DOI QR코드

DOI QR Code

The Characteristics of Soil Organic Matter

  • You Sun-Jae (Department of Civil & Environmental Engineering, Kunsan National University) ;
  • Kim Jong-gu (Department of Civil & Environmental Engineering, Kunsan National University) ;
  • Cho Eun-Il (Major of Civil & Environmental Engineering, Cheju National University)
  • Published : 2006.01.01

Abstract

The purpose of this study is to illustrate the characteristics of soil organic matter (SOM) and partition coefficient $(K_{DOC})$. Humic substances (HS) from eight soils of varying properties were extracted by two different methods. The dissolved organic carbon (DOC) concentration was stabilized in 22hrs. The ratio of UV absorbance at 465nm and 665nm (E4/E6 ratio) for HS were similar pattern for 8 soils. The extraction with increasing pH increased dissolution of SON. The ratio of organic carbon (OC) associated with HA and FA (the HA:FA ratio) was varied widely in accordance with the soils and was highly correlated to OC $content(\%)$ of the soils. in modeling metal speciation in soils and soil solutions, assumptions that all DOC in soil solution is associated with FA and that HA:FA ratio in SOM is constant have been made. The results of this study indicate that the validity of these assumptions is questionable. By sequential pH extraction, the $K_{DOC}$ showed in a linear correlation with pH.

Keywords

References

  1. Tipping, E., 1994, WHAM- a chemical equili­brium model and computer code for water, sedi­ments and soils incorporating a discrete site/elec­trostatic model of ion-binding humic substances. computers and geoscience, 20, 973-1023 https://doi.org/10.1016/0098-3004(94)90038-8
  2. Tipping, E., D. Berggren, J. Mulder and C. Woof, 1995, Modeling the solid-solution distributions of protons, aluminum, base cations and humic sub­stances in acid soils, Eur. J. Soil Sci., 46, 77-94 https://doi.org/10.1111/j.1365-2389.1995.tb01814.x
  3. Tipping, E., J. Rieuwerts, G. Pan, M. R. Ashmore, S. Lofts, M. T. R. Hill, M. E. Farago and I. Thornton, 2003, The solid-solution partitioning of heavy metals (Cu, Zn, Cd, Pb) in upland soils of England and Wales, Environ. Pollut., 125, 213-225 https://doi.org/10.1016/S0269-7491(03)00058-7
  4. You, S. J., Y. Yin and H. E. Allen, 1999, Partitioning of organic matter in sioils: effects of pH and wa­ter/soil ratio, The Sci. of the Total Environ., 227, 155-160 https://doi.org/10.1016/S0048-9697(99)00024-8
  5. Yin, Y., H. E. Allen, C. P. Huang and P. F. Sanders, 1977, Adsorption/desorption isotherms of Hg(II) by soil, Soil Sci., 162, 35-45 https://doi.org/10.1097/00010694-199701000-00006
  6. Sims, J. T. and S. E. Heckendon, 1991, Methods of soil analysis, Univesity of Delaware, Newark
  7. Tan, K. H., 2003, Humic matter in soil and the environment- principles and controversies, New­York, NY, USA: Marcel Dekker Inc
  8. Impellitteri, C. A., 2000, In Predicting partitioning of cadmium, copper, lead, nickel, zinc, and soil organic matter in soil solution from soil parameters. Ph.D. Dissertation, University of Delaware, USA
  9. Kononova, M. M., 1966, Soil organic matter, Second ed. Pregamon, London
  10. Garcia, C., T. Hernandez and B. Ceccanti, 1995, Characterization by isoelectric focusing of the or­ganic matter of a regenerated soil, Commun. Soil Sci. Plant Anal., 26( 17 & 18), 3033-3041 https://doi.org/10.1080/00103629509369506
  11. Leenheer, J. L., 1980, Origin and nature of humic substances in the waters of the Amazon River basin, Acta Amazonica, 10, 513-526 https://doi.org/10.1590/1809-43921980103513
  12. Baes, A. U. and P. R. Bloom, 1990, Fulvic acid ultraviolet-visible spectra: Influence of solvent and pH, Soil Sci. Soc. AM. J., 54, 1248-1254 https://doi.org/10.2136/sssaj1990.03615995005400050008x
  13. De Wit, H. A., M. Kotowski and J. Mulder, 1999, Modeling aluminum and organic matter solubility in the forest floor using WHAM, Soil Sci. Soc. Am. J, 63, 1141-1148 https://doi.org/10.2136/sssaj1999.6351141x
  14. Berggren, D. and J. Mulder, 1995. The role of organic matter in controlling aluminum solubility in acidic mineral soil horizons, Geochim. Cosmochim. Acta, 59, 4167-4180 https://doi.org/10.1016/0016-7037(95)94443-J
  15. Lofts, S., C. Woof, E. Tipping, N. Clarke and J. Mulder, 2001, Modeling pH buffering and alumi­num solubility in European forest soils, Eur. J. Soil Sci., 52, 189-204 https://doi.org/10.1046/j.1365-2389.2001.00358.x
  16. Vulkan, R, F. Zhao, V. B. Jefferson, S. Preston, G. I. Paton, and S.P. McGrath, 2000, Copper speci­ation and impacts on bacterial biosensors in the pore water of copper-contaminated soils, Environ Sci. Technol., 34, 5115-5121 https://doi.org/10.1021/es0000910
  17. Weng, L. P., L. M. Lexmond, Woolthoorn, E. J. M. Temminghoff and W. H. Van Riemsdijk, 2003, Phytotoxicity and bioavailability of nickel: Chemical speciation and bioaccumulation, Eviron. Toxicol. Chem., 22, 2180-2187 https://doi.org/10.1897/02-116