• 제목/요약/키워드: low oxygen pressure

검색결과 434건 처리시간 0.03초

산화제 과잉 예연소기 연소에서 관찰되는 압력섭동에 대한 연구 (Study on Pressure Fluctuations Observed in Combustion of Oxygen-Rich Preburners)

  • 서성현;강상훈;이수용
    • 한국추진공학회지
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    • 제17권2호
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    • pp.122-127
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    • 2013
  • 고성능 폐회로 액체로켓엔진 시스템에 적용되는 산화제 과잉 예연소기 내에서 발생하는 연소 압력 섭동 데이터에 대한 분석 결과를 수록하였다. 연소실험은 두 단계의 압력 값을 순차적으로 형성하였는데 상대적으로 저압 조건에서만 78 Hz의 특성 주파수를 갖는 자발적인 압력 섭동이 발생하였다. 이와 같은 연소 불안정은 bulk mode에 해당하는 것으로 판단된다. 압력 섭동의 세기는 rms 기준으로 연소실 정압 대비 13.3%에 해당하며, 설계압 구간(19.3 MPa)에서는 매우 안정적인 모습을 보였다. 이와 같은 bulk mode는 연소실 내부에서 특성 압력파의 위상차가 없이 전체 공간에서 압력이 증가와 감소를 반복하는 것으로 Helmholtz 공진기와 비슷한 특성을 보이는 것으로 판단된다.

Solid-liquid phase equilibria on the GdBa2Cu3O7-δ stability phase diagram in low oxygen pressures (1 - 100 mTorr)

  • Lee, J.W.;Lee, J.H.;Moon, S.H.;Yoo, S.I.
    • 한국초전도ㆍ저온공학회논문지
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    • 제14권4호
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    • pp.28-31
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    • 2012
  • We report the solid-liquid phase equilibria on the $GdBa_2Cu_3O_{7-{\delta}}$ (GdBCO) stability phase diagram in low oxygen pressures ($PO_2$) ranging from 1 to 100 mTorr. On the basis of the GdBCO stability phase diagram experimentally determined in low oxygen pressures, the isothermal sections of three different phase fields on log $PO_2$ vs. 1/T diagram were schematically constructed within the $Gd_2O_3-Ba_2CuO_y-Cu_2O$ ternary system, and the solid-liquid phase equilibria in each phase field were described. The invariant points on the phase boundaries include the following three reactions; a pseudobinary peritectic reaction of $GdBCO{\leftrightarrow}Gd_2O_3$ + liquid ($L_1$), a ternary peritectic reaction of $GdBCO{\leftrightarrow}Gd_2O_3+GdBa_6Cu_3O_y$ + liquid ($L_2$), and a monotectic reaction of $L_1{\leftrightarrow}GdBa_6Cu_3O_y+L_2$. A conspicuous feature of the solid-liquid phase equilibria in low $PO_2$ regime (1 - 100 mTorr) is that the GdBCO phase is decomposed into $Gd_2O_3+L_1$ or $Gd_2O_3+GdBa_6Cu_3O_y+L_2$ rather than $Gd_2BaCuO_5+L$ well-known in high $PO_2$ like air.

PLD로 저온 증착한 Ga-doped ZnO 박막의 산소 분압에 따른 영향 (Effect of Oxygen Pressure on the properties of Ga-doped ZnO Thin Films Prepared by Pulsed Laser Deposition at Low Temperature)

  • 문성준;김지홍;노지형;김재원;도강민;문병무;구상모
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2010년도 하계학술대회 논문집
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    • pp.297-297
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    • 2010
  • Transparent conductive Oxide (TCO) is an essential material in the various optoelectronic applications as a transparent electrode, such as solar cells, flat panel displays and organic light emitting diodes. Currently, Indium tin oxide (ITO) is commonly used in industry due to its low electrical resistivity, high transmittance and high adhesion to substrate. However, ITO is expensive and should be prepared at high temperature, which makes it hard to use ITO in flexible devices. In this regard, Ga-doped ZnO is expected as an ideal candidate for replacing ITO.

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Emulsion 건조방법에 의한 고온초전도체 분말제조 (Preparation of High Tc Superconductor Powders by Emulsion Drying Method)

  • 엄우식;김호기
    • 한국재료학회지
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    • 제1권2호
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    • pp.71-76
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    • 1991
  • The superconducting powders in $YBa_2Cu_3O_{7-x}$ and Bi-Pb-Sr-Ca-Cu-O system were easily prepared from water in oil type emulsion by loading each cation into the aqueous phase. In $YBa_2Cu_3O_{7-x}$ system, the superconducting orthorhombic phase was formed by calcining at $750^{\circ}C$ for 10h in $O_2$. The size of the superconducting phase powders was submicron. The density of the sintered specimen using this powders was about 95% of the theoretical density and the resistance sharply decreases at about 90K, In Bi-Pb-Sr-Ca-Cu-O system the low Tc phase($(Bi, Pb)_2Sr_2Ca_1Cu_2O_y$) was formed by calcining at $800^{\circ}C$ for 10h in a low oxygen partial pressure of 1/20 atm The shape of clacined powder is thin plate of which size is about $2\mu\textrm{m}$ and thickness is smaller than $\mu\textrm{m}$. It was observed that the high Tc phase ($(Bi, Pb)_2Sr_2Ca_2Cu_3O_y$) was formed by sintering at $850^{\circ}C$ for 30h in oxygen pressure of 1/20 atm without intermediary grinding. The above sintered sample exhibited superconductivity with a Tc(zero)=105K.

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0.5 MWth 급 케미컬루핑 연소시스템에서 대량생산 산소전달입자의 환원반응 특성에 미치는 온도, 압력, 유속 및 용량의 영향 (Effects of Temperature, Pressure, Gas Velocity, and Capacity on Reduction Characteristics of Mass Produced Particle in a 0.5 MWth Chemical Looping Combustion System)

  • 류호정;이도연;남형석;황병욱;김하나;원유섭;백점인
    • 한국수소및신에너지학회논문집
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    • 제32권1호
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    • pp.53-62
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    • 2021
  • Batch type reduction-oxidation tests were performed to check effects of temperature, pressure, gas velocity, and capacity on reduction characteristics of mass produced particle in a 0.5 MWth chemical looping combustion system. The fuel conversion and the CO2 selectivity increased as the temperature increased and as the gas velocity decreased. However the CO2 selectivity showed the maximum and decreased as the capacity increased because the CO emission increased. The results show that high temperature, low gas velocity and low inert gas concentration are preferable to ensure high reactivity of oxygen carrier in the fuel reactor.

$CaF_{2}$를 이용한 고체전해질 산소센서의 제조및 그 특성 (Fabrication of Solid Electrolyte Oxygen Sensors Using $CaF_{2}$ and their Characteristics)

  • 이재현;이덕동
    • 센서학회지
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    • 제3권2호
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    • pp.40-49
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    • 1994
  • $CaF_{2}$ 불화물 고체전해질을 모물질로하는 저온동작용($300^{\circ}C{\sim}$500^{\circ}C) 산소센서를 제조하였다. $CaF_{2}$ 산소센서는 수축률과 SEM사진의 결과를 토대로 $850^{\circ}C$-3hr 동안 열처리 하였다. 디스크형 산소 센서는 기준전극으로 Air($O_{2}:21%$)|Pt를, 전해질로는 $CaF_{2}$, 감지전극으로 Pt를 사용하였으며, 기준전극 내장형 산소센서는 기준전극으로 NiO/Ni (30:70)을 사용하였다. 디스크형 산소센서의 경우 측정온도 $400^{\circ}C$에서 산소농도($0.1 %{\sim}10%$)로 변화시 45mV 정도의 기전력 변화를 보였으며, 기준전극 내장형의 경우는 40mV의 변화를 보였다.

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산소 분압에 따라 전자빔 증착법으로 제작된 TiO2 박막의 구조적.광학적 특성 (Optical and Structural Properties of TiO2 Thin Films Prepared at Various Oxygen Pressure by Electron-Beam Evaporation)

  • 최원석;김장섭;정종민;한성홍;김의정;이충우;주종현
    • 한국광학회지
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    • 제18권2호
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    • pp.171-177
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    • 2007
  • 전자빔 증착법을 이용하여 산소 분압에 따라 $TiO_2$ 박막을 제작하고, 열처리 온도에 따른 박막의 구조적 특성과 광학적 특성을 분석 하였다. $TiO_2$ 박막들의 물리적 특성은 주입된 산소량에 의존하였다. 주입된 산소량이 증가 할수록 상전이 온도가 높아지고, 가시광선 영역에서 $TiO_2$ 박막의 투과율이 증가하였다. 그리고 주입된 산소량이 작은 경우, $700^{\circ}C$에서 $1100^{\circ}C$로 열처리 후 $TiO_2$ 박막의 흡수단 이 좀더 장파장으로 이동하였다.

표면열처리용 변성가스의 위험성에 관한 연구 (A Study on the Hazard of Converted Gas for Surface Heating Treatment)

  • 최재욱;민철웅;임우섭;이병철;김동규
    • 한국가스학회지
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    • 제9권3호
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    • pp.9-14
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    • 2005
  • 변성가스의 폭발특성을 평가하기 위하여, 산소농도 변화와 수소의 첨가에 따른 변성가스 조성을 변화시켜 폭발거동에 대한 실험을 행하였다. 이러한 실험을 행한 결과 산소농도 $21\%$에서 변성가스와 수소의 농도가 증가할수록 폭발하한계는 낮아졌으며, 산소농도 $6\%$에서 폭발한계산소농도를 구하였다. 변성가스의 최대폭발압력은 $4.61 kg_f/cm^2$의 최적값을 얻었고, 이때 최대폭발압력상승속도는 변성가스 농도 $40\%$에서 $130.75 kg_f/cm^2/s$를 구하였다. 또한 폭발에 필요한 최소점화에너지는 변성가스 농도 $50\%$에서 0.13 mJ를 구하였다.

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응력부식균열을 고려한 고리 1호기 원자로냉각재계통의 배관 파손확률 평가 (Evaluation of Piping Failure Probability of Reactor Coolant System in Kori Unit 1 Considering Stress Corrosion Cracking)

  • 박정순;최영환;박재학
    • 한국압력기기공학회 논문집
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    • 제6권1호
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    • pp.43-49
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    • 2010
  • The piping failure probability of the reactor coolant system in Kori unit 1 was evaluated considering stress corrosion cracking. The P-PIE program (Probabilistic Piping Integrity Evaluation Program) developed in this study was used in the analysis. The effect of some variables such as oxygen concentration during start up and steady state operation, and operating temperature, which are related with stress corrosion cracking, on the piping failure probabilities was investigated. The effects of leak detection capability, the size of big leak, piping loops, and reactor types on the piping failure probability were also investigated. The results show that (1) LOCA (loss of coolant accident) probability of Kori unit 1 is extremely low, (2) leak probability is sensitive to oxygen concentration during steady state operation and operating temperature, while not sensitive to the oxygen concentration during start up, and (3) the piping thickness and operating temperature play important roles in the leak probabilities of the cold leg in 4 reactor types having same inner diameter.

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저잡음화 계측회로에 의한 다음극형 용존산소센서의 산소투과특성 (Oxygen Permeability Characteristics of the Multi-Cathode Type Dissolved Oxygen Sensor Using the Low Noise Measuring Circuit)

  • 이동희;김태진;김영환;성영권
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1998년도 추계학술대회 논문집 학회본부 C
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    • pp.764-766
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    • 1998
  • An evaluation method for oxygen permeable characteristics of the membrane covering to each cathode of multiple cathode - single anode type dissolved oxygen sensor, which has high reproducibility and is capable of measuring multiple components in solutions. For this purpose, a measuring circuit for the multiple cathode type DO sensor was designed to lower the noise signal by adapting a digital LPF to readout the sensor output accurately. Digital LPF is designed by setting up the transfer function to set the cutoff frequency to 10Hz, and the transfer function is programmed by C language, and then the filtering characteristics are evaluated with the simulation and experiments. Using this LPF added measuring circuit for the multiple cathode type DO sensor, we have obtained the calibration factor for each cathode to calibrate the variation of the output signals. The calibration factor was obtained by measuring the sensor output signal followed by oxygen partial pressure, using the same oxygen permeable membrane at each cathode of the multiple cathode type DO sensor.

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