• Title/Summary/Keyword: length structure

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A Study on the Ternary GF/PA/PP Composites Manufactured by Using Pre-impregnated Glass Fiber (유리섬유를 미리 함침시켜 제조한 GF/PA/PP 삼성분 복합재료에 관한 연구)

  • 윤병선;우동진;서문호;이석현
    • Polymer(Korea)
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    • v.24 no.5
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    • pp.701-712
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    • 2000
  • The continuous fiber reinforced composites of GF/PA were fabricated using a pultrusion resin impregnation apparatus and cut into pellets of 6 mm length. GF/PA pellets were then melt-mixed with PP resin to prepare new types of ternary composites, GF/PA/PP. Mechanical and rheological properties of such composites revealed to be better than conventional ternary composites due to the longer average glass fibers. Measurements also showed that the mechanical properties of the composites prepared by direct injection molding were higher than those of the composites prepared by injection molding followed by extrusion. To improve adhesions of fiber surfaces and polymer matrix, PP-MAH (maleic anhydride) has been introduced in the GF/PA/PP composites as a compatibilizer. It was found that PP-MAH did indeed improve surface adhesion between fibers and polymer matrix and that, as a result, various mechanical properties were markedly enhanced. Visualization of the phase structure in the samples was done by means of SEM. The surfaces of glass fibers in GF/PA/PP composites revealed that the fibers remained to be encapsulated by PA resin. However, pre-encapsulation did not persist in GF/PA/PP/PP-MAH composites due to the improvement of surface adhesion between fibers and polymer matrix, although resin sticking to the fiber was observed.

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Improvement of Thermal Stability of Optical Current Sensors Based on Polymeric Optical Integrated Circuits for Quadrature Phase Interferometry (사분파장 위상 간섭계 폴리머 광집적회로 기반 광전류센서의 온도 안정성 향상 연구)

  • Chun, Kwon-Wook;Kim, Sung-Moon;Park, Tae-Hyun;Lee, Eun-Su;Oh, Min-Cheol
    • Korean Journal of Optics and Photonics
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    • v.30 no.6
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    • pp.249-254
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    • 2019
  • An optical current sensor device that measures electric current by the principle of the Faraday effect was designed and fabricated. The polarization-rotated reflection interferometer and the quadrature phase interferometer were introduced so as to improve the operational stability. Complex structures containing diverse optical components were integrated in a polymeric optical integrated circuit and manufactured in a small size. This structure allows sensing operation without extra bias feedback control, and reduces the phase change due to environmental temperature changes and vibration. However, the Verdet constant, which determines the Faraday effect, still exhibits an inherent temperature dependence. In this work, we tried to eliminate the residual temperature dependence of the optical current sensor based on polarization-rotated reflection interferometry. By varying the length of the fiber-optic wave plate, which is one of the optical components of the interferometer, we could compensate for the temperature dependence of the Verdet constant. The proposed optical current sensor exhibited measurement errors maintained within 0.2% over a temperature range, from 25℃ to 85℃.

Two-Wavelength Lasers Based on Oversized Rib Polymer Waveguide Bragg Reflectors (대형 립 폴리머 광도파로 브래그 격자를 이용한 두 파장 레이저)

  • Sung, Chi-Hun;Kim, Jun-Whee;Shin, Jin-Soo;Oh, Min-Cheol
    • Korean Journal of Optics and Photonics
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    • v.25 no.1
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    • pp.38-43
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    • 2014
  • An external cavity laser supporting two wavelengths is demonstrated by incorporating polymer waveguide Bragg reflectors and a superluminescent light-emitting diode. An oversized rib waveguide structure and Bragg gratings are designed by using the effective-index and transmission-matrix methods. Bragg gratings with different periods are inscribed on a polymer waveguide through double-exposure laser interferometry. In order to tune the cavity loss affected by the reflectivity of Bragg gratings, a Bragg reflectors with varying length is incorporated. Two-wavelength-mode lasing is achieved for the device consisting of 2-mm long, 537-nm period gratings and 2.2-mm long, 540-nm period gratings; the lasing wavelengths are 1554 nm and 1564 nm, with an output power close to 0 dBm, a 20-dB bandwidth of 0.2 nm, and a side-mode suppression ratio of 45 dB.

Thermal and Cholesteric Mesophase Properties of Hydroxypropyl Celluloses and (Butoxypropyl)celluloses (히드록시프로필 셀룰로오스들 그리고 (부톡시프로필)셀룰로오스들의 열 및 콜레스테릭 상의 특성)

  • Jeong, Seung-Yong;Ma, Yung-Dae
    • Polymer(Korea)
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    • v.33 no.3
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    • pp.254-262
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    • 2009
  • Nine kinds of hydroxypropyl celluloses (HPCs) with degree of substitution (DS) and molar substitution (MS) ranging from 2.10 to 2.71 and 2.3 to 6.7, respectively and seven kinds of fully butanoated HPCs (BPCs) based on the HPCs with $2.3\;{\le}\;MS\;{\le}\;6.7$ were synthesized, and the molecular characteristics of HPCs and the thermotropic liquid crystalline properties of the derivatives were investigated. MS was nearly equal to DS for small value of DS, but it became exceedly larger than DS for $DS{\gtrsim}1$, showing that in the later stages of reaction, propylene oxide preferentially adds to the side chains rather than the main chain. All the derivatives formed enantiotropic cholesteric phases with right-handed helical structures. The glass and clearing transition temperatures of both HPCs and BPCs were decreased with increasing MS. The optical pitches (${\lambda}_m'S$) of BPCs, as well as HPCs themselves, increased with increasing temperature. However, the ${\lambda}_m'S$ of both HPCs and BPCs at the same temperature increased with increasing MS. Moreover, the temperature dependence of ${\lambda}_m$ of HPCs was weaker than that of BPCs, suggesting that the helical twisting power of the cellulose chain highly depends on the length and chemical structure of the side chain introduced in cellulose chain.

The Spin Reorientations in $\alpha-Fe_2O_3$ Thin Film ($\alpha-Fe_2O_3$ 박막에서 스핀 재 정렬에 관한 연구)

  • 서정철;이호선
    • Journal of the Korean Magnetics Society
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    • v.11 no.1
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    • pp.21-25
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    • 2001
  • $\alpha$-Fe$_2$O$_3$ thin films were prepared on Si substrate by a pulsed laser deposition system and characterized by X-ray and Mossbauer spectroscopy. The appropriate conditions of pulsation was the power of 5.128 W/cm2 at on oxygen pressure of 0.1 Torr at a substrate temperature of 30$0^{\circ}C$. After that the film was heated at 80$0^{\circ}C$ for 1 day. The particles shape deposited on the film was ellipsoidal and the average length and width were 200~300 nm, 70~150 am respectively. The crystal structure was conformed to be of corundums symmetry with the hexagonal unit cell having a lattice constant of u = 5.03$\pm$0.05 $\AA$, c = 13.735$\pm$0.05 $\AA$. The average angles between the atomic spin and the magnetic hyperfine field of Fe ion were 38$^{\circ}$and 48$^{\circ}$ at above and blow the Morin transition temperature respectively. The Morin transition was found to occur at the temperature ranges from 200 K to room temperature and atomic spin direction was assumed to change from 48$^{\circ}$ to 80$^{\circ}$in respect to the c-axis.

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Isolation and Characterization of a Novel Calcium/Calmodulin-Dependent Protein Kinase, AtCK, from Arabidopsis

  • Jeong, Jae Cheol;Shin, Dongjin;Lee, Jiyoung;Kang, Chang Ho;Baek, Dongwon;Cho, Moo Je;Kim, Min Chul;Yun, Dae-Jin
    • Molecules and Cells
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    • v.24 no.2
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    • pp.276-282
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    • 2007
  • Protein phosphorylation is one of the major mechanisms by which eukaryotic cells transduce extracellular signals into intracellular responses. Calcium/calmodulin ($Ca^{2+}/CaM$)-dependent protein phosphorylation has been implicated in various cellular processes, yet little is known about $Ca^{2+}/CaM$-dependent protein kinases (CaMKs) in plants. From an Arabidopsis expression library screen using a horseradish peroxidase-conjugated soybean calmodulin isoform (SCaM-1) as a probe, we isolated a full-length cDNA clone that encodes AtCK (Arabidopsis thaliana calcium/calmodulin-dependent protein kinase). The predicted structure of AtCK contains a serine/threonine protein kinase catalytic domain followed by a putative calmodulin-binding domain and a putative $Ca^{2+}$-binding domain. Recombinant AtCK was expressed in E. coli and bound to calmodulin in a $Ca^{2+}$-dependent manner. The ability of CaM to bind to AtCK was confirmed by gel mobility shift and competition assays. AtCK exhibited its highest levels of autophosphorylation in the presence of 3 mM $Mn^{2+}$. The phosphorylation of myelin basic protein (MBP) by AtCK was enhanced when AtCK was under the control of calcium-bound CaM, as previously observed for other $Ca^{2+}/CaM$-dependent protein kinases. In contrast to maize and tobacco CCaMKs (calcium and $Ca^{2+}/CaM$-dependent protein kinase), increasing the concentration of calmodulin to more than $3{\mu}M$ suppressed the phosphorylation activity of AtCK. Taken together our results indicate that AtCK is a novel Arabidopsis $Ca^{2+}/CaM$-dependent protein kinase which is presumably involved in CaM-mediated signaling.

Bacterial Community Structure of Food Wastewater Treatment System Combined with Rotating Biological Contactor and Tapered Aeration Reactor (회전접촉장치와 점감포기 반응조를 이용한 식품폐수 처리시설의 세균군집 구조)

  • Jeong, Soon-Jae;Nam, Ji-Hyun;Bae, Woo-Keun;Lee, Dong-Hun
    • Korean Journal of Microbiology
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    • v.46 no.2
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    • pp.169-176
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    • 2010
  • A pilot-scale wastewater treatment plant combined with rotating biological contactor and tapered aeration reactors was operated with the wastewater discharged from a food factory for 5 months. The bacterial communities of this plant were investigated by terminal restriction fragment length polymorphism (T-RFLP) and phylogenetic analysis of 16S rRNA genes. In spite of high concentration of nitrogen and phosphorus as well as organic carbon, removal efficiency of chemical oxygen demand, total nitrogen, and total phosphorus was 98%, 93%, and 95%, respectively. Bacterial community at the initial operation stage was clearly distinguished from that of the stable operation stage. The most predominant phylum in the sample of stable stage was Bacteroidetes. Major population of operation period was Haliscomenobacter, Sphaerotilus, and candidate division TM7, which were classified as filamentous bacteria. However, sludge bulking caused by these bacteria was not observed. The population that has a close relationship with Haliscomenobacter increased during the stable operation stage, emerging as the most predominant group. These results suggest that the filamentous bacteria participated in nutrient removal when using rotating biological contactor and tapered aeration reactor.

2D-QSAR and HQSAR Analysis on the Herbicidal Activity and Reactivity of New O,O-dialkyl-1-phenoxy-acetoxy-1-methylphosphonate Analogues (새로운 O,O-dialkyl-1-phenoxyacetoxy-1-methylphosphonate 유도체들의 반응성과 제초활성에 관한 2D-QSAR 및 HQSAR 분석)

  • Sung, Nack-Do;Jang, Seok-Chan;Hwang, Tae-Yeon
    • The Korean Journal of Pesticide Science
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    • v.11 no.2
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    • pp.72-81
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    • 2007
  • Quantitative structure-activity relationships (QSARs) on the pre-emergency herbicidal activity and reactivity of a series of new O,O-dialkyl-1-phenoxyacetoxy-1-methylphosphonates (S) analogues against seed of cucumber (Cucumus Sativa) were discussed quantitatively using 2D-QSAR and HQSAR methods. The statistical values of HQSAR model were better than that of 2D-QSAR model. From the frontier molecular orbital (FMO) interaction between substrate molecule (S) and $BH^+$ ion (I) in PDH enzyme, the electrophilic reaction was superior in reactivity. From the effect of substituents, $R_2$-groups in substrate molecule (S) contributed to electrophilic reaction with carbonyl oxygen atom while X, Y-groups contributed to nucleophilic reaction with carbonyl carbon atom. And the influence of X,Y-groups was more effective than that of $R_2$-groups. As a results of 2D-QSAR model (I & II) and atomic contribution maps with HQSAR model, the more length of X, Y-groups is longer, the more herbicidal activity tends to increased. And also, the optimal ${\epsilon}LUMO$ energy, $({\epsilon}LUMO)_{opt.}$=-0.479 (e.v.) of substrate molecule is important factor in determining the herbicidal activity. It is predicted that the herbicidal activity proceeds through a nucleophilic reaction. From the analytical results of 2D-QSAR and HQSAR model, it is suggested that the structural distinctions and descriptors that contribute to herbicidal activities will be able to applied new herbicide design.

A Study on Storytelling and Musical Composition of the Sillian Song -Focusing on the 'mojookjirangga'- (신라 향가의 스토리텔링과 음악적 가창성 연구 -모죽지랑가를 중심으로-)

  • Lee, Chang-Ho
    • The Journal of the Korea Contents Association
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    • v.15 no.2
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    • pp.163-176
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    • 2015
  • This study aims to decode newly 'Mojookjirangga' of the Sillian songs on higher viewpoint that is to integrate previous decodings; furthermore to discuss a musical composition of the Sillian song. So to speak, when we read 'hoe(廻)' as 'gam(감)-' instead of 'dol(돌)-' in the song 'Mojookjirangga' which was written in Chinese Characters, such a decoding contributes largely to grip the deep meaning-structure of the elegiac song. Consequently we are able to sing that 'Mojookjirangga' according to the characteristics of national music. However the characteristics of national music are 1) the length of a phrase makes a rhythm, 2) the first beat is strong beat and becomes more and more weak, 3) there are shaking sounds on the long rhythm and changing vowels, 4) there is deep and great dignity in those national music songs. Then we can find those characteristics easily at Sijo-songs. In fact, the Sillian songs and Sijo-songs of Chosun period are more popular music. Then we are going to sing 'Mojookjirangga', referring to the method of Sijo-song and the characteristics of national music. Nowadays such an attempt is to contribute to enrich our national culture and to make the global Korean-stream more abundant.

Fishing Mechanism of Pots and their Modification 5. An Experiment for Modifying the Pot for Conger Eel, Astroconger myriaster (통발어구의 어획기구 및 개량에 관한 연구 5. 붕장어통발의 개량실험)

  • KIM Dae-An;KO Kwan-Soh
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.23 no.4
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    • pp.315-322
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    • 1990
  • In order to find out the most favorable shape and structure of pot for conger eel, Astroconger myriaster(Brevoort), the box type, tube type and flat box type of net pots and the pipe type of plastic pot were prepared. Then, the ability of the pots attracting the eel into them were investigated through a tank experiment. The attracting ability was highest in the pipe type without distinction of its length, 50cm and 60cm. In the flat box type, the effective height of pot and the diameter of entrance tip turned out 5cm respectively. But the ability was very poor in the rest pots, especially in the tube type. Thus, the pipe type and flat box type of pots were employed again in a field experiment for comparing their catches with those of the conventional bamboo and plastic pots. In the experiment, the catches were the most in the pipe type and second in the flat box type. But the bamboo and plastic pots both produced comparatively low catches, showing no significant difference between them. It was therefore concluded that the pipe type of pot might be the most favorable one for catching the conger eel.

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