• Journal of Korea Foundry Society
• /
• v.35 no.4
• /
• pp.75-79
• /
• 2015

Commercial Zr-based amorphous alloy was recycled and oxygen was introduced during the recycling process. The oxygen content can have a great effect on the glass forming ability and the mechanical properties of the alloy. Therefore, it was closely examined. The initial oxygen content in the raw material was 1,244 ppm. It was increased to 3,789 ppm in the alloy after ten recycling processes. As the recycling processes were repeated, the oxygen content increased. Specifically, after four recycling processes, it increased sharply as compared to that after three recycling processes. After ten recycling processes, the glass transition temperature (Tg) increased from 613 K to 634 K and the crystallization temperature (Tx) increased from 696 K to 706 K. On the other hand, the super-cooled liquid region (${\Delta}T=Tx-Tg$) decreased slightly from 83 K to 72 K while the reduced glass transition temperature (Trg = Tg/Tm) was 0.63, remaining constant even when the oxygen content was increased. These results indicated that the increased oxygen content deteriorated the glass forming ability. The bending strength as determined in a three-point bending test showed a sharp decrease from 3,055 to 2,062 MPa as the oxygen content was increased from 1,244 ppm to 3,789 ppm; the extension was also decreased from 3.02 to 1.74 mm. These findings meant that the alloy became brittle.

• Resources Recycling
• /
• v.24 no.3
• /
• pp.27-33
• /
• 2015

EAFD (Electric Arc Furnace Dust) is considered as pernicious pollutant, assigned hazardous waste. Since this dust is a by-product of industry, it contains valuable metals such as Fe, Zn, Ni, Cu which can be turned into resources by recycling process. In this study, hydrometallurgical process was applied to recover Zn from Electric Arc Furnace Dusts. The result showed 95% Zn recovery at 3M $H_2SO_4$, Solids/Liquid ratio 1:2 and aeration of 1.8L/min for 2hr. However there was 80% Zn recovery at lower $H_2SO_4$ concentration apply for pilot scale plant.

• Journal of Korean Society of Industrial and Systems Engineering
• /
• v.40 no.1
• /
• pp.35-40
• /
• 2017

A most important progress in civilization was the introduction of mass production. One of main methods for mass production is die-casting molds. Due to the high velocity of the liquid metal, aluminum die-casting is so complex where flow momentum is critical matter in the mold filling process. Actually in complex parts, it is almost impossible to calculate the exact mold filling performance with using experimental knowledge. To manufacture the lightweight automobile bodies, aluminum die-castings play a definitive role in the automotive part industry. Due to this condition in the design procedure, the simulation is becoming more important. Simulation can make a casting system optimal and also elevate the casting quality with less experiment. The most advantage of using simulation programs is the time and cost saving of the casting layout design. For a die casting mold, generally, the casting layout design should be considered based on the relation among injection system, casting condition, gate system, and cooling system. Also, the extent or the location of product defects was differentiated according to the various relations of the above conditions. In this research, in order to optimize the casting layout design of an automotive Oil Pan_BR2E, Computer Aided Engineering (CAE) simulation was performed with three layout designs by using the simulation software (AnyCasting). The simulation results were analyzed and compared carefully in order to apply them into the production die-casting mold. During the filling process with three models, internal porosities caused by air entrapments were predicted and also compared with the modification of the gate system and overflows. With the solidification analysis, internal porosities occurring during the solidification process were predicted and also compared with the modified gate system.

• Proceedings of the Materials Research Society of Korea Conference
• /
• 2011.05a
• /
• pp.58.1-58.1
• /
• 2011

WC-Co and other similar cemented carbides have been widely used as hard materials in industrial cutting tools and as mould metals; and a number of techniques have been applied to improve its microstructural characteristics, hardness and ear resistance. Cobalt is used primarily to facilitate liquid phase sintering and acts as a matrix, i.e. a cementing phase between WC grains. A uniform distribution of metal phase in a ceramic is beneficial for improved mechanical properties of the composite. WC-Co, starting from initial powders, is vastly used for a variety of machining, cutting, drilling, and other applications because of its unique combination of high strength, high hardness, high toughness, and moderate modulus of elasticity, especially with fine grained WC and finely distributed cobalt. In this study, that started with two different compositions of initial powders, WC-7.5wt%Co and WC-12wt%Co with initial powder size being 1~3 ${\mu}m$, magnetic pulsed compaction followed by subsequent vacuum sintering were carried out to produce consolidated preforms. Magnetic Pulsed Compaction (MPC), a very short duration (~600 ${\mu}s$), high pressure (~4 Gpa), high-density preform molding method was used with varied pressure between 0.5 and 3.0 Gpa, in order to reach an initial high density that would help improve the sintering behavior. For both compositions and varied MPC pressure, before and after sintering, changes in microstructural behavior and mechanical properties were analyzed. With proper combination of MPC pressure and sintering, samples were obtained with better mechanical properties, densification and microstructural behavior, and considerably improved than other conventional processes.

• Nuclear Engineering and Technology
• /
• v.41 no.8
• /
• pp.1053-1064
• /
• 2009

The existence of a large sodium pool in the KALIMER, a pool-type LMR developed by the Korea Atomic Energy Research Institute, plays an important role in reactor safety and operability because it determines the grace time for operators to cope with an abnormal event and to terminate a transient before reactor enters into an accident condition. A two-dimensional hot pool model has been developed and implemented in the SSC-K code, and has been successfully applied for the assessment of safety issues in the conceptual design of KALIMER and for the analysis of anticipated system transients. The other important models of the SSC-K code include a three-dimensional core thermal-hydraulic model, a reactivity model, a passive decay heat removal system model, and an intermediate heat transport system and steam generation system model. The capability of the developed two-dimensional hot pool model was evaluated with a comparison of the temperature distribution calculated with the CFX code. The predicted hot pool coolant temperature distributions obtained with the two-dimensional hot pool model agreed well with those predicted with the CFX code. Variations in the temperature distribution of the hot pool affect the reactivity feedback due to an expansion of the control rod drive line (CRDL) immersed in the pool. The existing CRDL reactivity model of the SSC-K code has been modified based on the detailed hot pool temperature distribution obtained with the two-dimensional pool model. An analysis of an unprotected transient over power with the modified reactivity model showed an improved negative reactivity feedback effect.

• International Journal of Internet, Broadcasting and Communication
• /
• v.7 no.2
• /
• pp.96-104
• /
• 2015

Fischer Tropsch reaction is one of the interesting topic for renewable and clean energy. Polymerization of carbon monoxide or carbon dioxide with hydrogen over metal supported catalyst can produce long chain hydrocarbons. Synthetic liquid hydrocarbons are promising alternative to fossil fuels. This research work has been focused on the synthesis of Fe based catalyst for Fischer Tropsch reaction. Mesoporous silica (MS) support prepared by a precipitation method using two different washing solution, distilled water (DW) and acid in ethanol solution (ET), and different calcination temperature. Then, Fe/MS was prepared by an incipient wetness impregnation method. All of samples were systematically characterized using various physical and chemical techniques. TEM and XRD analysis were used to ensure that the cubic Ia3d mesostructure is stable after calcination. FTIR spectra are useful to ascertain the existence of template in the support. TPR studies were also used to understand the nature of Fe species and their reducibility. The results reveal that washing the support with distilled water and calcination at $550^{\circ}C$ can efficiently remove the triblock copolymer templates. The existence of template in the support affects the textural properties of all catalyst investigated.

• Journal of the Korea Institute of Military Science and Technology
• /
• v.1 no.1
• /
• pp.227-237
• /
• 1998

HgCdTe Is the most versatile material for the developing infrared devices. Not like III-V compound semiconductors or silicon-based photo-detecting materials, HgCdTe has unique characteristics such as adjustable bandgap, very high electron mobility, and large difference between electron and hole mobilities. Many research groups have been interested in this material since early 70's, but mainly due to its thermodynamic difficulties for preparing materials, no single growth technique is appreciated as a standard growth technique in this research field. Solid state recrystallization(SSR), travelling heater method(THM), and Bridgman growth are major techniques used to grow bulk HgCdTe material. Materials with high quality and purity can be grown using these bulk growth techniques, however, due to the large separation between solidus and liquidus line on the phase diagram, it is very difficult to grow large materials with minimun defects. Various epitaxial growth techniques were adopted to get large area HgCdTe and among them liquid phase epitaxy(LPE), metal organic chemical vapor deposition(MOCVD), and molecular beam epitaxy(MBE) are most frequently used techniques. There are also various types of photo-detectors utilizing HgCdTe materials, and photovoltaic and photoconductive devices are most interested types of detectors up to these days. For the larger may detectors, photovoltaic devices have some advantages over power-requiring photoconductive devices. In this paper we reported the main results on the HgCdTe growing and characterization including LPE and MOCVD, device fabrication and its characteristics such as single element and linear array($8{\times}1$ PC, $128{\times}1$ PV and 4120{\times}1$ PC). Also we included the results of the dewar manufacturing, assembling, and optical and environmental test of the detectors.

• Journal of the Earthquake Engineering Society of Korea
• /
• v.5 no.5
• /
• pp.25-33
• /
• 2001

For the seismic design and analysis of LMR(liquid metal reactor) being developed in Korea, it is necessary to develop the simple seismic analysis model including the fluid-structure interaction effects. In this paper, the theoretical backgrounds for the fluid added mass of the immersed concentric cylinders are investigated and the seismic analysis code using the Runge-Kutta algorithm, which can consider the fluid added mass matrix in system matrix, are developed to perform the time history seismic analysis. Form the coupled modal analysis and the seismic analysis for the simple immersed concentric cylinders, it is verified that the fluid added mass significantly affect the vibration characteristics and the seismic responses. Therefore the fluid coupled effects should be carefully considered in seismic response analysis of the immersed concentric cylinders.

• Applied Chemistry for Engineering
• /
• v.30 no.6
• /
• pp.652-658
• /
• 2019

Direct hydrazine fuel cells (DHFCs) have been considered to be one of the promising fuel cells because hydrazine as a liquid fuel possesses several advantages such as no emission of CO₂, relatively high energy density and catalytic activity over platinum group metal (PGM)-free anode catalysts. Judging from plenty of research works, however, regarding key components such as electrocatalysts as well as their physicochemical properties, it becomes quite necessary to understand better the underlying processes in DHFCs for the long term stability. Herein, we highlight recent studies of DHFCs in terms of a systematic approach for developing cost-effective and stable anode catalysts and electrode structures that incorporate mass transport characteristics of hydrazine, water and gas bubbles.

• Journal of the Korean Vacuum Society
• /
• v.6 no.3
• /
• pp.206-212
• /
• 1997

The reflow characteristics of copper, which is expected to be used as interconnection materials in the next generation semiconductor devices, were investigated. Copper films were deposited on hole and trench patterns by metal organic chemical vapor deposition and annealed in nitrogen and oxygen ambient with the annealing temperatures ranging from $350^{\circ}C$ to $550^{\circ}C$. Copper films were not reflowed into the patterns upon the annealing in nitrogen ambient, but reflowed at the annealing temperature higher than $450^{\circ}C$ in oxygen ambient. It is considered that the reflow takes place as the heat generated by the oxidation of copper liquefies the copper film partly and the liquid copper fills the patterns for minimizing the surface energy and the potential energy. Upon the annealing in oxygen ambient, the copper oxide whose thickness was less than 300$\AA$ formed at the surface of an agglomerate and the resistivity of copper film increased drastically at an annealing temperature of $550^{\circ}C$ due to the copper agglomeration.