rate of atomizing gas. Fe-based alloy coatings with amorphous phase fraction was then prepared by high velocity oxygen fuel spraying (HVOF) of gas atomized $Fe_{50}Cr_{24}Mo_{21}Si_2B_3$ powder. Microstructural studies show that the coatings present dense layered structure and low porosity of 0.17% in about $200{\mu}m$ thickness. The Fe-based alloy coating exhibits an average hardness of about 1230 HV. Our results show that the HVOF process results in dense and well-bonded coatings, making it attractive for protective coatings applications.

새로운 대기압 플라즈마 소스를 이용한 결정질 실리콘 태양전지 인산 도핑 가능성에 관한 연구 (A Study on Feasibility of the Phosphoric Acid Doping for Solar Cell Using Newly Atmospheric Pressure Plasma Source)

  • 조이현;윤명수;조태훈;권기청
    • 조명전기설비학회논문지
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    • 제27권6호
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    • pp.95-99
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    • 2013
  • Furnace is currently the most important doping process using POCl3 in solar cell. However furnace need an expensive equipment cost and it has to purge a poisonous gas. Moreover, furnace typically difficult appling for selective emitters. In this study, we developed a new atmospheric pressure plasma source, in this procedure, we research the atmospheric pressure plasma doping that dopant is phosphoric acid($H_3PO_4$). Metal tube injected Ar gas was inputted 5 kV of a low frequency(scores of kHz) induced inverter, so plasma discharged at metal tube. We used the P type silicon wafer of solar cell. We regulated phosphoric acid($H_3PO_4$) concentration on 10% and plasma treatment time is 90 s, 150 s, we experiment that plasma current is 70 mA. We check the doping depth that 287 nm at 90 s and 621 nm at 150 s. We analysis and measurement the doping profile by using SIMS(Secondary Ion Mass Spectroscopy). We calculate and grasp the sheet resistance using conventional sheet resistance formula, so there are 240 Ohm/sq at 90 s and 212 Ohm/sq at 150 s. We analysis oxygen and nitrogen profile of concentration compared with furnace to check the doped defect of atmosphere.

고양이에서 체표냉각에 따른 심혈관계 변동에 관한 연구 (Cardiovascular Changes of Cat in Hypothermia)

  • 안영수;고창만;이우주
    • 대한약리학회지
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    • 제19권1호
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    • pp.61-69
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    • 1983
  • Hypothermia is an essential preparatory procedure for cardiac surgery, which lows the metabolic rate and myocardial oxygen demand. However, hypothermia itself is a stress enough to change the tonus of sympathoadrenal system, especially the cardiovascular responses to the catecholamines. It is reported that the positive chronotropic and inotropic response of catecholamines is exaggerated during hypothermia because of decreased norepinephrine uptake at the junctional cleft or decreased catecholamine metabolism. On the other hand, there are evidences of diminished catecholamines responses in low temperature ana further, interconversion of adrenergic receptors is also suggested. Present investigation was planned to observe the cardiovascular changes and its responses to catecholamines during surface hypothermia in cat. Healthy mongrel cats, weighing $2{\sim}3\;kg$, anesthetized with secobarbital(30 mg/kg), were permitted to hypothermia by external cooling technic. Esophageal temperature, ECG (lead II), heart rate, left ventricular pressure with dP/dt, carotid artery pressure and left ventricular contractile force were monitored with Polygragh (Model 7, Grass), and the respiration was maintained with artificial respirator (V 5 KG, Narco). Followings are summarized results. 1) Surface cooling caused progressive decrease of body temperature and reached $l8.8{\pm}0.8^{\circ}C$ and $16.9{\pm}0.6^{\circ}C$ in 120 and 150 min respectively, after immersion into ice water, and ventricular fibrillation was developed at $20.4{\pm}0.65^{\circ}C$. 2) Heart rate, blood pressure and myocardial contractility were decreased after initial increase as the body temperature falls. 3) Systolic and diastolicdd P/dt of left ventricular pressure were decreased and that the decrement of diastolic dP/dt was more marked. 4) On ECG, ST depression, Twave inversion and prolongation of PR interval were prominent in hypothermia, and moreover, the prolongation of PR interval was marked just prior to the development of ventricular fibrillation. 5) The cardiovascular responses to catecholamines, especially to isoproterenol, were suppressed under hypothermia.

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액체로켓엔진 연소기용 단일 분사기 연소기와 축소형 연수고 수류/연소시험 결과 비교 (Comparison of Combustion Performance between Single Injector Combustor and Sub-scale Combustor)

  • 김승한;한영민;서성현;문일윤;이광진
    • 유체기계공업학회:학술대회논문집
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    • 유체기계공업학회 2006년 제4회 한국유체공학학술대회 논문집
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    • pp.451-454
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    • 2006
  • This paper describes the results of cold flow test and hot firing tests of an uni-element coaxial swirl injector and hot firing tests of a subscale combustor, as to the development effort of coaxial swirl injector for high performance liquid rocket engine combustor. A major design parameter for coaxial swirl injector is the recess number of a bi-swirl injector. The results of hot firing tests of the uni-element injector combustor and the sub-scale combustor are analyzed to investigate the effect of the recess number influencing on the combustion performance and pressure fluctuation. The test results of a cold flow test of the unielement combustor shows that it was shown that the change in recess number has significant effect on mixing characteristics and efficiency, while the effect of recess number on atomization characteristic is not The results of a series of firing tests using unielement and subscale combustor show that the recess length significantly affects the hydraulic characteristics, the combustion efficiency, and the dynamics of the liquid oxygen/kerosene bi-swirl injector. As a point of combustion performance, combustion efficiencies are 90% for unielement combustor and 95% for subscale combustor. The difference in the characteristic velocities between the unielement combustor and the subscale combustor may be caused by the difference in thermal loss to the combustor wall and the relative lengths of the combustion chamber. For a mixed type coaxial swirl combustor, the pressure drop across the injector increases as recess number becomes larger. The low frequency pressure fluctuation observed in unielement combustor can be related to the propellant mixing characteristics of the coaxial bi-swirl injector. The effect of the recess number on the pressure fluctuation inside the combustion chamber is more significant in un i-element combustor than the subscale combustor, of which the phenomena are also observed in time domain and frequency domain.

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고폐동맥압을 동반한 선천성 심기형 환자에서 술후 폐동맥압과 혼합정맥혈 산소분압의 변화에 관한 분석 (An analysis of change in pulmonary arterial pressure and mixed venous oxygen tension after correction of congenital heart disease associated with pulmonary hypertension)

  • 김기봉;김용진
    • Journal of Chest Surgery
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    • 제22권6호
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    • pp.894-900
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    • 1989
  • It has been suggested that mixed venous $O_{2}$ tension is a predicor of cardiac output especially in a critically ill patient after an open heart surgery. From April 1988 through September 1989, we monitored mixed venous $O_{2}$ tension and pulmonary arterial pressure in 48 patients with acyanotic congenital heart disease at postoperative 1 hour, 6 hour, 12 hour, 24 hour, and 48 hour respectively. They were divided into Group I, with severe pulmoary hypertension, and Group II, without severe pulmonary hypertension. In Group I, mixed venous $O_{2}$ tension and cardiac index showed significant increase with time (p<0.05), but the ratio of pulmonary-aortic systolic pressure didn't show significant change. The increase was significant only 24 hour after operation, and so this low cardiac performance in early postoperative period should be considered when postoperative management is being planned in the risky patient. In Group II, all of the three variables didn't show any significant change with time. The correlation coefficient between mixed venous $O_{2}$ tension and cardiac index was significantly different from zero in both Group I (p<0.001) and group II (p<0.05) at each imeperiod, but the ratio of pulmonary-aortic systolic pressure didn't correlated well with the other 2 variables. Our study showed that serial determination of mixed venous $O_{2}$ tension in acyanotic congenital heart disease could be used as a guide in estimating the cardiac index postoperatively.

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선박디젤기관에서 바이오디젤 폐식용유의 연소특성에 대한 실험적 연구 (Experimental Study on Combustion Characteristics of Biodiesel Waste Cooking Oil in Marine Diesel Engine)

  • 조상곤
    • Journal of Advanced Marine Engineering and Technology
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    • 제39권4호
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    • pp.381-386
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    • 2015
  • 최근에 환경오염 문제와 대체에너지 문제에 많은 관심을 가지고 있다. 디젤기관은 세계적으로 연료의 경제성 때문에 사용이 증가할 것이다. 그러므로 선박용기관의 대기오염 문제도 여러 분야에서 큰 관심사가 되고 있다. 화석연료로 부터 배출되는 유해 배기가스를 줄이기 위하여 대체연료기술이 개발되고 있다. 이러한 신재생에너지의 바이오디젤연료는 기존 디젤연료를 대체할 친환경 에너지로 각광을 받고 있으며, 일정한 비율로 디젤연료와 혼합하면 기존 디젤기관에 개조 없이 사용가능하다. 본 연구에서 바이오디젤연료가 선박디젤기관의 연소특성에 미치는 영향을 분석하기 위하여 폐식용유로부터 제조된 바이오디젤유를 엔진에 적용하여 실험을 수행하였다. 폐식용 성분에는 세탄가와 점도가 높은 성분이 있고, 탄소함유량이 적으면서 산소함유량이 잔존하고 있다. 연구 결과 연료소비율은 증가하고, 압력, 압력상승율 및 열발생율은 감소하였다.

산업용 밀폐형 니켈수소전지의 전극 제조 및 전기화학적 특성 (Electrode Fabrication and Electrochemical Characterization of a Sealed Ni-MH Battery for Industrial Use)

  • 안양임;김세환;조진훈;김호성
    • 전기화학회지
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    • 제11권4호
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    • pp.289-296
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    • 2008
  • 산업용 밀폐형 니켈수소전지에 사용되는 수산화니켈 및 수소저장합금 전극에 대해 반쪽전지 시험에 의한 전기화학적 특성을 조사하고, 대용량 밀폐형 니켈수소전지를 제작하여 전지의 충전 효율 및 내압 특성에 대해 평가하였다. 전기화학적 특성 실험은 전지의 충방전 사이클에 따른 전지 내압 상승 억제를 목표로 수산화니켈 전극 및 수소저장합금 전극에 대해 전위주사법을 이용하여 수행하였다. 전위주사법 실험 결과, 수산화니켈 전극의 프로톤 산화 환원 반응 양태, 산소발생 거동, 그리고 수소저장합금 전극의 수소화 반응 특성을 명확히 파악할 수 있었다. 또한 산소 과전압이 높은 수산화니켈 분말과 수소 활성화 특성이 우수한 수소저장합금 분말을 사용하여 제작한 130 Ah 니켈수소전지의 충전 효율은 1 C 전류로 충전 시 98% 수준이 얻어 졌으며 과충전 시 전지 내압이 4 atm 이하로 유지됨을 확인하였다. 그리고 충방전 사이클에 의한 전지 보존 용량도 약 400 사이클에서 약 95% 수준으로 그 특성이 우수함을 알 수 있었다.

질화알루미늄의 소결(I) : 상압소결 (Sintering of Aluminum Nitride (I) : Pressureless Sintering)

  • 최상욱;이희철;이전;이임창
    • 한국세라믹학회지
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    • 제28권6호
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    • pp.457-464
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    • 1991
  • Aluminum nitride (AlN) has excellent properties such as high thermal conductivity and electrical resistivity, whereas it has some disadvantages such as low sinterability and tendency to be hydrolyzed by moisture at room temperature. In the present work, the relative density, modulus of rupture and microhardness were examined for pressure-less-sintered AlN (synthetic and commercial) bodies which were prepared under the conditions of various sintering temperatures, holding times and additions of CaCO3 which showed the best effect on sinterability among the various sintering aids. As a result, the AlN bodies with 1.0 wt% CaCO3 (0.56wt% CaO) which were sintered at 1800$^{\circ}C$ for 20 min showed good densification. In this case, the relative densities were 95.9% and 95.2%, and microhardnesses were 10.3 GPa and 9.8 GPa for synthetic and commercial AlN respectively. And as the holding time at 1800$^{\circ}C$ was increased from 10 min to 60 min, the relative density was increased from 91.9% to 96.5%. It was considered that impurities of metals and oxygen promoted the densification of AlN at low temperature (1600$^{\circ}C$).

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RF 스퍼터법을 이용한 Sr2FeMoO6 박막 제조 및 전기전도 특성 (Preparation of Sr2FeMoO6 Thin Films by RF Magnetron Sputtering and Their Electrical Conduction Properties)

  • 유희욱;선호정
    • 한국전기전자재료학회논문지
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    • 제23권12호
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    • pp.966-972
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    • 2010
  • Single-phase $Sr_2FeMoO_6$ thin films were produced by RF magnetron sputtering for use as electrodes in integrated sensors and found to be good conductors at room temperature. The films were deposited from a powder-type sputtering target under various conditions, and were crystallized by annealing. Elimination of $O_2$ gas during deposition, by the use of a solely Ar sputtering gas under a working pressure as low as possible, and vacuum annealing were important to promote the $Sr_2FeMoO_6$ phase. However, oxygen exclusion from sputtering and annealing was not enough to yield single-phase $Sr_2FeMoO_6$: hydrogen annealing was also required. Film production was optimized by varying the deposition parameters and hydrogen annealing conditions. The film had good electrical conduction, with a low resistivity of $1.6{\times}10^{-2}\Omega{\cdot}cm$ at room temperature.