• Title/Summary/Keyword: liquid limits

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ESTIMATION OF OFF-SITE DOSE AND RELEASE CONCENTRATION OF RADIOACTIVE LIQUID EFFLUENTS FROM RADWASTE TREATMENT SYSTEM IN KORI 3&4

  • Kim, H.S.;Son, J.K.;Kim, K.D.;Ha, J.H.;Song, M.J.
    • Journal of Radiation Protection and Research
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    • v.26 no.3
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    • pp.291-298
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    • 2001
  • The designed release rate of liquid effluents from radwaste treatment system should be calculated and evaluated during normal operation, including anticipated operational occurrence and be assured that the release concentration and off-site dose at unrestricted area do not exceed the limits of regulation. The expected annual release rate and off-site dose for the currently operating nuclear power plants in Korea had been calculated and evaluated using PWR-GALE and LADTAP-II which was based on USNRC Regulatory Guide 1.109. Recently, the MOST Notice 2001-2 related to release concentration and off-site dose at unrestricted area was revised to reflect the concept of ICRP-60. It is necessary for KORI 3&4 to re-calculate the release concentration and off-site dose and to compare these results with the limits of regulation. As the results of assessment, we confirmed that the release concentrations were less than its limits of MOST Notice 2001-2 and the off-site dose at unrestricted area using K-DOSE60 was 3.61E-03 mSv/yr to the age of five for the effective dose, and 4.10E-2 mSv/yr to thyroid of the age of five for the organ equivalent dose. We also confirmed the off-site dose was within the limits of MOST Notice 2001-2. Therefore, the release concentration and off-site dose re-evaluated at unrestricted area in KORI 3&4 were well below the regulation limits of MOST Notice 2001-2.

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Prediction of Lower Explosion Limits of Binary Liquid Mixtures by Means of Solution Thermodynamics (용액열역학에 의한 2성분계 혼합물의 폭발하한계 예측)

  • Ha, Dong-Myeong;Lee, Sung-Jin
    • Journal of the Korean Institute of Gas
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    • v.13 no.5
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    • pp.20-25
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    • 2009
  • Low explosion limits of flammable liquid mixtures can be calculated with the appropriate use of the fundamental laws of Raoult, Dalton, Le Chatelier and activity coefficient models. In this paper, Raoult's law, van Laar equation and Wilson equation are shown to be applicable for the prediction of the lower explosion limits for ethylacetate+ethanol and ethanol+toluene systems. The calculated values based on Raoult's law were found to be better than those based on van Laar and Wilson equations.

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Prediction of Upper Explosion Limits(UEL) by Measurement of Upper Flash Point Using Setaflash Apparatus for n-Alcohols (Setaflash 장치를 이용한 노말 알코올류의 상부인화점 측정에 의한 폭발상한계의 예측)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.25 no.2
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    • pp.35-40
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    • 2010
  • Explosion limit and flash point are the major combustion properties used to determine the fire and explosion hazards of the flammable substances. In this study, in order to predict upper explosion limits(UEL), the upper flash point of n-alcohols were measured under the VLE(vapor-liquid equilibrium) state by using Setaflash closed cup tester(ASTM D3278). The UELs calculated by Antoine equation using the experimental upper flash point are usually lower than the several reported UELs. From the given results, using the proposed experimental and predicted method, it is possible to research the upper explosion limits of the other flammable substances.

Prediction of Upper Explosion Limits(UEL) by Measurement of Upper Flash Points for n-Alkanes and Aromatic Compounds (노말알칸류와 방향족탄화수소류의 상부인화점 측정에 의한 폭발상한계의 예측)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.26 no.4
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    • pp.59-64
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    • 2011
  • Explosion limit and flash point are the major combustion properties used to determine the fire and explosion hazards of the flammable substances. In this study, in order to predict upper explosion limits(UELs), the upper flash point of n-alkanes and aromatic compounds were measured under the VLE(vapor-liquid equilibrium) state by using Setaflash closed cup tester(ASTM D3278). The UELs calculated by Antoine equation and chemical stoichiometric coefficient tusing the experimental upper flash point were compared with the several reported UELs. From the given results, using the proposed experimental and predicted method, it is possible to research the upper explosion limits of the other flammable substances.

Development of Prototype Liquid Scintillator System for Monitoring Liquid Radioactive Waste (배수 모니터링 액체섬광검출시스템의 프로토 타입 개발)

  • Nam, Uk-Won;Seon, Kwang-Il;Kong, Kyoung-Nam;Kim, Chang-Kyu;Lee, Dong-Myung;Lee, Sang-Kook
    • Journal of Radiation Protection and Research
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    • v.28 no.3
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    • pp.173-182
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    • 2003
  • A prototype liquid scillatillator system for measurement of multiple beta-labeled mixtures was developed and its characteristic was investigated. The signal processing system consists of two photomultiplier tubes and the coincident count circuit. The characteristic of the system was analyzed using 4 beta-labeled samples $(^3H,\;^{14}C,\;^{36}Cl\;and\;^{90}Sr)$. Beta spectra from the samples were obtained without radiation shielding, and the detection limits for each nuclides were estimated based on the spectra. The estimated detection limits were compared to the legal regulation values. It is found that the liquid radioactive nuclides are detectable well below the legal regulation values.

Development of Analytical Method and Monitoring of Organophosphorus Pesticides in the Raw Water and Clean Water by Liquid Chromatography-Tandem Mass Spectrometry (LC/MS/MS를 이용한 유기인계 농약류의 최적 분석법 정립과 원·정수에서의 모니터링)

  • Kim, Gyung-A;Song, Mi-Jeong;Yeom, Hoon-Sik;Son, Hee-Jong;Lee, Sang-Won;Choi, Jin-Tack
    • Journal of Environmental Science International
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    • v.24 no.12
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    • pp.1569-1582
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    • 2015
  • The analytical method for 16 organophosphorus pesticides was developed in this study. The 16 organophosphorus pesticides were analyzed by liquid chromatography-tandem mass spectrometry (LC/MS/MS) using on-line solid phase extraction (on-line SPE) with PLRP- S cartridge. Analysis of all analytes in the MS/MS was processed in the electrospray ioni-zation (ESI) positive mode. They are Azinphos ethyl, Chlorfenvinphos, Ethion, Famphur, Phosmet, Phosphamidon, Terbufos, Aspon, Chlorpyrifos-methyl, Crotoxyphos, Dichlofenthi-on, Dicrotophos, Fonofos, Thionazin, Dimethoate and Iprobenfos. Limits of detection (LODs) and Limits of quantification(LOQs) were obtained as 0.8~2.0 ng/L and 2.6~6.4 ng/L, respectively. All compounds were not detected at the 8 sampling points of the raw water and clean water.

Capillary Electrochromatography with Liquid Crystal Crown Ether Modified Hybrid Silica Monolith for Analysis of Imidacloprid and Carbendazim in Tomatoes

  • Wang, Mingming;Feng, Rui;Shen, Jing;Chen, Hao;Zeng, Zhaorui
    • Bulletin of the Korean Chemical Society
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    • v.33 no.7
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    • pp.2224-2228
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    • 2012
  • This study describes the ability of capillary electrochromatography (CEC) for the determination of imidacloprid and carbendazim in tomato samples. A novel liquid crystal crown ether modified hybrid silica monolithic column was synthesized, characterized and developed as separation column for the first time. Baseline separation of imidacloprid and carbendazim could be achieved using a mobile phase containing 90% (v/v) 20 mmol/L phosphate buffer (pH 7.0) and 10% (v/v) acetonitrile. The matrix matched calibration curves were linear with correlation coefficient $r^2$ > 0.9998 in the range of 0.20-10.00 mg/L. The limits of detection for imidacloprid and carbendazim were 0.061 and 0.15 mg/kg, respectively, which were below the maximum residue limits established by the European Union as well as Codex Alimentarius. Average recoveries for imidacloprid and carbendazim varied from 101.6-108.0% with relative standard deviations lower than 6.3%. This method was applied to the analysis of tomatoes collected from local markets.

Effect of Sand Contents on Plastic and Liquid Limits and Shear Strength of Clays (모래 함유량이 점토의 액소성한계 및 전단강도에 미치는 영향)

  • Park, Sung-Sik;Nong, Zhenzhen
    • Journal of the Korean Geotechnical Society
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    • v.30 no.2
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    • pp.65-76
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    • 2014
  • For soil improvement, sand mats or sand compaction piles are often constructed on soft marine clays. In such cases, some amounts of sand and clay are inevitably mixed. Sand or gravel often exists in the weathered soils near the slope surface. This research investigates the effect of mixing sand content on consistency limits and shear strength of clays. Firstly, sand was mixed with kaolinite or bentonite at 0, 9, 17, 23, 29, 33, 50% and then liquid and plastic limits were measured. Both plastic and liquid limits decreased as a sand content increased. The water content of clay-sand mixtures with different sand content increased by 10% or 20% step by step and then their undrained shear strength was measured using a portable vane shear device called Torvane. For all cases, undrained shear strength of clay-sand mixtures decreased rapidly until reaching a certain value. Their state changed from undrained to drained state gradually as the sand content increased, which caused their undrained shear strength to decrease. On the other hand, a series of direct shear tests were also conducted on such clay-sand mixtures to investigate the effect of sand content on cohesion and angle of internal friction. It was found from clay-sand mixtures that their cohesion decreased but angle of internal friction increased as the sand content increased.

Microcystin Detection Characteristics of Fluorescence Immunochromatography and High Performance Liquid Chromatography

  • Pyo, Dong-Jin;Park, Geun-Young;Choi, Jong-Chon;Oh, Chang-Suk
    • Bulletin of the Korean Chemical Society
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    • v.26 no.2
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    • pp.268-272
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    • 2005
  • Different detection characteristics of fluorescence immunochromatography method and high performance liquid chromatography (HPLC) method for the analysis of cyanobacterial toxins were studied. In particular, low and high limits of detection, detection time and reproducibility and detectable microcystin species were compared when fluorescence immunochromatography method and high performance liquid chromatography method were applied for the detection of microcystin (MC), a cyclic peptide toxin of the freshwater cyanobacterium Microcystis aeruginosa. A Fluorescence immunochromatography assay system has the unique advantages of short detection time and low detection limit, and high performance liquid chromatography detection method has the strong advantage of individual quantifications of several species of microcystins.

CFD analysis on the behavior of liquid water in flow channel of PEM fuel cell (PEM 연료전지 유로에서 물의 거동에 대한 CFD 해석)

  • Kim, Hyun-Il;Nam, Jin-Hyun;Shin, Dong-Hoon;Chung, Tae-Yong;Kim, Young-Gyu
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.23-26
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    • 2007
  • Liquid water in flow channel is an important factor that limits the steady and transient performance of PEM fuel cells. A computational fluid dynamics study based on the volume-of-fluid (VOF) multi-phase model is conducted to understand the transport behavior of liquid water in flow channel. The liquid water transport in $180^{\circ}$ bends is investigated and the effect of chamfering is discussed. The effect of wall adhesion is also considered by varying the contact angle of channel surfaces. The result of this study is believed to provide a useful guideline for design optimization of flow patterns or channel configurations of PEM fuel cells.

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