• Macromolecular Research
• /
• v.14 no.5
• /
• pp.491-498
• /
• 2006

The thermal degradation of poly(hexamethylene guanidine) phosphate (PHMG) was studied by dynamic thermogravimetric analysis (TGA) and pyrolysis-GC/MS (p-GC). Thermal degradation of PHMG occurs in three different processes, such as dephosphorylation, sublimation/vaporization of amine compounds and decomposition/ recombination of hydrocarbon residues. The kinetic parameters of each stage were calculated from the Kissinger, Friedman and Flynn-Wall-Ozawa methods. The Chang method was also used for comparison study. To investigate the degradation mechanisms of the three different stages, the Coats-Redfern and the Phadnis-Deshpande methods were employed. The probable degradation mechanism for the first stage was a nucleation and growth mechanism, $A_n$ type. However, a power law and a diffusion mechanism, $D_n$ type, were operated for the second degradation stage, whereas a nucleation and growth mechanism, $A_n$ type, were operated again for the third degradation stage of PHMG. The theoretical weight loss against temperature curves, calculated by the estimated kinetic parameters, well fit the experimental data, thereby confirming the validity of the analysis method used in this work. The life-time predicted from the kinetic equation is a valuable guide for the thermal processing of PHMG.

• Proceedings of the Korean Society for Technology of Plasticity Conference
• /
• 2007.10a
• /
• pp.360-363
• /
• 2007

This paper deals with the dynamic tensile characteristics of the steel sheets for structural members of a train. Train accidents occurs rarely but lead to many casualties and economical loss. Therefore the safety of the train becomes important during the train crash. The dynamic tensile characteristics of the steel sheets are indispensable to analyze the structural crashworthiness. Current research reports the stress-strain curves, fracture elongation and strain rate sensitivities evaluated at the various strain rates especially for SUS304L-ST and SUS304L-LT steel sheets. The results include the difference in the dynamic tensile characteristics of both rolling and transverse directions. Dynamic tensile tests were performed at the strain rates ranging from 0.003/sec to 200/sec using High Speed Material Testing Machine. The materials tested in this research shows interesting behavior at the low strain rates. The strain hardening exponent decreases remarkably while the yield strength increases.

• Bulletin of the Korean Space Science Society
• /
• 2009.10a
• /
• pp.24.2-24.2
• /
• 2009

We present the results of new CCD photometry for the contact binary BX Peg, made during three successive months beginning on September 2008. As do historical light curves, our observations display an O'Connell effect and the November data by themselves indicate clear evidence for very short-time brightness disturbance. For these variations, model spots are applied separately to the two data set of Group I (Sep.--Oct.) and Group II (Nov.). The former is described by a single cool spot on the secondary photosphere and the latter by a two-spot model with a cool spot on the cool star and a hot one on either star. These are generalized manifestations of the magnetic activity of the binary system. Twenty light-curve timings calculated from Wilson-Devinney code were used for a period study, together with all other minimum epochs. The complex period changes of BX Peg can be sorted into a secular period decrease caused dominantly by angular momentum loss due to magnetic stellar wind braking, a light-travel-time (LTT) effect due to the gravitational effect of a low-mass third companion, and a previously unknown short-term oscillation. This last period modulation could be produced either by a second LTT orbit with a period of about 16 yr due to the existence of a fourth body or by the effect of magnetic activity with a cycle length of about 12 yr.

• Bulletin of the Korean Chemical Society
• /
• v.30 no.5
• /
• pp.1021-1025
• /
• 2009

A novel supramolecular network containing binuclear copper unit $[Cu(phen)_{2}({\mu}-ID\;A)Cu(phen){\cdot}(NO_{3})](NO_{3}){\cdot}4(H_{2}O)$ (1) was synthesized through the self-assembly of iminodiacetic acid ($H_2IDA$) and 1,10-phenanthroline (phen) in the condition of pH = 6. It has been characterized by the infrared (IR) spectroscopy, elemental analysis, single crystal X-ray diffraction, and thermogravimetric analysis (TGA). 1 shows a 2-D supramolecular structure assembled through strong and unique $\pi-\pi$ packing interactions. Density functional theory (DFT) calculations show that theoretical optimized structures can well reproduce the experimental structure. The TGA and powder X-ray diffraction (PXRD) curves indicate that the complex 1 can maintain the structural integrity even at the loss of free water molecules. The magnetic property is also reported in this paper.

• The Transactions of the Korean Institute of Electrical Engineers A
• /
• v.55 no.1
• /
• pp.37-44
• /
• 2006

In this paper we explore the susceptibility of common sensitive loads by voltage sags of power distribution systems. The experimental approach was used for obtaining the susceptibility of single-phase loads and the three-phase induction motor. The experimental result of single-phase loads was transformed to the ITIC(Information of Technology Industry Council) format and used for evaluating the adverse impacts of a individual and repetitive sags using the performance contour of the foreign standard data. In order to assess the impact of voltage sags on three-phase induction motor, also, the experiment was peformed. The experiment was focused on the current, torque, and speed loss of the motor during a voltage sag. For comparing the impacts of individual and repetitive voltage sags, the variations of motor torque is focused among the experimental results. The sensitive curves of instantaneous current peak are used to describe the susceptibility of three-phase induction motor and 진so it were used for the quantitative analysis of the impact of three-phase induction motor due to voltage sags. Through the results of experiment, we verified that some types loads have more severe impact at repetitive voltage sags than individual ones and proposed method can be effectively used to evaluate the actual impact of voltage sags.

• Journal of the Korean Chemical Society
• /
• v.55 no.2
• /
• pp.268-278
• /
• 2011

Corrosion of aluminum in 0.1 M HCl solution in the absence and presence of ${\beta}$-blocker inhibitors (atenolol, propranolol, timolol and nadolol) was investigated using weight loss, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques. The inhibition efficiency increased with inhibitor concentration and decreased with rise of temperature. Potentiodynamic polarization curves revealed that they acted as cathodic inhibitors. Some thermodynamic parameters were calculated and discussed. All inhibitors were adsorbed on Al surface obeying Frumkin isotherm. All EIS tests exhibited one capacitive loop which indicates that the corrosion reaction is controlled by charge transfer process. The inhibition efficiencies of all test methods were in good agreement.

• The Journal of the Acoustical Society of Korea
• /
• v.31 no.5
• /
• pp.273-279
• /
• 2012

In this thesis, a nonlinear compression fitting method was studied for each frequency channel of a 64 channel digital hearing aid. Unlike conventional fitting formula method done from the result of the hearing loss test, the present fitting method uses the auditory threshold of sound pressure measured near the tympanic membrane while ITE (In-The-Ear) hearing aid is fitted into the user's ear canal. Also, the spectral distribution of the voice sound pressure was used for realizing of output sound pressure compression curves against input sound pressure level. Theoretical research results of FFT-iFFT compression algorithm has been evaluated by experimental gain measurements at each different input sound pressure level 50 dB, 70 dB, 90 dB respectively.

• Korean Journal of Optics and Photonics
• /
• v.3 no.3
• /
• pp.143-147
• /
• 1992

1)iscussed in this paper are the effects of phase modulation on the line spread functions (LSF) and MTFs of ;I binocular objective system. The binocular objective lens is made in Korea. It has rotationally symmetric aberrations. The LSFs and MTFs are measured experimentally. The phase modulation is carried out by applying phase retardation $\pi$ on the aperture. The area where the phase is not retarded presents a double annular type. The OTF curves of phase modulated aperture are compared with that of unmodulated aperture. The comparison shows that there is the aberration compensation effect in aberration loaded system. Therefore the performance of many optical system can be improved without any loss of light energy by properly modulating the phase on the aperture.

• Geomechanics and Engineering
• /
• v.18 no.6
• /
• pp.661-668
• /
• 2019

Seismic vulnerability assessment is a useful tool for rational safety analysis and planning of large and complex structural systems; it can deal with the effects of uncertainties on the performance of significant structural systems. In this study, an efficient dynamic reliability approach, probability density evolution methodology (PDEM), is proposed for seismic vulnerability analysis of earth dams. The PDEM provides the failure probability of different limit states for various levels of ground motion intensity as well as the mean value, standard deviation and probability density function of the performance metric of the earth dam. Combining the seismic reliability with three different performance levels related to the displacement of the earth dam, the seismic fragility curves are constructed without them being limited to a specific functional form. Furthermore, considering the seismic fragility analysis is a significant procedure in the seismic probabilistic risk assessment of structures, the seismic vulnerability results obtained by the dynamic reliability approach are combined with the results of probabilistic seismic hazard and seismic loss analysis to present and address the PDEM-based seismic probabilistic risk assessment framework by a simulated case study of an earth dam.

• Journal of Korean Neurosurgical Society
• /
• v.65 no.1
• /
• pp.151-160
• /
• 2022

Continuous monitoring of intracranial pressure is a well established medical procedure. Still, little is known about long-term behavior of intracranial pressure in normal pressure hydrocephalus. The present study is designed to evaluate periodicity of intracranial pressure over long-time scales using intraventricular pressure monitoring in patients with normal pressure hydrocephalus. In addition, the circadian and diurnal patterns of blood pressure and body temperature in those patients are studied. Four patients, selected with "probable" normal pressure hydrocephalus, were monitored for several dozen hours. Intracranial pressure, blood pressure, and body temperature were recorded hourly. Autocorrelation functions were calculated and cross-correlation analysis were carried out to study all the time-series data. Autocorrelation results show that intracranial pressure, blood pressure, and body temperature values follow bimodal (positive and negative) curves over a day. The cross-correlation functions demonstrate causal relationships between intracranial pressure, blood pressure, and body temperature. The results show that long-term fluctuations in intracranial pressure exhibit cyclical patterns with periods of about 24 hours. Continuous intracranial pressure recording in "probable" normal pressure hydrocephalus patients reveals circadian fluctuations not related to the day and night cycle. These fluctuations are causally related to changes in blood pressure and body temperature. The present study reveals the complete loss of the diurnal blood pressure and body temperature rhythmicities in patients with "probable" normal pressure hydrocephalus.