• Mass Spectrometry Letters
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• 제4권1호
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• pp.18-20
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• 2013

Headspace solid phase micro-extraction gas chromatography/flame ionization detection (HS-SPME-GC/FID) method was compared with headspace gas chromatography/mass selective detection (HS-GC/MS). Organic solvent-spiked urine as well as urine samples from workspace was analyzed under optimal condition of each method. Detection limit of each compound by HS-SPME-GC/FID was $3.4-9.5{\mu}g/L$, which enabled trace analysis of organic solvents in urine. Linear range of each organic solvent was $10-400{\mu}g/L$, with fair correlation coefficient between 0.992 and 0.999. The detection sensitivity was 4 times better than HS-GC/MS in selected ion monitoring (SIM) mode. Accuracy and precision was confirmed using commercial reference material, with accuracy around 90% and precision less than 4.6% of coefficient of variance. Among 48 urine samples from workplace, toluene was detected from 45 samples in the range of $20-324{\mu}g/L$, but no other solvents were found. As a method for trace analysis, SPME HS GC/FID showed high sensitivity for biological monitoring of organic solvent in urine.

• 한국대기환경학회지
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• 제17권5호
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• pp.415-424
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• 2001

The concentrations of PCBs (polychlorinated biphenyls) in air and plants (MOrus allba, Allum turberosum) were measured every other week at Hankyong University located in Ansung, Kyoung-ki province, Korea from July to November in 1999. Total concentrations of PCBs in air ranged from 19.8 to 71.9 pg/ $m^3$. It was observed in air that the concentrations of tai-chlorinated biphenyls(CBs) were higher than those of other PCB homologs probably due to their higher vapor pressure. Total concentrations of PCBs in plants ranged from 24.5 to 1,287 pg/g dry weight for Morus allba and 26.5 to 337 pg/g dry weight for Allum turberosum. A positive linear correlation was observed between log plant-air partition coefficients ( $m^3$air/g plant dry weight-defined here as the scavenging coefficient[S.C]) and log octanol-air partition coefficients ( $K_{oa}$ ) for each plant. In this study, slope of log S.C and log $K_{oa}$ for Morus allba, Allum turberosum were 1.07 ($R^2$= 0.83, p<0.01), 0.84 ($R^2$=0.53, p<0.05), respectively. This means that these plants may approach to equilibrium for air-plant partitioning.

• 한국환경과학회지
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• 제15권1호
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• pp.1-7
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• 2006

The purpose of this study is to illustrate the characteristics of soil organic matter (SOM) and partition coefficient $(K_{DOC})$. Humic substances (HS) from eight soils of varying properties were extracted by two different methods. The dissolved organic carbon (DOC) concentration was stabilized in 22hrs. The ratio of UV absorbance at 465nm and 665nm (E4/E6 ratio) for HS were similar pattern for 8 soils. The extraction with increasing pH increased dissolution of SON. The ratio of organic carbon (OC) associated with HA and FA (the HA:FA ratio) was varied widely in accordance with the soils and was highly correlated to OC $content(\%)$ of the soils. in modeling metal speciation in soils and soil solutions, assumptions that all DOC in soil solution is associated with FA and that HA:FA ratio in SOM is constant have been made. The results of this study indicate that the validity of these assumptions is questionable. By sequential pH extraction, the $K_{DOC}$ showed in a linear correlation with pH.

• Journal of Mechanical Science and Technology
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• 제18권3호
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• pp.513-525
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• 2004

This paper reports an experimental study on flow boiling of pure refrigerants R l34a and R l23 and their mixtures in a uniformly heated horizontal tube. The flow pattern was observed through tubular sight glasses with an internal diameter of 10㎜ located at the inlet and outlet of the test section. Tests were run at a pressure of 0.6 MPa in the heat flux ranges of 5-50㎾/㎡, vapor quality 0-100 percent and mass velocity of 150-600㎏/㎡s. Both in the nucleate boiling-dominant region at low quality and in the two-phase convective evaporation region at higher quality where nucleation is supposed to be fully suppressed, the heat transfer coefficient for the mixture was lower than that for an equivalent pure component with the same physical properties as the mixture. The reduction of the heat transfer coefficient in mixture is explained by such mechanisms as mass transfer resistance and non-linear variation in physical properties etc. In this study, the contribution of convective evaporation, which is obtained for pure refrigerants under the suppression of nucleate boiling, is multiplied by the composition factor by Singal et al. (1984). On the basis of Chen's superposition model, a new correlation is presented for heat transfer coefficients of mixture.

• 한국태양에너지학회 논문집
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• 제33권5호
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• pp.1-8
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• 2013

Wind resource data of short-term period has to be corrected a long-term period by using MCP method that Is a statistical method to predict the long-term wind resource at target site data with a reference site data. Because the field measurement for wind assessment is limited to a short period by various constraints. In this study, 2 different MCP methods such as Linear regression and Matrix method were chosen to compare the predictive accuracy between the methods. Finally long-term wind speed, wind power density and capacity factor at the target site for 20 years were estimated for the variability of wind and wind energy. As a result, for 20 years annual average wind speed, Yellow sea off shore wind farm was estimated to have 4.29% for coefficient of variation, CV, and -9.57%~9.53% for range of variation, RV. It was predicted that the annual wind speed at Yellow sea offshore wind farm varied within ${\pm}10%$.

• 대한음성학회지:말소리
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• 제54호
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• pp.27-43
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• 2005

Existing standard speech coders can provide speech communication of high quality while they degrade the performance of speech recognition systems that use the reconstructed speech by the coders. The main cause of the degradation is that the spectral envelope parameters in speech coding are optimized to speech quality rather than to the performance of speech recognition. For example, mel-frequency cepstral coefficient (MFCC) is generally known to provide better speech recognition performance than linear prediction coefficient (LPC) that is a typical parameter set in speech coding. In this paper, we propose a speech coder using MFCC instead of LPC to improve the performance of a server-based speech recognition system in network environments. However, the main drawback of using MFCC is to develop the efficient MFCC quantization with a low-bit rate. First, we explore the interframe correlation of MFCCs, which results in the predictive quantization of MFCC. Second, a safety-net scheme is proposed to make the MFCC-based speech coder robust to channel error. As a result, we propose a 8.7 kbps MFCC-based CELP coder. It is shown from a PESQ test that the proposed speech coder has a comparable speech quality to 8 kbps G.729 while it is shown that the performance of speech recognition using the proposed speech coder is better than that using G.729.

• 감성과학
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• 제7권3호
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• pp.15-25
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• 2004

본 연구의 목적은 적응신경망퍼지추론시스템(ANFIS)과 회귀분석을 활용하여 7가지 역학적 특성치를 갖는 면직물의 시각적 질감을 해석하고 두 가지 방법을 비교하는 것이다. AMFIS는 퍼지 소속 함수와 신경망 구조를 갖는 것으로 인간의 비선형적 감성예측에 유용한 도구이다. 상관관계 및 회귀 분석의 통계분석은 7가지 역학적 특성치가 주관적 질감과 선형의 관계가 있음을 나타내었지만 설명력이 높지 않았고, 선형 이외의 관련성과 변수들 간의 상호작용을 표현하기 어려운 문제가 있었다. 통계분석과 비교하여, ANFIS는 변수들 간의 비선형적인 관련성과 상호작용을 가시적으로 보여주는데 설명력 있는 유용한 도구였으나, 입력 변수 중 출력 변수에 영향력이 있는 변수를 변별하지 못하여, 생성된 규칙의 수가 복잡한 문제가 있었다. 따라서 ANFIS의 해석이 단순하고 의미있는 모델을 구성하기 위해서는 영향력 있는 출력 변수를 추출하고 나머지 변수를 유사하게 통제하는 실험 모델의 구성이 필요하다.

• Environmental Engineering Research
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• 제22권4호
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• pp.339-346
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• 2017

The objective of this study is the evaluation of the performance of a large-scale respirometer (LSR) of 17.7 L in the determination of the methane generation rate constant (k) values. To achieve this objective, a comparison between anaerobic (GB21) and LSR tests was conducted. The data were modeled using a linear function, and the resulting correlation coefficient ($R^2$) of the linear regression is 0.91. This result shows that despite the aerobic conditions, the biodegradability values that were obtained from the LSR test produced results that are similar to those from the GB21 test. In this respect, the LSR test can be an indicator of the anaerobic biodegradability for landfill waste. In addition, the results show the high repeatability of the tests with an average coefficient of variance (CV) that is lower than 10%; furthermore, the CV for the LSR is lower than that of the GB21, which indicates that the LSR-test method could provide a better representation of waste samples. Therefore, the LSR method allows for both the prediction of the long-term biodegradation potential in a shorter length of time and the reduction of the sampling errors that are caused by the heterogeneity of waste samples. The k values are $0.156y^{-1}$ and $0.127y^{-1}$ for the cumulative biogas production (GB21) and the cumulative oxygen uptake for the LSR, respectively.

• 한국물환경학회지
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• 제25권6호
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• pp.896-901
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• 2009

In this study, in order to apply the air and pure oxygen in the Jet Loop Reactor (JLB) in which the oxygen transfer rate is high, differentiate the operation mode according to each air flowrate and liquid flowrate and investigate the oxygen transfer characteristic, an experiment was carried out. The oxygen concentration with the air flowrate ($Q_g$) and liquid flowrate ($Q_L$) was identical but the oxygen transfer coefficient ($K_L{\cdot}a$) is linear depending on degree of two factors. The width of an increase is small in $0.1min^{-1}$ when the air flowrate is 0.2 L/min with increasing the liquid flowrate. Whereas, the increment was exposed to be very high for $1.5min^{-1}$ when the air flowrate was 5 L/min. In the experiments using the pure oxygen, it was 30 mg/L of oxygen concentration finally and it was 3.5 times than using the air. But the time reached the saturated concentration was similar to using the air, and $K_L{\cdot}a$ was similar to using the air too. Analysis between two independent variable and oxygen transfer of the correlation is the same model like $K_L{\cdot}a={0.0161Q_L}^{1.5371}{Q_g}^{0.5433}$ using with coefficient non linear regression analysis. It was resulted that the liquid flowrate were approximately three times than air flowrate on effect to oxygen transfer rate.

• 한국음향학회지
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• 제35권2호
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• pp.134-142
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• 2016

본 논문에서는 40 kHz 초음파 신호를 입 주변에 쏘고, 되돌아오는 초음파 신호를 이용해 음성신호를 합성하는 방법을 소개하고 성능을 평가하였다. 발성하고 있는 입주변에 초음파를 방사하게 되면, 입술, 턱, 뺨 등의 움직임으로 인한 변위로 도플러 현상이 발생하고, 이에 따라 반사 신호에는 본래의 주파수 성분과는 다른 도플러 주파수가 관찰되는데, 본 논문에서는 이러한 도플러 주파수를 이용하여 음성 파라메터를 추정하도록 하였다. 음성합성에 앞서서 초음파 도플러 신호와 음성 신호 간의 상관관계를 각 주파수 별로 분석하였으며, 이로부터 초음파 도플러 신호를 이용한 음성 신호의 합성 가능성을 살펴보았다. 변환에는 초음파 도플러의 정적, 동적 특성을 함께 반영한 특징 변수를 사용하였으며 결합-혼합 가우시안 기법을 이용하여 음성 파라메터로 변환하였다. 5명의 피 실험자를 이용한 음성 합성 실험에서 필터뱅크 에너지 값을 초음파신호의 특징변수로, LPC(Linear Predictive Coefficient) 켑스트럼 계수를 음성 변수로 사용하는 경우 가장 우수한 변환 성능을 나타내었다. 음성신호에서 추출한 여기신호를 이용하여 합성음을 생성하고, 이를 청취하였을 때 72.2 %의 평균 인식율이 얻어짐을 확인할 수 있었다.