• Title/Summary/Keyword: long range interaction

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Fluorine-Induced Local Magnetic Moment in Graphene: A hybrid DFT study

  • Kim, Hyeon-Jung;Jo, Jun-Hyeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.127.1-127.1
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    • 2013
  • Recent experimental evidence that fluorinated graphene creates local magnetic moments around F adatoms has not been supported by semilocal density-functional theory (DFT) calculations where the adsorption of an F adatom induces no magnetic moment in graphene. Here, we show that such an incorrect prediction of the nonmagnetic ground state is due to the self-interaction error inherent in semilocal exchange-correlation functionals. The present hybrid DFT calculation for an F adatom on graphene predicts not only a spin-polarized ground state with a spin moment of ${\sim}1{\mu}_B$, but also a long-range spin polarization caused by the bipartite nature of the graphene lattice as well as the induced spin polarization of the graphene states. The results provide support for the experimental observations of local magnetic moments in fluorinated graphene.

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Diffusion of Choline Chloride in Aqueous Solutions of Chondroitin Sulfate

  • Jung, Ok-Sun;Kim, Si-Joong;Kim, Hyoung-Man
    • Bulletin of the Korean Chemical Society
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    • v.5 no.6
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    • pp.249-253
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    • 1984
  • Mutual diffusion coefficients of choline chloride were determined by using the diaphragm cell method in aqueous solutions of chondroitin sulfate A at $25^{\circ}C$. The diffusion coefficients of choline chloride in 0.1g/100ml, 0.5g/100ml and 1g/100ml respectively of chondroitin sulfate solutions were compared with those of binary systems of water-choline chloride. At low concentrations, the diffusion coefficients of the choline chloride in the presence of chondroitin sulfate were significantly smaller than the values obtained in the absence of chondroitin sulfate, indicating a strong interaction between these solutes. The effect of this interaction on the diffusion of choline ion is largest at higher chondroitin sulfate concentrations and at lower choline chloride concentrations. The influence of chondroitin sulfate is overcome at higher choline chloride concentrations. Self-diffusion coefficients of choline ion in the presence of chondroitin sulfate are also obtained. Excellent agreements were obtained between the experimental data and the calculated values obtained by using the Manning's equations. These observations suggest that the interaction between choline chloride and chondroitin sulfate involves primarily a long range electrostatic effect and there is no appreciable "condensation" or binding of choline ion to the chondroitin sulfate.

The Mouse & Keyboard Control Application based on Smart Phone (스마트 폰 기반의 마우스와 키보드 제어 어플리케이션)

  • Lim, Yang Mi
    • Journal of Korea Multimedia Society
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    • v.20 no.2
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    • pp.396-403
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    • 2017
  • In recent years, the use of touch screens has expanded, and devices such as remote controllers have been developed in various ways to control and access contents at long range. The wireless-based touch screen is used in classroom, seminar room, and remote video conversation in addition to the TV remote control. The purpose of the study is to design a smart phone-based intuitive interface that can perform the role of a wireless mouse and a wireless keyboard at range using Bluetooth and to develop an application that integrates functions of a mouse and a keyboard. Firstly, touch interaction model for controlling software such as PowerPoint by connecting to a general PC on a smart phone has been studied. The most simple touch operation interface is used to reproduce the function of existing devices and design more simply. The studies of the extension of interfaces with various functions are important, but development of optimized interfaces for users will become more important in the future. In this sense, this study is valuable.

A Tsunami Simulation Model based on Cellular Automata for Analyzing Coastal Inundation: Case Study of Gwangalli Beach (지진해일로 인한 해안 침수 분석을 위한 셀 오토마타 기반의 시뮬레이션 모델 개발: 광안리 해변 사례 연구)

  • Joo, Jae Woo;Joo, Jun Mo;Kim, Dong Min;Lee, Dong Hun;Choi, Seon Han
    • Journal of Korea Multimedia Society
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    • v.23 no.5
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    • pp.710-720
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    • 2020
  • Tsunami occurred by a rapid change in the ocean floor is a natural disaster that causes serious damage worldwide. South Korea seems to be out of the range of this damage, but it is quite possible that South Korea will fall within the range due to the long-distance propagation features of tsunami and many earthquakes occurred in Japan. However, the analysis and preparation for tsunami have been still insufficient. In this paper, we propose a tsunami simulation model based on cellular automata for analyzing coastal inundation. The proposed model calculates the range of inundation in coastal areas by propagating the energy of tsunami using the interaction between neighboring cells. We define interaction rules and algorithms for the energy transfer and propose a software tool to effectively utilize the model. In addition, to verify and tune the simulation model, we used the actual tsunami data in 2010 at Dichato, Chile. As a case study, the proposed model was applied to analyze the coastal inundation according to tsunami height in Gwangali Beach, a famous site in Busan. It is expected that the simulation model can be a help to prepare an effective countermeasure against tsunami and be used for a virtual evacuating training.

Direct Interaction of KIF5s and Actin-Based Transport Motor, Myo9s (KIF5s와 직접 결합하는 액틴 결합 운동단백질 Myo9s의 규명)

  • Seog, Dae-Hyun
    • Journal of Life Science
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    • v.21 no.8
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    • pp.1076-1082
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    • 2011
  • Microtubule-based kinesin motor proteins are used for long-range vesicular transport. KIF5s (KIF5A, KIF5B and KIF5C) mediate the transport of various membranous vesicles along microtubules, but the mechanism behind how they recognize and bind to a specific cargo has not yet been completely elucidated. To identify the interaction protein for KIF5B, yeast two-hybrid screening was performed and a specific interaction with the unconventional myosin Myo9b, an actin-based vesicle transport motor, was found. The GTPase-activating protein (GAP) domain of Myo9s was essential for interaction with KIF5B in the yeast two-hybrid assay. Myo9b bound to the carboxyl-terminal region of KIF5B and to other KIF5 members. In addition, glutathione S-transferase (GST) pull-downs showed that Myo9s specifically interact to the complete Kinesin-I complex. An antibody to KIF5B specifically co-immunoprecipitated KIF5B associated with Myo9s from mouse brain extracts. These results suggest that kinesin-I motor protein interacts directly with actin-based motor proteins in the cell.

Formation of surface mediated iron colloids during U(VI) and nZVI interaction

  • Shin, Youngho;Bae, Sungjun;Lee, Woojin
    • Advances in environmental research
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    • v.2 no.3
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    • pp.167-177
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    • 2013
  • We investigated that removal of aqueous U(VI) by nano-sized Zero Valent Iron (nZVI) and Fe(II) bearing minerals (controls) in this study. Iron particles showed different U(VI) removal efficiencies (Mackinawite: 99%, green rust: 95%, nZVI: 91%, magnetite: 87%, pyrite: 59%) due to their different PZC (Point of Zero Charge) values and surface areas. In addition, noticeable amount of surface Fe(II) (181 ${\mu}M$) was released from nZVI suspension in 6 h and it increased to 384 ${\mu}M$ in the presence of U(VI) due to ion-exchange of U(VI) with Fe(II) on nZVI surface. Analysis of Laser-Induced Breakdown Detection (LIBD) showed that breakdown probabilities in both filtrates by 20 and 200 nm sizes was almost 24% in nZVI suspension with U(VI), while 1% of the probabilities were observed in nZVI suspension without U(VI). It indicated that Fe(II) colloids in the range under 20 nm were generated during the interaction of U(VI) and nZVI. Our results suggest that Fe(II) colloids generated via ion-exchange process should be carefully concerned during long-term remediation site contaminated by U(VI) because U could be transported to remote area through the adsorption on Fe(II) colloids.

Microstructure and shear modulus in concentrated dispersions of bidisperse charged spherical colloids

  • Chun, Myung-Suk;Lee, Sangwoo;Lee, Tae-Seok;Cho, Jae-Seol
    • Korea-Australia Rheology Journal
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    • v.16 no.1
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    • pp.17-26
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    • 2004
  • We examine rigorous computations on microstructural as well as rheological properties of concentrated dispersions of bidisperse colloids. The NVT Monte Carlo simulation is applied to obtain the radial distribution function for the concentrated system. The long-range electrostatic interactions between dissimilar spherical colloids are determined using the singularity method, which provides explicit solutions to the linearized electrostatic field. The increasing trend of osmotic pressure with increasing total particle concentration is reduced as the concentration ratio between large and small particles is increased. From the estimation of total structure factor, we observe the strong correlations developed between dissimilar spheres. As the particle concentration increases at a given ionic strength, the magnitude of the first peak in structure factors increases and also moves to higher wave number values. The increase of electrostatic interaction between same charged particles caused by the Debye screening effect provides an increase in both the osmotic pressure and the shear modulus. The higher volume fraction ratio providing larger interparticle spacing yields decreasing high frequency limit of the shear modulus, due to decreasing the particle interaction energy.

INTERACTIONS WITH EDDIES IN THE UPSTREAM OF THE KUROSHIO AS SEEN BY THE HF RADAR AND ALTIMETRY DATA

  • Ichikawa, Kaoru;Tokeshi, Ryoko
    • Proceedings of the KSRS Conference
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    • v.2
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    • pp.969-972
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    • 2006
  • The long-range High-Frequency (HF) ocean radar system has observed surface velocity field in the upstream of the Kuroshio north of Ishigaki Island and east of Taiwan since 2001. Applying a new method to extract geostrophic velocity component from the HF surface velocity data with the aid of satellite-born wind data, time series of daily surface geostrophic velocity field has been determined. Despite limited width of the study area of the HF radar, analysis of the sea surface height anomaly determined from the satellite altimetry data in a wider area can provide estimated dates of arrival of mesoscale eddies in the study area of the HF radar. Variations of the Kuroshio position and strength are studied in detail for these cases of interaction with mesoscale eddy, although number of occurrence of direct interaction with the Kuroshio in the study area is not statistically enough. For example, when an anticyclonic eddy approaches to the Kuroshio, the Kuroshio axis is found tend to move northward, keeping away from the approaching eddy from the east.

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SWR as Tool for Determination of the Surface Magnetic Anisotropy Energy Constant

  • Maksymowicz, L.J.;Lubecka, M.;Jablonski, R.
    • Journal of Magnetics
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    • v.3 no.4
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    • pp.105-111
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    • 1998
  • The low energy excitations of spin waves (SWR) in thin films can be used for determination of the surface anisotropy constant and the nonhomogeneities of magnetization in the close-to-surface layer. The dispersion relation in SWR is sensitive on the geometry of experiment. We report on temperature dependence of surface magnetic anisotropy energy constant in magnetic semiconductor thin films of$ CdCr_{2-2x}In_{2x}Se_4$ at spin glass state. Samples were deposited by rf sputtering technique on Corning glass substrate in controlled temperature conditions. Coexistence of the infinite ferromagnetic network (IFN) and finite spin slusters (FSC) in spin glass state (SG) is know phenomena. Some behavior typical for long range magnetic ordering is expected in samples at SG state. The spin wave resonance experiment (microwave spectrometer at X-band) with excited surface modes was applied to describe the energy state of surface spins. We determined the surface magnetic anisotropy energy constant versus temperature using the surface inhomogeneities model of magnetic thin films. It was found that two components contribute to the surface magnetic anisotropy energy. One originates from the exchange interaction term due to the lack of translation symmetry for surface spin as well as from the originates from the exchange interaction term due to the lack of translation symmetry for surface spin as well as from the stray field of the surface roughness. The second one comes from the demagnetizing field of close-to surface layer with grad M. Both term linearly decrease when temperature is increased from 5 to 123 K, but dominant contribution is from the first component.

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Effects of Passive Upper Arm Exercise on Range of Motion, Muscle Strength, and Muscle Spasticity in Hemiplegic Patients with Cerebral Vascular Disease (입원초기에 적용된 상지수동운동이 뇌혈관질환자의 환측 관절가동범위, 근력 및 상지 경직에 미치는 효과)

  • Shin, Dong Soon;Song, Rhayun;Shin, Eun Kyung;Seo, Sung Ju;Park, Jeong Eun;Han, Seung Yeon;Jung, Hoi Yong;Ryu, Choon Ji
    • Journal of Korean Academy of Nursing
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    • v.42 no.6
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    • pp.783-790
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    • 2012
  • Purpose: The purpose of this study was to investigate the effects of passive upper arm exercise on range of motion, muscle strength, and muscle spasticity in hemiplegic patients with cerebral vascular disease. Methods: A quasi-experimental design with nonequivalent control group was utilized. According to inclusion criteria, 25 patients were assigned to the control group with routine care, followed by 25 to the intervention group with passive exercise for 30 minutes per session, twice a day for 2 weeks. Eighteen patients in the intervention group and 17 in the control group completed the posttest measurement, including range of motion for upper arm joints, manual muscle test, and Modified Ashworth Scale for muscle spasticity. Results: The intervention group had a significantly improved range of motion in the shoulder and wrist joints. No interaction effect was found for the elbow joint. No significant differences were found in muscle strength or muscle spasticity between the groups. Conclusion: Results of the study indicate that passive exercise safely applied for two weeks improves range of motion in joints of the upper arm in these patients. Further study with long-term follow-up is needed to verify the role of passive exercise in preventing muscle spasticity in this population.