• Title/Summary/Keyword: low oxygen pressure

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Study on Pressure Fluctuations Observed in Combustion of Oxygen-Rich Preburners (산화제 과잉 예연소기 연소에서 관찰되는 압력섭동에 대한 연구)

  • Seo, Seonghyeon;Kang, Sang Hun;Lee, Soo-Yong
    • Journal of the Korean Society of Propulsion Engineers
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    • v.17 no.2
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    • pp.122-127
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    • 2013
  • The paper includes the analytic results of pressure fluctuation data from the combustion of an oxidizer-rich preburner applicable to high-performance, closed-cycle liquid rocket engine systems. The combustion experiments went through two different steps of a chamber pressure during single run. Self-excited pressure fluctuations with a frequency of 78 Hz were observed only at the relatively low chamber pressure condition. These pressure fluctuations are regarded as a bulk mode. The intensity of pressure fluctuations by a root-mean-square value is 13.3% normalized by the chamber static pressure and no pressure excitation was observed at the design pressure condition. The bulk mode has an identical phase across the inside of the chamber and reveals the similar characteristics to the Helmholtz resonator.

Solid-liquid phase equilibria on the GdBa2Cu3O7-δ stability phase diagram in low oxygen pressures (1 - 100 mTorr)

  • Lee, J.W.;Lee, J.H.;Moon, S.H.;Yoo, S.I.
    • Progress in Superconductivity and Cryogenics
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    • v.14 no.4
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    • pp.28-31
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    • 2012
  • We report the solid-liquid phase equilibria on the $GdBa_2Cu_3O_{7-{\delta}}$ (GdBCO) stability phase diagram in low oxygen pressures ($PO_2$) ranging from 1 to 100 mTorr. On the basis of the GdBCO stability phase diagram experimentally determined in low oxygen pressures, the isothermal sections of three different phase fields on log $PO_2$ vs. 1/T diagram were schematically constructed within the $Gd_2O_3-Ba_2CuO_y-Cu_2O$ ternary system, and the solid-liquid phase equilibria in each phase field were described. The invariant points on the phase boundaries include the following three reactions; a pseudobinary peritectic reaction of $GdBCO{\leftrightarrow}Gd_2O_3$ + liquid ($L_1$), a ternary peritectic reaction of $GdBCO{\leftrightarrow}Gd_2O_3+GdBa_6Cu_3O_y$ + liquid ($L_2$), and a monotectic reaction of $L_1{\leftrightarrow}GdBa_6Cu_3O_y+L_2$. A conspicuous feature of the solid-liquid phase equilibria in low $PO_2$ regime (1 - 100 mTorr) is that the GdBCO phase is decomposed into $Gd_2O_3+L_1$ or $Gd_2O_3+GdBa_6Cu_3O_y+L_2$ rather than $Gd_2BaCuO_5+L$ well-known in high $PO_2$ like air.

Effect of Oxygen Pressure on the properties of Ga-doped ZnO Thin Films Prepared by Pulsed Laser Deposition at Low Temperature (PLD로 저온 증착한 Ga-doped ZnO 박막의 산소 분압에 따른 영향)

  • Moon, Sung-Joon;Kim, Ji-Hong;Roh, Ji-Hyung;Kim, Jae-Won;Do, Kang-Min;Moon, Byung-Moo;Koo, Sang-Mo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.297-297
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    • 2010
  • Transparent conductive Oxide (TCO) is an essential material in the various optoelectronic applications as a transparent electrode, such as solar cells, flat panel displays and organic light emitting diodes. Currently, Indium tin oxide (ITO) is commonly used in industry due to its low electrical resistivity, high transmittance and high adhesion to substrate. However, ITO is expensive and should be prepared at high temperature, which makes it hard to use ITO in flexible devices. In this regard, Ga-doped ZnO is expected as an ideal candidate for replacing ITO.

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Preparation of High Tc Superconductor Powders by Emulsion Drying Method (Emulsion 건조방법에 의한 고온초전도체 분말제조)

  • Eom, Woo-Sik;Kim, Ho-Gi
    • Korean Journal of Materials Research
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    • v.1 no.2
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    • pp.71-76
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    • 1991
  • The superconducting powders in $YBa_2Cu_3O_{7-x}$ and Bi-Pb-Sr-Ca-Cu-O system were easily prepared from water in oil type emulsion by loading each cation into the aqueous phase. In $YBa_2Cu_3O_{7-x}$ system, the superconducting orthorhombic phase was formed by calcining at $750^{\circ}C$ for 10h in $O_2$. The size of the superconducting phase powders was submicron. The density of the sintered specimen using this powders was about 95% of the theoretical density and the resistance sharply decreases at about 90K, In Bi-Pb-Sr-Ca-Cu-O system the low Tc phase($(Bi, Pb)_2Sr_2Ca_1Cu_2O_y$) was formed by calcining at $800^{\circ}C$ for 10h in a low oxygen partial pressure of 1/20 atm The shape of clacined powder is thin plate of which size is about $2\mu\textrm{m}$ and thickness is smaller than $\mu\textrm{m}$. It was observed that the high Tc phase ($(Bi, Pb)_2Sr_2Ca_2Cu_3O_y$) was formed by sintering at $850^{\circ}C$ for 30h in oxygen pressure of 1/20 atm without intermediary grinding. The above sintered sample exhibited superconductivity with a Tc(zero)=105K.

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Effects of Temperature, Pressure, Gas Velocity, and Capacity on Reduction Characteristics of Mass Produced Particle in a 0.5 MWth Chemical Looping Combustion System (0.5 MWth 급 케미컬루핑 연소시스템에서 대량생산 산소전달입자의 환원반응 특성에 미치는 온도, 압력, 유속 및 용량의 영향)

  • RYU, HO-JUNG;LEE, DOYEON;NAM, HYUNGSEOK;HWANG, BYUNG WOOK;KIM, HANA;WON, YOOSEOB;BAEK, JEOM-IN
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.1
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    • pp.53-62
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    • 2021
  • Batch type reduction-oxidation tests were performed to check effects of temperature, pressure, gas velocity, and capacity on reduction characteristics of mass produced particle in a 0.5 MWth chemical looping combustion system. The fuel conversion and the CO2 selectivity increased as the temperature increased and as the gas velocity decreased. However the CO2 selectivity showed the maximum and decreased as the capacity increased because the CO emission increased. The results show that high temperature, low gas velocity and low inert gas concentration are preferable to ensure high reactivity of oxygen carrier in the fuel reactor.

Fabrication of Solid Electrolyte Oxygen Sensors Using $CaF_{2}$ and their Characteristics ($CaF_{2}$를 이용한 고체전해질 산소센서의 제조및 그 특성)

  • Lee, Jae-Hyun;Lee, Duk-Dong
    • Journal of Sensor Science and Technology
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    • v.3 no.2
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    • pp.40-49
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    • 1994
  • Potentiometric cell oxygen sensors using $CaF_{2}$ were fabricated for monitering the oxygen partial pressure in the low temperature range ($300^{\circ}C{\sim}$500^{\circ}C). The disk type oxygen sensors consist of a reference electrode: Air($O_{2}:21%$)|Pt, a solid electrolyte $CaF_{2}$, and a sensing metel Pt electrode. And the change in open circuit emf of the disk type cell was about 45mV for the oxygen concentration range, $0.1%{\sim}10%$, at the cell temperature of $400^{\circ}C$. Also, the reference electrode incorporated type sensor showed the change of 40mV for 0.1% to 10% oxygen partial pressure range.

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Optical and Structural Properties of TiO2 Thin Films Prepared at Various Oxygen Pressure by Electron-Beam Evaporation (산소 분압에 따라 전자빔 증착법으로 제작된 TiO2 박막의 구조적.광학적 특성)

  • Choi, Won-Seok;Kim, Jang-Seob;Jung, Jong-Min;Hahn, Sung-Hong;Kim, Eui-Jung;Lee, Chung-Woo;Joo, Jong-Hyun
    • Korean Journal of Optics and Photonics
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    • v.18 no.2
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    • pp.171-177
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    • 2007
  • We prepared $TiO_2$ thin films by electron-beam evaporation at various oxygen pressures, and investigated their optical and structural properties as a function of the annealing temperature. The physical properties of the $TiO_2$ thin films depend upon the injection oxygen content. With the increased injection of oxygen, the phase transformation temperature and the transmittance of $TiO_2$ thin films in the range of visible wavelength were increased. For low injection of oxygen, the absorption edges of $TiO_2$ thin films were more red-shifted when annealed at temperatures from $700^{\circ}C$ to $1100^{\circ}C$.

A Study on the Hazard of Converted Gas for Surface Heating Treatment (표면열처리용 변성가스의 위험성에 관한 연구)

  • Choi Jae-Wook;Min Wong-Chul;Lim Woo-Sub;Lee Byoung-Chul;Kim Dong-Kyu
    • Journal of the Korean Institute of Gas
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    • v.9 no.3 s.28
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    • pp.9-14
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    • 2005
  • To estimate the explosion characteristics of converted gas, the study was examined into effects of altering oxygen concentration and adding hydrogen. From the result of the experiment, as the concentration of converted gas and hydrogen were increased at $21\%$ oxygen concentration, the lower explosion limit was low. Minimum explosion oxygen concentration was $6\%$. Maximum explosion pressure of converted gas was $4.61 kg_f/cm^2$, now Maximum explosion pressure rising velocity was $130.75 kg_f/cm^2/s$ at converted gas concentration $40\%$. Also, minimum ignition energy was 0.13 mJ at converted gas concentration $50\%$.

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Evaluation of Piping Failure Probability of Reactor Coolant System in Kori Unit 1 Considering Stress Corrosion Cracking (응력부식균열을 고려한 고리 1호기 원자로냉각재계통의 배관 파손확률 평가)

  • Park, Jeong Soon;Choi, Young Hwan;Park, Jae Hak
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.6 no.1
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    • pp.43-49
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    • 2010
  • The piping failure probability of the reactor coolant system in Kori unit 1 was evaluated considering stress corrosion cracking. The P-PIE program (Probabilistic Piping Integrity Evaluation Program) developed in this study was used in the analysis. The effect of some variables such as oxygen concentration during start up and steady state operation, and operating temperature, which are related with stress corrosion cracking, on the piping failure probabilities was investigated. The effects of leak detection capability, the size of big leak, piping loops, and reactor types on the piping failure probability were also investigated. The results show that (1) LOCA (loss of coolant accident) probability of Kori unit 1 is extremely low, (2) leak probability is sensitive to oxygen concentration during steady state operation and operating temperature, while not sensitive to the oxygen concentration during start up, and (3) the piping thickness and operating temperature play important roles in the leak probabilities of the cold leg in 4 reactor types having same inner diameter.

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Oxygen Permeability Characteristics of the Multi-Cathode Type Dissolved Oxygen Sensor Using the Low Noise Measuring Circuit (저잡음화 계측회로에 의한 다음극형 용존산소센서의 산소투과특성)

  • Rhie, Dong-Hee;Kim, T.J.;Kim, Y.H.;Sung, Yung-Kwon
    • Proceedings of the KIEE Conference
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    • 1998.11c
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    • pp.764-766
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    • 1998
  • An evaluation method for oxygen permeable characteristics of the membrane covering to each cathode of multiple cathode - single anode type dissolved oxygen sensor, which has high reproducibility and is capable of measuring multiple components in solutions. For this purpose, a measuring circuit for the multiple cathode type DO sensor was designed to lower the noise signal by adapting a digital LPF to readout the sensor output accurately. Digital LPF is designed by setting up the transfer function to set the cutoff frequency to 10Hz, and the transfer function is programmed by C language, and then the filtering characteristics are evaluated with the simulation and experiments. Using this LPF added measuring circuit for the multiple cathode type DO sensor, we have obtained the calibration factor for each cathode to calibrate the variation of the output signals. The calibration factor was obtained by measuring the sensor output signal followed by oxygen partial pressure, using the same oxygen permeable membrane at each cathode of the multiple cathode type DO sensor.

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