• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1999.11a
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• pp.395-397
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• 1999

There are many efforts to improve electrolytes to satisfy the requirements of a lithium rechargeable battery. We have investigated a binary solvent mixture containing the electrolyte lithium salt($LiBF_4$, $LiPF_6$), that is conductive and electrochemically stable. Ionic conductivities were measured between -5 and $80^{\circ}C$, and cyclic voltammetry between 2.5 and 4.3 V were measured by SUS or platinum electrode.

• Journal of Power Electronics
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• v.10 no.2
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• pp.210-217
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• 2010

This paper introduces a lithium ion battery management system (BMS) for the STSAT-3 satellite. The specifications of a lithium ion battery unit are proposed to supply power to the satellite and the overall electrical and mechanical designs for a lithium ion battery management system are presented. The structural simulation results will be shown to confirm the behavior of both the BMS and the cells.

• Journal of Power Electronics
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• v.13 no.3
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• pp.497-506
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• 2013

This paper proposes a new method to improve the available battery capacity in electric vehicles by connecting lead-acid batteries with lithium-ion battery in parallel to supply power. In addition, this method combines the discharge characteristics of batteries to improve their efficiency and lower their cost for electric vehicles. A lithium-ion battery set is used to connect with N sets of lead-acid batteries in parallel. The lead-acid battery supplies the initial power. When the lead-acid battery is discharged by the load current until its output voltage drops to the cut-off voltage, the power management unit controls the lead-acid battery and changes it to discharge continuously with a small current. This discharge can be achieved by connecting the lead-acid battery to a lithium-ion battery in parallel to supply the load power or to discharge its current to another lead-acid or lithium-ion battery. Experimental results demonstrates that the available capacity can be improved by up to 30% of the rated capacity of the lead-acid batteries.

• Bulletin of the Korean Chemical Society
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• v.4 no.1
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• pp.14-17
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• 1983

The effects of trialkylborane on the stereochemistry of ketone reduction with lithium borohydride were studied for the four representative ketones, namely 4-t-butylcyclohexanone, 2-methylcyclohexanone, norcamphor, and camphor. The presence of trialkylborane increased the yields of the less stable alcohols. For example, in the presence of tri-s-butylborane, 42 % yield of cis-4-t-butylcyclohexanol was observed whereas only 8 % yield with lithium borohydride alone in the reduction of 4-t-butylcyclohexanone. The in situ formation of lithium trialkylborohydride, by the hydride transfer from lithium trialkoxyborohydride to trialkylborane, was demonstrated as a possible mechanism for the catalytic effect of trialkylborane.

• Journal of Industrial and Engineering Chemistry
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• v.68
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• pp.140-145
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• 2018

Bulky carbon layer uniformly distributed with nanoscale $Fe_2O_3$ was prepared via a direct carbonation of $Fe^{3+}$-polyacrylonitrile complexes at $700^{\circ}C$ under $N_2$ flow. The iron oxide carbon composites exhibited an excellent cycling performance for lithium storage with a reversible capacity of ${\sim}810mAh\;g^{-1}$ after 250 cycles at a current rate of $100mA\;g^{-1}$. The enhancement was mainly attributed to dual functions of bulky carbon layer which facilitated the lithium-ion diffusion and accommodated the volume changes of active $Fe_2O_3$ during charge/discharge process. Our novel chemical strategy is quite effective for scalable fabrication of high capacity lithium-storage materials.

• Bulletin of the Korean Chemical Society
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• v.12 no.6
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• pp.644-649
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• 1991

The approximate rates and stoichiometry of the reaction of excess lithium tris(dibutylamino)aluminum hydride (LT-DBA) with selected organic compounds containing representative functional groups under standardized conditions (tetrahydrofuran, $0^{\circ}C$) were studied in order to characterize the reducing characteristics of the reagent for selective reductions. The reducing ability of LTDBA was also compared with those of the parent lithium aluminum hydride and the alkoxy derivatives. The reagent appears to be much milder than the parent reagent, but stronger than lithium tri-t-butoxyaluminohydride in reducing strength. LTDBA shows a unique reducing characteristics. Thus, the reagent reduces aldehydes, ketones, esters, acid chlorides, epoxides, and amides readily. In addition to that, ${\alpha},{\beta}$-unsaturated aldehyde is reduced to ${\alpha},{\beta}$-unsaturated alcohol. Quinones are reduced to the corresponding diols without evolution of hydrogen. Tertiary amides and aromatic nitriles are converted to aldehydes with a limiting amount of LTDBA. Finally, disulfides and sulfoxides are readily reduced to thiols and sulfides, respectively, without hydrogen evolution.

• Applied Chemistry for Engineering
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• v.29 no.6
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• pp.635-644
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• 2018

Lithium ion batteries have been broadly used in various applications to our daily life such as portable electronics, electric vehicles and grid-scale energy storage devices. Significant efforts have recently been made on developing electrode materials for lithium ion batteries that meet commercial needs of the high energy density, light weight and low cost. In this review, we summarize the principles and recent research advances in cathode and anode materials for lithium ion batteries, and particularly emphasize electrode material designs and advanced characterization techniques.

• The Transactions of the Korean Institute of Power Electronics
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• v.24 no.5
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• pp.342-348
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• 2019

The emergency power supplies (EPSs) are required to increase battery sizing for protecting power source loss above designed criteria. This study proposes a sizing method for lithium-based batteries for EPSs in nuclear power plants on the basis of the calculation method for the required energy under variable conditions. The variable conditions are related with the characteristics of lithium-based batteries, such as the temperature of the location of EPS installation, aging, and design margin. The usage of lithium-based battery reduces the cost and installation space and enables the safe and long-term supply of power compared with the use of lead-acid battery.

• Journal of Electrochemical Science and Technology
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• v.13 no.1
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• pp.19-31
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• 2022

Lithium-ion battery development is one of the most active contemporary research areas, gaining more attention in recent times, following the increasing importance of energy storage technology. The galvanostatic intermittent titration technique (GITT) has become a crucial method among various electrochemical analyses for battery research. During one titration step in GITT, which consists of a constant current pulse followed by a relaxation period, transient and steady-state voltage changes were measured. It draws both thermodynamic and kinetic parameters. The diffusion coefficients of the lithium ion, open-circuit voltages, and overpotentials at various states of charge can be deduced by a series of titration steps. This mini-review details the theoretical and practical aspects of GITT analysis, from the measurement method to the derivation of the diffusivity equation for research cases according to the specific experimental purpose. This will shed light on a better understanding of electrochemical reactions and provide insight into the methods for improving lithium-ion battery performance.

• Smart Media Journal
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• v.11 no.11
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• pp.63-74
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• 2022

Nowadays, lithium-ion battery has become more popular around the world. Knowing when batteries reach their end of life (EOL) is crucial. Accurately predicting the remaining useful life (RUL) of lithium-ion batteries is needed for battery health management systems and to avoid unexpected accidents. It gives information about the battery status and when we should replace the battery. With the rapid growth of machine learning and deep learning, data-driven approaches are proposed to address this problem. Extracting aging information from battery charge/discharge records, including voltage, current, and temperature, can determine the battery state and predict battery RUL. In this work, we first outlined the charging and discharging processes of lithium-ion batteries. We then summarize the proposed techniques and achievements in all published data-driven RUL prediction studies. From that, we give a discussion about the accomplishments and remaining works with the corresponding challenges in order to provide a direction for further research in this area.