• Journal of the Korean Chemical Society
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• v.54 no.4
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• pp.437-442
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• 2010

Sodium hydrogen sulphate ($NaHSO_4$), n-tetra butyl ammonium bromide (TBAB) as a phase transfer catalyst (PTC) in water, and 1-butyl-3-methyl imidazolium hydrogen sulphate [bmim]$HSO_4$ as ionic liquid (IL) has been used as a mild reaction promoter for the cyclocondensation of formalin, ${\beta}$-naphthol and aromatic amines to afford respective 2,3-dihydro-2-phenyl-1H-naphtho-[1,2-e] [1,3] oxazine derivatives. The present protocols are greener, high yielding and involved the nonchromatographic isolation procedure.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2010.11a
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• pp.601-604
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• 2010

An experimental study was carried out to investigate the effect of film cooling in a liquid rocket engine using Hydrogen peroxide/Kerosene as propellants. The heat fluxes were calculated by the measured wall temperatures on the axial direction of thrust chamber for mass flow rate of coolant and different type of film cooling rings. The flow rate of coolant was 0~20 percent of the total propellant.

• Journal of Hydrogen and New Energy
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• v.30 no.2
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• pp.119-127
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• 2019

Reliable $H_2$ supply is necessary for entering a $H_2$ society. Among the various $H_2$ storage and transportation methods, liquid organic $H_2$ carrier (LOHC) is in the spotlight because of a lot of advantages compared to conventional one such as compressed $H_2$ and liquefied $H_2$. Therefore, we performed preliminary economic analysis of $H_2$ supply cost using LOHC for a $H_2$ production capacity of $300Nm^3\;h^{-1}$ employing itemized cost estimation and sensitivity analysis to evaluate economic viability of this technology in Korea.

• Progress in Superconductivity and Cryogenics
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• v.24 no.2
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• pp.27-38
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• 2022

Urban air mobility (UAM) has recently attracted lots of attention as a solution to urban centralization and global warming. Electric vertical take-off and landing (eVTOL) is a concept that emerges as one of the promising and clean technologies for UAM. There are two difficult challenges for eVTOL aircraft to solve. One is how to improve the weight efficiency of aircraft, and the other is how to complete long-range missions for UAM's flight scenarios. To approach these challenges, we propose a consolidated concept design of battery-fuel cell hybrid tiltrotor aircraft with a liquid hydrogen (LH₂) fuel tank. The efficiency of a battery-fuel cell hybrid powertrain system on the designed eVTOL aircraft is compared to that of a battery-only powertrain system. This paper shows how much payload can increase and the flight scenario can be improved by hybridizing the battery and fuel cell and presenting a detailed concept of a cryogenic storage tank for LH₂.

• Journal of the Korean Society of Visualization
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• v.22 no.2
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• pp.11-19
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• 2024

We performed numerical simulations on a C-type liquid hydrogen (LH2) storage tank for commercial vehicles to reduce evaporation rates by manipulating vortical structures. Owing to external heat, natural convection occurs inside the tank, leading to the enhanced evaporation of LH2. We observed that the regions of high magnitude vorticity correlate with those of high evaporation rates. Specifically, vortical structures in the side section area show higher vorticity magnitude and evaporation rates compared to those in the midsection area. To suppress these vortical motions, we installed an array of ribs at intervals corresponding to the mean diameter of the vortical structures. As a result, the area occupied by vortical structures in the side section area decreased, leading to a reduction in evaporation speed by approximately 2.3 times. This study elucidates the internal evaporation mechanism in storage tanks from the perspective of flow structures and potentially contributes to minimizing the boil-off rate in cryogenic storage tanks.

• Journal of Hydrogen and New Energy
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• v.16 no.3
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• pp.290-295
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• 2005

For the application of fuel cell, the content and concentration of impurities in hydrogen stream must be classified. The purpose of this study is to provide analysis tool for the determination of impurities in hydrogen with ultra high purity. To produce UHT hydrogen, we purified hydrogen gas by both getter-based catridge and liquid-nitrogen soaked catridge. We compare two methods and propose new method to know about what is in hydrogen stream.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.04a
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• pp.175-178
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• 2011

A performance characteristics and application status of liquid-monopropellants used for 3-axis control thrusters are surveyed, in this paper. Hydrogen peroxide was widely used as monopropellant until mid-1960s, but it is rapidly replaced with hydrazine which has better performance of specific impulse, storability, and so on. Hydrazine is mostly employed as a liquid-monopropellant of satellite, interplanetary spacecraft, and space launch vehicle owing to its moderate performance features.

• Journal of Hydrogen and New Energy
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• v.29 no.6
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• pp.627-634
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• 2018

Gallium-based liquid metal, e.g., eutectic gallium-indium (EGaIn), is highly attractive as an electrode material for flexible and stretchable devices. On the liquid metal, oxide layer is spontaneously formed, which has a wide band-gap, and therefore is electrically insulating. In this paper, we fabricate a capacitor based on eutectic gallium-indium (EGaIn) liquid metal and investigate its cyclic voltammetry (CV) behavior. The EGaIn capacitor is composed of two EGaIn electrodes and electrolyte. CV curves reveal that the EGaIn capacitor shows the behavior of electric double-layer capacitors (EDLC), where the oxide layers on the EGaIn electrodes serves as the dielectric layer of EDLC. The oxide thicker than the spontaneously-formed native oxide decreases the capacitance of the EGaIn capacitor, due to increased voltage loss across the oxide layer. The EGaIn capacitor without oxide layer exhibits unstable CV curves during the repeated cycles, where self-repair characteristic of the oxide was observed. Finally, the electrolyte concentration is optimized by comparing the CV curves at various electrolyte concentrations.

• Journal of the Korean Society of Propulsion Engineers
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• v.14 no.4
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• pp.46-58
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• 2010

Hydrogen peroxide(HP) and liquid methane have deserved renewed considerations as green propellants in recent years, because main design concerns in the development of the new generation propulsion system for spacecrafts are concentrated on low operation cost and environmental cleanness. Although HP has a long history of application to aerospace propulsion systems due to high density, mono-propellant characteristics and low toxicity, it had been replaced by hydrazine and liquid oxygen due to extreme performance requirement during the cold war. But HP has received a renewed interest due to its increased stability and many researches have been conducted to develop high performance LREs(Liquid Rocket Engines) using HP. Liquid methane has also received a new interest in rocket propulsion system for the future space exploration according to its possibility of ISRU(In-Situ Resource Utilization).

• Journal of Hydrogen and New Energy
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• v.21 no.6
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• pp.513-518
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• 2010

In the present work the second-order perturbation solutions of the simple physical model for liquid pool spreading is obtained for the case of instantaneous spill. To generalize the solution governing equations are non-dimensionalized, and two dimensionless parameters, dimensionless evaporation rate and aspect ratio of the initial pool, are identified to control the governing equations. The dimensional governing equations have three parameters. The second-order solution improves fairly the first-order solution for the pool volume.