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http://dx.doi.org/10.5322/JESI.2015.24.12.1569

Development of Analytical Method and Monitoring of Organophosphorus Pesticides in the Raw Water and Clean Water by Liquid Chromatography-Tandem Mass Spectrometry  

Kim, Gyung-A (Water Quality Institute, Busan Water Authority)
Song, Mi-Jeong (Water Quality Institute, Busan Water Authority)
Yeom, Hoon-Sik (Water Quality Institute, Busan Water Authority)
Son, Hee-Jong (Water Quality Institute, Busan Water Authority)
Lee, Sang-Won (Water Quality Institute, Busan Water Authority)
Choi, Jin-Tack (Water Quality Institute, Busan Water Authority)
Publication Information
Journal of Environmental Science International / v.24, no.12, 2015 , pp. 1569-1582 More about this Journal
Abstract
The analytical method for 16 organophosphorus pesticides was developed in this study. The 16 organophosphorus pesticides were analyzed by liquid chromatography-tandem mass spectrometry (LC/MS/MS) using on-line solid phase extraction (on-line SPE) with PLRP- S cartridge. Analysis of all analytes in the MS/MS was processed in the electrospray ioni-zation (ESI) positive mode. They are Azinphos ethyl, Chlorfenvinphos, Ethion, Famphur, Phosmet, Phosphamidon, Terbufos, Aspon, Chlorpyrifos-methyl, Crotoxyphos, Dichlofenthi-on, Dicrotophos, Fonofos, Thionazin, Dimethoate and Iprobenfos. Limits of detection (LODs) and Limits of quantification(LOQs) were obtained as 0.8~2.0 ng/L and 2.6~6.4 ng/L, respectively. All compounds were not detected at the 8 sampling points of the raw water and clean water.
Keywords
Organophosphorus pesticides; Liquid chromatography-tandem mass spectrometry; On-line solid phase extraction; Electrospray ionization; Azinphos ethyl;
Citations & Related Records
Times Cited By KSCI : 4  (Citation Analysis)
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1 Anagnostopoulos, C., Miliadis, G. E., 2013, Development and validation of an easy multiresidue method for the determination of multiclass pesticide residues using GC-MS/MS and LC-MS/MS in olive oil and olives. Talanta, 112, 1-10.   DOI
2 Sim, H. R., Kim, S. H., Lee, J. Y., Lee, H. J., 2009, Creating highly sensitive and selective bio-chip sensors for the detection of organophosphorus/ carbamate pesticides, J. Korean Ind. Eng. Chem., 20 (6), 571-580.
3 Choi, J. W., Kim. Y. S., 2010, Applications of high resolution mass spectrometer for simultaneous measurement of residual organophosphorous pesticides, J. of the Korean Society for Environmental Analysis, 13(4), 195-203.
4 Choi, J. W., Kim, Y. S., 2011, Applications of high resolution mass spectrometer for simultaneous quantitation of pyrethroid pesticides in water, J. of the Korean Society for Environmental Analysis, 14(1), 55-62.
5 Choi, J. W., 2012, Analysis of triazines in water using orbitrap high resolution and accurate mass spectrometer, J. of the Korean Society for Environmental Analysis, 15(4), 282-291.
6 Laura, D., Julio, L. P., Ignacio, V., 2008, Ultra trace determination of 31 pesticides in water samples by direct injection rapid resolution liquid chromatography-electrospray tandem mass spectrometry, analytica chimica acta, 624, 90-96.   DOI
7 Lee, W. J., 2011, Pesticide exposure and health, J. of Environ health sci., 37(2), 81-93.
8 Lutz, A., Kerstin, G., 2008, Fast multiresidue screening of 300 pesticides in water for human consumption by LC/MS/MS, Anal. Bioanal. Chem., 391, 183-197.   DOI
9 Ministry of Environment Notice, 2013, Official test methods of Drinking water quality, 2013(136).
10 Rural Development Administration(Nongjajae Management Division), 2012, Safe use of pesticides for agricultural production safety(educational resources).
11 Rural Development Administration(Pesticide Registration Search Service), 2014, http://npms.rda.go.kr/epmso.
12 Sinha, S. N., 2010, Effect of dissociation energy: signal to noise ratio on ion formation and sensitivity of analytical method for quantification and confirmation of triazofos in blood samples using gas chromatography-mass spectrometer (GC-MS/MS), International Journal of Mass Spectrometry, 296, 47-52.   DOI
13 Sinha, S. N., Bhatnagar V. K., Doctor, P., Toteja, G. S., Agnihotri, N. P., Kalra, R. L., 2011a, A novel method for pesticides analysis in refined sugar samples using GC-MS/MS and solvent extraction method, Food Chemistry, 126, 379-386.   DOI
14 Sinha, S. N., Vasudev, K., Vishnu Vardhana Rao M., Odetokun, M., 2011b, Quantification of organophosphate insecticides in drinking water in urban areas using lyophilization and high-performance liquid chromatography electrospray ionization-mass spectrometry technique. International Journal of Mass Spectrometry, 300, 12-20.   DOI
15 Sinha S. N., Vishnu Vardhana Rao M., Vasudev K., Odetokun M., 2012, A liquid chromatography mass spectrometry-based method to measure organophosphorous insecticide, herbicide and nonorganophosphorous pesticide in grape and apple samples, Food Control, 25, 636-646.   DOI
16 USEPA Method 535, 2005, Measurement of chloroacetanilide and other Acetamide herbicide degradates in drinking water by olid phaze extraction and liquid chromatography/tandem mass spectrometry(LC/MS/MS).
17 Thorsten R., Lutz A., Ursula B., 2013, A multimethod for the determination of 150 pesticide metabolites in surface water and groundwater using direct injection liquid chromatography mass spectrometry, J. Chromatography A, 1271, 95-104.   DOI