• Title/Summary/Keyword: liquid storage

Search Result 851, Processing Time 0.025 seconds

Degradation of cyclic compounds by liquid ferrate(VI) manufactured by an innovative method (액상 ferrate(VI)를 이용한 고리형 화합물 분해 특성 연구)

  • Jung, Sun-Young;Kim, Il-Kyu
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.32 no.1
    • /
    • pp.27-35
    • /
    • 2018
  • The stability of liquid ferrate(VI) produced by an innovative method was confirmed and the degradation characteristics of cyclic compounds(Benzene, Aniline, Toluene, 1,4-Dioxane) by liquid ferrate(VI) were investigated under the same reaction conditions. When it was compared with the ferrate manufactured by the wet oxidation method, the liquid ferrate was more stable. And the stability of liquid ferrate was tested at the storage temperature. As a result, only 17.7% of liquid ferrate(VI) has decomposed at the storage temperature($4^{\circ}C$) for 28 days. Among the cyclic compounds, the aniline was rapidly degraded compare to other cyclic compounds, which seems to be due to the electron-donating ability of the substituent, $-NH_2$ group. Especially, when 1,4-dioxane was compared with benzene, the decomposition rate of 1,4-dioxane was lower than that of benzene, suggesting that oxygen atoms hinder the electrophilic reaction. Among 4 cyclic compounds, it was observed that aniline has the highest rate constant than those of other cyclic compounds.

Study on seismic response of a seismic isolation liquid storage tank

  • Xiang Li;Jiangang Sun;Lei Xu;Shujin Zhang;Lifu Cui;Qinggao Zhang;Lijie Zhu
    • Earthquakes and Structures
    • /
    • v.26 no.5
    • /
    • pp.337-348
    • /
    • 2024
  • This paper presents a new seismic isolation design for liquid storage tank (LST). The seismic isolation system includes: LST, flexible membrane, sand mat and rolling seismic isolation devices. Based on the mechanical equilibrium theory, the symmetric concave rolling restoring force model of the isolation device is derived. Based on the elasticity theory and restoring force model of the seismic isolation, a simplified mechanical model of LST with the new seismic isolation is established. The rationality of the seismic isolation design of LST is explored. Meanwhile, the seismic response of the new seismic isolation LST is investigated by numerical simulation. The results show that the new seismic isolation tank can effectively reduce the seismic response, especially the control of base shear and overturning moment, which greatly reduces the risk of seismic damage. The seismic reduction rate of the new seismic isolation storage tanks in Class I, II, and III sites is better than that in Class IV sites. Moreover, the seismic isolation device can effectively control the ground vibration response of storage tanks with different liquid heights. The new seismic isolation LST design provides better isolation for slender LSTs than for broad LSTs.

Design of Sidewall Ribs for Suppressing Vortex Structures and Reducing Evaporation Rate in Liquid Hydrogen Storage Tank (액체수소 저장용기의 와류 구조 억제 및 증발률 저감을 위한 측벽 rib 설계)

  • Byeonggeon Kim;Hyungi Kim;Yunjeong Park;Mingyu Im;Sungwoo Park;Jinyul Hwang
    • Journal of the Korean Society of Visualization
    • /
    • v.22 no.2
    • /
    • pp.11-19
    • /
    • 2024
  • We performed numerical simulations on a C-type liquid hydrogen (LH2) storage tank for commercial vehicles to reduce evaporation rates by manipulating vortical structures. Owing to external heat, natural convection occurs inside the tank, leading to the enhanced evaporation of LH2. We observed that the regions of high magnitude vorticity correlate with those of high evaporation rates. Specifically, vortical structures in the side section area show higher vorticity magnitude and evaporation rates compared to those in the midsection area. To suppress these vortical motions, we installed an array of ribs at intervals corresponding to the mean diameter of the vortical structures. As a result, the area occupied by vortical structures in the side section area decreased, leading to a reduction in evaporation speed by approximately 2.3 times. This study elucidates the internal evaporation mechanism in storage tanks from the perspective of flow structures and potentially contributes to minimizing the boil-off rate in cryogenic storage tanks.

Changes in Quality of Welsh Onion (Allium fistulosum L.) during the Freezing Storage Period under Different Freezing Conditions (냉동조건에 따른 대파의 냉동저장 중 품질변화)

  • Kim, Seok-Young;Kim, Hee-Sun;Kim, Jin-Se;Han, Gwi-Jung
    • Korean journal of food and cookery science
    • /
    • v.32 no.6
    • /
    • pp.665-676
    • /
    • 2016
  • Purpose: This study was conducted to find the optimal freezing method and storage conditions for welsh onion. Methods: Cut welsh onions (0.3 cm) were packed in nylon/linear low density polyethylene (LLDPE) film bags, and frozen utilizing still-air freezing at -$20^{\circ}C$ (SAF20) and -$40^{\circ}C$ (SAF40), and immersed-liquid freezing at -$40^{\circ}C$ (ILF40); they were then stored at -$20^{\circ}C$ for 7 months. During storage, quality characteristics were measured monthly. Results: Drip loss was the lowest in the ILF40 packaging. Color difference in the stem (white part) did not differ significantly according to freezing conditions and storage time. Color difference in the leaf (green part) and stem was the lowest in SAF20. pH remained unchanged, while total aerobic bacterial count, pyruvic acid and moisture content decreased during storage. Pyruvic acid content of ILF40 was the highest among the freezing treatments. Fructose and glucose contents increased gradually during storage. Citric acid, malic acid, succinic acid and fumaric acid contents were unaffected, regardless of the freezing conditions. Conclusion: The optimal freezing method for welsh onions with the least quality changes was determined to be immersed liquid freezing, following by preservation up to 7 months by freeze-storing.

Synthesis and Properties of Pyrrolidinium and Piperidinium Bis(trifluoromethanesulfonyl)imide Ionic Liquids with Allyl Substituents

  • Yim, Tae-Eun;Lee, Hyun-Yeong;Kim, Hyo-Jin;Mun, Jun-Young;Kim, Sang-Mi;Oh, Seung-M.;Kim, Young-Gyu
    • Bulletin of the Korean Chemical Society
    • /
    • v.28 no.9
    • /
    • pp.1567-1572
    • /
    • 2007
  • New pyrrolidinium and piperidinium bis(trifluoromethanesulfonyl)imide (TFSI) ionic liquids (ILs) having allyl substituents were synthesized and characterized. All of them are liquid at room temperature and stable up to 300 oC. The pyrrolidinium-based ILs showed better conductivities and lower viscosities than the corresponding piperidinium-based ILs. Among them, 1-allyl-1-methylpyrrolidinium TFSI showed the lowest viscosity of 52 cP, the highest conductivity of 5.7 mS cm?1, and the most negative cathodic voltage window of ?3.2 V (vs. Fc/Fc+) on a platinum electrode, which are the improved results compared to the corresponding analogue having a saturated substituent, 1-methyl-1-propylpyrrolidinium TFSI.

Experimental study on the applicability of liquid air as the refrigerant in artificial ground freezing for subsea tunnels (해저터널을 위한 동결공법 냉매로서의 액화공기 적용성에 대한 실험적 연구)

  • Son, Young-Jin;Choi, Hyeungchul;Moon, Hung-Man;Choi, Hangseok;Ko, Tae Young
    • Journal of Korean Tunnelling and Underground Space Association
    • /
    • v.18 no.2
    • /
    • pp.175-181
    • /
    • 2016
  • In this paper, the liquid air was selected as the refrigerant in artificial ground freezing to be used for rapid ground freezing and to reduce the risk of suffocation and the applicability of liquid air was verified. In order to evaluate the stability of the liquid air, the oxygen concentration of mixtures with liquid nitrogen and liquid oxygen was experimentally examined to meet the oxygen concentration criteria in the Occupational Safety and Health Act. In addition, the effects of the mixture ratio of liquid nitrogen and liquid oxygen, pressure and flow rate change in the storage vessel on the oxygen concentration in the liquid air were investigated. As a result, the ratio of liquid nitrogen and liquid oxygen 8: 2 was shown to meet the oxygen concentration standards. Pressure and flow rate change in the storage vessel did not have significant effects on the oxygen concentration in the liquid air.

Development and Validation of Predictive Model for Salmonella Growth in Unpasteurized Liquid Eggs

  • Kim, Young-Jo;Moon, Hye-Jin;Lee, Soo-Kyoung;Song, Bo-Ra;Lim, Jong-Soo;Heo, Eun-Jeong;Park, Hyun-Jung;Wee, Sung-Hwan;Moon, Jin-San
    • Food Science of Animal Resources
    • /
    • v.38 no.3
    • /
    • pp.442-450
    • /
    • 2018
  • Liquid egg products can be contaminated with Salmonella spp. during processing. A predictive model for the growth of Salmonella spp. in unpasteurized liquid eggs was developed and validated. Liquid whole egg, liquid yolk, and liquid egg white samples were prepared and inoculated with Salmonella mixture (approximately 3 Log CFU/mL) containing five serovars (S. Bareilly, S. Richmond, S. Typhimurium monophasic, S. Enteritidis, and S. Gallinarum). Salmonella growth data at isothermal temperatures (5, 10, 15, 20, 25, 30, 35, and $40^{\circ}C$) was collected by 960 h. The population of Salmonella in liquid whole egg and egg yolk increased at above $10^{\circ}C$, while Salmonella in egg white did not proliferate at all temperature. These results demonstrate that there is a difference in the growth of Salmonella depending on the types of liquid eggs (egg yolk, egg white, liquid whole egg) and storage temperature. To fit the growth data of Salmonella in liquid whole egg and egg yolk, Baranyi model was used as the primary model and the maximum growth rate and lag phase duration for each temperature were determined. A secondary model was developed with maximum growth rate as a function of temperature. The model performance measures, bias factor ($B_f$, 0.96-0.99) and $r^2$ (0.96-0.99) indicated good fit for both primary and secondary models. In conclusion, it is thought that the growth model can be used usefully to predict Salmonella spp. growth in various types of unpasteurized liquid eggs when those are exposed to various temperature and time conditions during the processing.

A study on the construction characteristic of bath cryostat (Bath cryostat의 제작특성에 관한 연구)

  • Kim, G.Y.
    • Journal of the Korean Society for Precision Engineering
    • /
    • v.10 no.2
    • /
    • pp.138-145
    • /
    • 1993
  • The bath cryostat of cryogenic apparatuses which are generally used to study physical phenomena under low temperature and ultra low temperature has been desigened and constructed. The practical use of the cryostat is verified by the measurement of the storage life of liquid heloum and liquid nitrogen vessels. The cryostat consists of triple structure of high vacuum environment in order to minimize the evaporation rate of liquid helium and liquid nitrogen by thermal conductivity and radiant heat. The minimum thickness which can stand against inner and outer pressures is calculated from considering the strength of the material.

  • PDF

Evaluation of Dynamic Response for Liquid Storage Tank using the Observed Earthquake Data (지진계측데이타에 근거한 유체저장탱크의 동적응답 평가)

  • 허택영
    • Proceedings of the Earthquake Engineering Society of Korea Conference
    • /
    • 1997.04a
    • /
    • pp.115-127
    • /
    • 1997
  • A study to evaluate the seismic response of $\frac{1}{2}$-scaled liquid storage tank constructed in Hualien, is performed. And this study is to identify the liquid-structure-soil interaction by observed earthquake data ans analyzed results. After the calculation of soil impedance for the test site by SASSI code, 3-dimensional seismic response analysis is performed by BEM-FEM-Impedance Method with the consideration of liquid-structure-soil interaction when the tank is excited by real earthquake. The observed acceleration and hydrodynamic pressure are compared with the numerical results. This comparisons show good agreement in predominant frequency and maximum hydrodynamic pressure. And the free surface sloshing motion due to earthquake loadings is computed in time domain.

  • PDF

Simple predictive heat leakage estimation of static non-vacuum insulated cryogenic vessel

  • Mzad, Hocine
    • Progress in Superconductivity and Cryogenics
    • /
    • v.22 no.3
    • /
    • pp.25-30
    • /
    • 2020
  • The diminishing of heat leak into cryogenic vessels can prolong the storage time of cryogenic liquid. With the storage of cryogenic liquid reducing, the heat leak decreases, while the actual storage time increases. Regarding to the theoretical analysis, the obtained results seems to be constructive for the cryogenic insulation system applications. This study presents a predictive assessment of heat leak occurring in non-vacuum tanks with a single layer of insulation. A Radial steady-state heat transfer, based on heat conduction equation, is taken into consideration. Graphical results show the thermal performance of the insulation used, they also allow us to choose the appropriate insulation thickness according to the shape and diameter of the storage tank.